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  • 1
    Keywords: Towards the Monitoring of Dumped Munitions Threat (Project). ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (251 pages)
    Edition: 1st ed.
    ISBN: 9789402411539
    Series Statement: NATO Science for Peace and Security Series C: Environmental Security Series
    DDC: 623.44500000000005
    Language: English
    Note: Intro -- Preface: The NATO Science for Peace and Security Perspective -- Acknowledgements -- Contents -- Editors and Contributors -- Editors -- Contributors -- Chapter 1: Introduction -- 1.1 Introduction -- 1.2 Study Area -- 1.2.1 Gotland Basin -- 1.2.2 Bornholm Deep -- 1.2.3 Little Belt -- 1.2.4 Gdansk Basin -- 1.3 Environmental Fate of Munitions and Chemicals -- 1.4 Risks and Impacts on the Marine Environment -- 1.5 Management Requirements -- 1.6 Conclusions -- References -- Chapter 2: Suitability Study of Survey Equipment Used in the MODUM Project -- 2.1 Introduction -- 2.2 Autonomous Underwater Vehicle (AUV) IVER2 -- 2.2.1 Sonar Performance -- 2.2.2 AUV Operation -- 2.2.3 Precision of Navigation -- 2.3 Edge Tech DF - 1000 Side Scan Sonar (SSS) -- 2.3.1 Sonar Performance -- 2.3.2 Edge Tech DF - 1000 Operation -- 2.3.3 Precision of Navigation -- 2.4 Klein 3900 Side Scan Sonar -- 2.4.1 Sonar Performance and Operation -- 2.5 Falcon Seaeye Remotely Operated Vehicle (ROV) -- 2.5.1 ROV Performance -- 2.5.2 Precision of Navigation -- 2.6 Sub-bottom Profiler Edge Tech SB216S -- 2.6.1 Equipment Description -- 2.6.2 Experimental Campaign -- 2.6.3 Data Collection -- 2.6.4 Data Analysis: Sub-bottom Data -- 2.6.5 Sub-bottom Anomalies -- 2.7 Summary and Conclusions -- References -- Chapter 3: Results of Acoustic Research in the CM Deploying Areas -- 3.1 Introduction -- 3.2 Theory of Sound Scattering at the Sea Bottom -- 3.3 Sound Backscattering at Munition and Methods of Detection -- 3.4 Setup Characteristics -- 3.5 Signal and Image Postprocessing -- 3.6 Statistics of Surveys Aimed at Acoustic Detection and Classification of Targets -- 3.7 Acoustic Classifications of Sediments in the Area and Critical Aspects of Detection and Classification -- 3.8 Summary -- References. , Chapter 4: Chemical Analysis of Dumped Chemical Warfare Agents During the MODUM Project -- 4.1 Introduction on Sea-Dumped CWAs in the Baltic Sea -- 4.1.1 Dumping Sites, Munitions and Chemicals -- 4.1.2 Arsenic Concentration in Baltic Sediments -- 4.2 Chemical Analysis On-Site by Gas Chromatography - Mass Spectrometry -- 4.2.1 On Ship Analysis with Deployable Headspace GC-MS -- 4.3 Analysis of Chemical Warfare Agents Degradation Products by Portable CE Instrument -- 4.3.1 Brief Overview of Capillary Electrophoresis -- 4.3.2 Overview of Analysis of Chemical Warfare Agents and Its Degradation Products by Portable CE Instruments -- 4.3.3 Tallinn University of Technology Research in MODUM Project -- 4.4 Reach-Back Laboratory -- 4.4.1 Analysis of Samples near the Wreck in Bornholm Deep -- 4.4.2 Analysis of Monitoring Samples Taken in Baltic Dumpsites -- 4.4.3 High-Resolution Mass Spectrometry Analysis -- 4.4.4 Total Arsenic Measurements -- 4.5 Conclusions/Summary -- References -- Chapter 5: Environmental Toxicity of CWAs and Their Metabolites -- 5.1 Introduction -- 5.2 Methods -- 5.2.1 Literature Review -- 5.2.2 Computational Toxicogenomics -- 5.2.3 Microtox™ -- 5.2.4 Mixture Toxicity (Microtox™) -- 5.2.5 Daphnia magna - Acute -- 5.2.6 Daphnia magna - Chronic -- 5.2.7 Zebrafish (Danio rerio) Subchronic Test -- 5.3 Results -- 5.3.1 Literature Review -- 5.3.2 Toxicogenomic Read-Across Analysis -- 5.3.3 Microtox™ -- 5.3.4 Microtox™ Mixture -- 5.3.5 Daphnia magna Acute -- 5.3.6 Daphnia magna - Chronic -- 5.3.7 Zebrafish Sub-chronic Locomotor Behaviour Test -- 5.4 Discussion and Conclusion -- References -- Chapter 6: The Health Status of Fish and Benthos Communities in Chemical Munitions Dumpsites in the Baltic Sea -- 6.1 General Introduction -- 6.2 Benthos Communities in the Deep Basins -- 6.3 Fish Communities in the Deep Basins. , 6.4 Fish Health in the Deep Basins -- 6.5 Summary and Conclusions -- References -- Chapter 7: Estimation of Potential Leakage from Dumped Chemical Munitions in the Baltic Sea Based on Two Different Modelling Approaches -- 7.1 Introduction -- 7.2 Materials and Methods -- 7.2.1 Passive Tracer -- 7.2.2 Lagrangian Tracking -- 7.2.2.1 Particle Transport Model -- 7.2.2.2 Bottom Stress Analysis -- 7.2.2.3 Verification of Random-Walk Model -- 7.3 Results and Discussion -- 7.3.1 Integrations Based on the Passive Tracer -- 7.3.2 Calculations of Trajectories -- 7.4 Summary -- Bibliography -- Chapter 8: Weight-of-Evidence Environmental Risk Assessment -- 8.1 Introduction -- 8.2 Methods -- 8.2.1 Risk Assessment -- 8.2.1.1 Predicted No Effect Concentration (PNEC) -- 8.2.1.2 Predicted Environmental Concentration (PEC) -- 8.2.1.3 Risk Quotient (RQ) -- 8.2.2 Weight of Evidence (WoE) -- 8.3 Materials and Data -- 8.3.1 Sediment Samples -- 8.3.2 Toxicity Data -- 8.3.3 Other Data -- 8.4 Results and Discussion -- 8.4.1 Risk Assessment -- 8.5 Weight of Evidence (WoE) -- 8.5.1 Lines of Evidence (LoE) -- 8.6 Conclusions -- Appendix 1 Risk Maps for Study Areas -- References -- Chapter 9: Best Practices in Monitoring -- 9.1 Introduction -- 9.2 When to Monitor -- 9.3 Survey -- 9.3.1 Stage I - Area Wide Assessment -- 9.3.2 Stage II Detail Survey and Investigation -- 9.3.3 Detail Description of Activities and Equipment Essential for Complete the Procedure -- 9.4 Physics -- 9.5 Sampling -- 9.6 Best Practices for Chemical Analysis of CW Contaminated Sediments -- 9.7 Studies Using Fish as Bioindicators -- 9.7.1 Rational for Monitoring Fish Health Effects of Dumped Munitions -- 9.7.2 How to Sample Fish -- 9.7.3 How to Examine Fish for Health Effects -- 9.7.4 How to Treat Fish Disease Data -- 9.8 Modelling -- 9.9 Conclusions -- References.
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  • 2
    Keywords: Environment ; System safety ; Environmental monitoring ; Environmental chemistry ; Environmental management ; Water pollution ; Environmental policy
    Description / Table of Contents: This book describes the creation of a monitoring network, which can provide information about the exact locations and the environmental threats posed by chemical weapons (CW) dumpsites in the Baltic Sea region, using autonomous underwater vehicles (AUVs) and remotely operated underwater vehicles (ROVs), and utilising the existing research vessels of NATO partner institutions as launching platforms. The dumping operations occurred shortly after World War II and included captured German munitions. Operations with munitions from the Soviet occupation zone were performed by the Soviet Navy, operations with munitions from British and American occupation zones were performed in areas outside of the Baltic Sea (Skagerrak Strait); the fate of munitions from the French occupation zone was never reported. Due to difficult legal status of these munitions, and high costs of remediation and retrieval, removal of these weapons from the bottom of the Baltic Sea seems unlikely in the foreseeable future. These dumped chemical weapons pose an actual environmental and security hazard in the Baltic Sea Region. Nowadays, with more and more industrial activities being performed in the Baltic Sea Area, the threat level is rising. The AUV survey is based on the IVER2 platform by OceanServer, equipped with Klein 3500 side-scan sonar. The identification phase utilises several ROVs, equipped with targeting sonars, acoustic cameras capable of penetrating turbid bottom waters up to 20m, and visual HD cameras. A novel sediment sampling system, based on a camera and sonar equipped cassette sampler, has been developed to obtain surface sediments. The test phase described consists of a survey phase, which will locate the actual objects concerned, and a monitoring phase, which will concentrate on the collection of environmental data close to the objects concerned
    Type of Medium: Online Resource
    Pages: Online-Ressource (XVII, 240 p. 101 illus. in color, online resource)
    ISBN: 9789402411539
    Series Statement: NATO Science for Peace and Security Series C: Environmental Security
    Language: English
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  • 3
    Publication Date: 2017-06-19
    Description: The central Baltic Sea is a marginal brackish basin which comprises anoxic bottom waters and is surrounded by geological source terrains with a wide variety of compositions and ages. This allows the investigation of water mass mixing using radiogenic isotope compositions of Nd and Hf as well as their geochemical cycling across varying redox conditions in the water column. In this study, we present the distribution of Nd and Hf concentrations and their isotopic compositions for 6 depth profiles and 3 surface water sites obtained during a cruise in the central Baltic Sea onboard the RV Oceania as a part of the international GEOTRACES program. The results obtained indicate that Nd isotopes effectively trace the mixing between more radiogenic saline waters from the south and unradiogenic fresh waters from the north, which helps to understand the reliability of Nd isotopes as water mass tracer in the open ocean. In surface waters, Nd shows higher concentrations and less radiogenic isotope compositions at the northern stations, which are progressively diluted and become more radiogenic to the south, consistent with the counterclockwise circulation pattern of central Baltic Sea surface waters. In contrast to the variable Nd concentrations, Hf shows much less variability. At the Gotland Deep station, the Nd concentrations of the euxinic waters are higher by a factor 〉10 than those of the overlying oxygen-depleted waters, whereas Hf only shows small concentration variations. This indicates faster removal of Hf from the water column than Nd. Moreover, the dissolved Hf isotope signatures document great variability but no consistent mixing trends. Our explanation is that Hf has a lower residence time than Nd, and also that the Hf isotope signatures of the sources are highly heterogeneous, which is attributed to their differing magmatic and tectonic histories as well as incongruent post-glacial weathering around the central Baltic Sea.
    Type: Article , PeerReviewed
    Format: text
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  • 4
    Publication Date: 2023-02-08
    Description: Seawater Mg:Ca and Sr:Ca ratios are biogeochemical parameters reflecting the Earth-ocean-atmosphere dynamic exchange of elements. The ratios' dependence on the environment and organisms' biology facilitates their application in marine sciences. Here, we present a measured single-laboratory dataset, combined with previous data, to test the assumption of limited seawater Mg:Ca and Sr:Ca variability across marine environments globally. High variability was found in open-ocean upwelling and polar regions, shelves/neritic and river-influenced areas, where seawater Mg:Ca and Sr:Ca ratios range from ∼4.40 to 6.40 mmol:mol and ∼6.95 to 9.80 mmol:mol, respectively. Open-ocean seawater Mg:Ca is semiconservative (∼4.90 to 5.30 mol:mol), while Sr:Ca is more variable and nonconservative (∼7.70 to 8.80 mmol:mol); both ratios are nonconservative in coastal seas. Further, the Ca, Mg, and Sr elemental fluxes are connected to large total alkalinity deviations from International Association for the Physical Sciences of the Oceans (IAPSO) standard values. Because there is significant modern seawater Mg:Ca and Sr:Ca ratios variability across marine environments we cannot absolutely assume that fossil archives using taxa-specific proxies reflect true global seawater chemistry but rather taxa- and process-specific ecosystem variations, reflecting regional conditions. This variability could reconcile secular seawater Mg:Ca and Sr:Ca ratio reconstructions using different taxa and techniques by assuming an error of 1 to 1.50 mol:mol, and 1 to 1.90 mmol:mol, respectively. The modern ratios' variability is similar to the reconstructed rise over 20 Ma (Neogene Period), nurturing the question of seminonconservative behavior of Ca, Mg, and Sr over modern Earth geological history with an overlooked environmental effect.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 5
    Publication Date: 2022-01-31
    Description: After World War II, as a move toward Germany demilitarization, up to 385,000 t of munitions were sunk in the Baltic Sea. Munition containing various harmful substances, including chemical warfare agents (CWA) and explosives, that can affect marine biota were dumped on the seafloor. Some of those objects contained mercury, either as elemental mercury or mercury compounds (e.g., mercury fulminate, a common explosive primer), and thus could act as a specific local source of mercury in the dumping areas. Unfortunately, there is a lack of information on how dumped munitions impact the mercury concentrations in the Baltic Sea sediments. This report aims to answer the question how much sedimentary mercury in the dumping areas originates from munitions and to determine to what extent the mercury present in those areas originates from mercury fulminate. Concentrations of total sedimentary mercury- HgTOT in samples collected from conventional (Kolberger Heide) and chemical (Bornholm Deep) munitions dumping sites are characterized by high variability. However, an increase in HgTOT concentrations was observed with a decreasing distance to particular munition objects at both study sites. Moreover, mercury speciation in sediments from Kolberger Heide proves that the mercury there can be traced back directly to mercury fulminate. Results of our study confirm that munitions dumpsites are a local point sources of mercury. Due to the ecosystem constrains, varying transport modes and pathways, and both unknown and varying decomposition rates, these sea-bed mercury concentrations are hard to evaluate quantitatively. Therefore we recommend that further detailed studies should be conducted to assess sedimentary mercury provenience in munitions dumpsites more accurately.
    Type: Article , PeerReviewed
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  • 6
    Publication Date: 2024-02-07
    Description: Armed conflicts have, in addition to severe impacts on human lives and infrastructure, also impacts on the environment, which needs to be assessed and documented. On September the 26th 2022, unknown perpetrators deliberately ruptured the two gas pipelines Nord Stream 1 and 2 with four coordinated explosions near a major chemical munition dump site near the Danish island of Bornholm in the Baltic Sea. While the massive release of natural gas into atmosphere raised serious concerns concerning the contribution to climate change—this paper assesses the overlooked direct impact of the explosions on the marine ecosystem. Seals and porpoises within a radius of four km would be at high risk of being killed by the shockwave, while temporary impact on hearing would be expected up to 50 km away. As the Baltic Proper population of harbour porpoises ( Phocoena phocoena ) is critically endangered, the loss or serious injury of even a single individual is considered a significant impact on the population. The rupture moreover resulted in the resuspension of 250000 metric tons of heavily contaminated sediment from deep-sea sedimentary basin for over a week, resulting in unacceptable toxicological risks towards fish and other biota in 11 km 3 water in the area for more than a month.
    Type: Article , PeerReviewed
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  • 7
    Publication Date: 2024-02-07
    Description: Biomass is defined as organic matter from living organisms represented in all kingdoms. It is recognized to be an excellent source of proteins, polysaccharides and lipids and, as such, embodies a tailored feedstock for new products and processes to apply in green industries. The industrial processes focused on the valorization of terrestrial biomass are well established, but marine sources still represent an untapped resource. Oceans and seas occupy over 70% of the Earth’s surface and are used intensively in worldwide economies through the fishery industry, as logistical routes, for mining ores and exploitation of fossil fuels, among others. All these activities produce waste. The other source of unused biomass derives from the beach wrack or washed-ashore organic material, especially in highly eutrophicated marine ecosystems. The development of high-added-value products from these side streams has been given priority in recent years due to the detection of a broad range of biopolymers, multiple nutrients and functional compounds that could find applications for human consumption or use in livestock/pet food, pharmaceutical and other industries. This review comprises a broad thematic approach in marine waste valorization, addressing the main achievements in marine biotechnology for advancing the circular economy, ranging from bioremediation applications for pollution treatment to energy and valorization for biomedical applications. It also includes a broad overview of the valorization of side streams in three selected case study areas: Norway, Scotland, and the Baltic Sea.
    Type: Article , PeerReviewed
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  • 8
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    In:  EPIC3Treffen Bund-Länderausschuß Nord- und Ostsee (BLANO), Bundesamt für Seeschifffahrt und Hydrographie (BSH), Hamburg, Germany, 2014-06-18-2014-06-18
    Publication Date: 2014-06-23
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 9
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    Institute of Oceanology Polish Academy of Sciences
    In:  EPIC3Gdańsk, Institute of Oceanology Polish Academy of Sciences, 86 p., ISBN: 978-83-936609-1-9
    Publication Date: 2014-06-23
    Repository Name: EPIC Alfred Wegener Institut
    Type: Book , peerRev
    Format: application/pdf
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  • 10
    Publication Date: 2019-03-16
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
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