Note: Cover -- Title Page -- Copyright -- Contents -- Preface -- About the Editors -- Part I Chemically Modified Carbon Nanotubes: Overview, Commercialization, and Economic Aspects -- Chapter 1 A Detailed Study on Carbon Nanotubes: Properties, Synthesis, and Characterization -- 1.1 Introduction -- 1.2 Evolution of Carbon: Graphite to CNTs -- 1.2.1 Graphite -- 1.2.2 Diamond -- 1.2.3 Graphene -- 1.2.3.1 Direct Lattice -- 1.2.3.2 The Reciprocal Lattice -- 1.2.4 Carbon Nanotubes -- 1.2.4.1 SWNTs: Types and Structure -- 1.2.4.2 Chirality -- 1.2.4.3 Electronic Properties of CNTs -- 1.2.4.4 Optical Properties of CNTs -- 1.2.4.5 Chemical Properties of CNTs -- 1.2.4.6 Defects in CNTs -- 1.2.4.7 CNTs Properties Modification by Chemical Functionalization Process -- 1.2.4.8 Applications of CNTs -- 1.2.4.9 Synthesis of CNTs -- 1.2.4.10 Analysis of CNTs by Raman Spectroscopy -- 1.3 Conclusion -- Declaration of Competing Interest -- Companies Dealing with Chemically Modified CNTs -- Acknowledgments -- References -- Chapter 2 Surface Modification Strategies for the Carbon Nanotubes -- 2.1 Introduction -- 2.2 Classification of Carbon Nanotubes and Their Fabrication -- 2.2.1 Arc‐Discharge Method -- 2.2.2 Laser Vapor Deposition -- 2.2.3 Chemical Vapor Deposition (CVD) -- 2.3 Purification of CNTs -- 2.4 Surface Modification of CNTs -- 2.4.1 Methods of Functionalization -- 2.4.2 Noncovalent Functionalization -- 2.4.3 Covalent (Chemical) Functionalization -- 2.4.3.1 Defect‐Group Functionalization -- 2.4.3.2 Sidewall Functionalization -- 2.4.3.3 CNTs Functionalized with Polymer -- 2.4.3.4 CNTs Functionalized with Biomolecules -- 2.4.3.5 CNTs Functionalization with Ionic Liquid (ILs) -- 2.4.3.6 Plasma Activated CNTs -- 2.5 Characterization of CNTs -- 2.6 Conclusion -- References. , Chapter 3 Latest Developments in Commercial Scale Fabrications for Chemically Modified Carbon Nanotubes -- Abbreviations -- 3.1 Introduction -- 3.2 Industrial Scale Fabrication Strategies -- 3.2.1 Basic Chemical Vapor Deposition (CVD) Process -- 3.2.1.1 Industrial Level Fabrication of CNT Through Various CVD Methods -- 3.2.1.2 High‐Pressure Chemical Vapor Deposition -- 3.2.1.3 Atmospheric‐Pressure Chemical Vapor Deposition (APCVD) -- 3.2.1.4 Low‐Pressure Chemical Vapor Deposition (LPCVD) -- 3.3 CVD on the Basis of Reactor Wall Temperature -- 3.3.1 Hot‐Wall Chemical Vapor Deposition (Hot‐Wall CVD) -- 3.3.2 Cold‐Wall Chemical Vapor Deposition (Cold‐Wall CVD) -- 3.4 Arc‐Discharge -- 3.5 Laser Vaporization -- 3.6 Other Synthesis Methods -- 3.7 Applications -- 3.7.1 Transistors -- 3.7.2 Conductor -- 3.7.3 Composites -- 3.7.4 Aerogels -- 3.8 Future Scope -- 3.9 Conclusion -- Conflict of Interest -- Other Sources -- Acknowledgments -- References -- Chapter 4 Economical Uses of Chemically Modified Carbon Nanotubes -- 4.1 Introduction -- 4.2 Properties of Carbon Nanotubes -- 4.3 Synthesis of Carbon Nanotubes -- 4.4 Functionalization of Carbon Nanotubes -- 4.5 Characterization/Analysis of Functionalized Carbon Nanotubes -- 4.6 Economy of Carbon Nanotubes -- 4.7 Economic Importance of Carbon Nanotubes -- 4.8 Hydrogen Fuel Cells -- 4.9 Water Splitting -- 4.10 Dye‐Sensitized Solar Cells -- 4.11 Quantum Dot Solar Cells -- 4.12 Silicon‐Based Solar Cells -- 4.13 Thermoelectric Fabrics -- 4.14 Cost of Carbon Nanotubes -- 4.15 Globalization of Carbon Nanotubes -- 4.16 Conclusion -- References -- Part II Chemically Modified Carbon Nanotubes: Energy and Environment Applications -- Chapter 5 Chemically Modified Carbon Nanotubes in Energy Production and Storage -- Abbreviations -- 5.1 Introduction -- 5.2 Production of Carbon Nanotubes. , 5.3 History of Energy Storage Devices and Materials -- 5.4 Carbon Nanotubes for Energy Storage -- 5.4.1 Carbon Nanotube Hybrid for Lithium‐Metal Batteries -- 5.4.2 Wearable Energy Storage with Fiberic Carbon Nanotube -- 5.4.3 Carbon Nanotube Hybrid for Supercapacitor Energy Storage -- 5.4.4 Carbon Nanotubes/Biochar for Energy Storage -- 5.5 Present and Future of Carbon Nanotubes -- 5.6 Commercial‐Scale Application of Chemically Modified CNTs for Energy Storage -- 5.7 Companies Produced CNTs for the Application of Chemically Modified Carbon Nanotubes for Energy Storage -- References -- Chapter 6 Chemically Modified Carbon Nanotubes for Pollutants Adsorption -- 6.1 Introduction -- 6.2 Chemically Modified CNTs -- 6.3 Chemically Modified CNTs for Adsorptive Removal of Pollutants -- 6.3.1 Organic Dyes -- 6.3.2 Removal of Pharmaceuticals -- 6.3.3 Other Organic Pollutants -- 6.3.4 Metal Ions -- 6.4 Influencing Factors -- 6.5 Adsorption Mechanisms of Chemically Modified CNTs -- 6.6 Modified CNT‐Based Materials Toward Commercialization -- 6.7 Conclusion and Future Perspectives -- Acknowledgments -- References -- Chapter 7 Chemically Modified Carbon Nanotubes in Removal of Textiles Effluents -- 7.1 Introduction -- 7.2 History of Removal of Textiles Effluents -- 7.3 Chemically Modified Carbon Nanotubes -- 7.3.1 Chemical Properties -- 7.3.2 Modification Through Chemical Reduction of Diazonium Salts -- 7.4 Dyes Removal Techniques -- 7.5 Adsorption -- 7.6 Carbon‐Based Nanoadsorbents -- 7.7 Carbon Nanotubes -- 7.8 Carbon Nanotubes as an Adsorption of Dye Molecules -- 7.9 Industrial Application of Synthetic Dyes -- 7.10 Conclusion -- Acknowledgment -- References -- Chapter 8 Chemically Modified Carbon Nanotubes in Membrane Separation -- 8.1 Introduction -- 8.2 Carbon Nanotubes (CNTs) Overview -- 8.3 Method of Synthesis of Carbon Nanotube (CNT) -- 8.3.1 Arc Discharge. , 8.3.2 Laser Ablation -- 8.3.3 Chemical Vapor Deposition (CVD) -- 8.3.4 Hydrothermal -- 8.3.5 Electrolysis -- 8.4 Fabrication Methods of CNTs -- 8.4.1 Fabrication of CNT‐Reinforced Metal Matrix Composites (CNT‐MMCs) -- 8.4.2 Microwave‐Assisted Fabrication of CNTs -- 8.5 Functionalization of CNTs -- 8.6 Chemically Modified Derivatization of CNTs -- 8.6.1 Electrochemically Assisted Covalent Modification -- 8.7 Polymer Grafting -- 8.8 Carbon Nanotubes Enhanced with Nanoparticles -- 8.9 Advantages of CNTs -- 8.10 Challenges in CNTs -- 8.11 Applications of CNTs as Membrane Separation -- 8.11.1 Water Treatment -- 8.11.2 Air Filtration -- 8.11.3 Energy Storage: Capacitors and Batteries -- 8.11.4 Electrochemical Separation and Catalysis -- 8.11.5 Electronic Devices Fabrication -- 8.11.6 Environment -- 8.11.7 Biology and Agriculture -- 8.12 Commercial‐Scale of Chemically Modified CNTs in Membrane Separation -- 8.13 Future Insights -- 8.14 Conclusion -- References -- Chapter 9 Chemically Modified Carbon Nanotubes for Water Purification System -- Abbreviations -- 9.1 Introduction -- 9.2 History of Water Purification Methods -- 9.3 Carbon Nanotubes CNTs Types -- 9.4 Vital of Modification of CNTs -- 9.5 Surface Modified CNTs for Water Purification -- 9.6 Polymer/CNTs Grafting for Water Purification -- 9.7 Bulk Modified CNTs for Water Purification -- 9.8 Important of Carbon Nanotubes for Water Purification -- 9.9 Conclusions and Future Research Directions -- 9.10 Commercial Application of Chemically Modified CNTs in Water Purification -- 9.11 Companies Produced CNTs for the Application of Chemically Modified Carbon Nanotubes for Water Purification System -- References -- Part III Chemically Modified Carbon Nanotubes: Electronic and Electrical Applications -- Chapter 10 Chemically Modified Carbon Nanotubes for Electronics and Photonic Applications. , 10.1 Introduction -- 10.2 Chemical Modifications of CNTs -- 10.2.1 Oxidative Functionalization of CNTs -- 10.2.2 Polymer/Ionic Liquid Modification of Oxidized CNTs -- 10.2.3 Direct Covalent Modification of CNT -- 10.2.4 Heteroatom Doping of CNTs -- 10.2.5 Charge Transfer/Noncovalent Doping of CNTs -- 10.3 Chemically Modified CNTs in Electronics -- 10.3.1 Transistors -- 10.3.2 Rectifying Diodes -- 10.3.3 Bioelectronics -- 10.4 Chemically Modified CNTs in Photonics -- 10.4.1 Organic Photovoltaics (OPV) -- 10.4.2 Organic Light‐Emitting Diodes (OLEDs) -- 10.4.3 Touch Panels -- 10.5 Summary and Future Scope -- References -- Chapter 11 Chemically Modified Carbon Nanotubes for Electrochemical Sensors -- 11.1 Introduction -- 11.2 Functionalization of Carbon Nanotubes Toward Sensors -- 11.2.1 Covalent Functionalization of CNTs Toward Sensing -- 11.2.2 Noncovalent Functionalization of CNTs Toward Sensing -- 11.2.3 Polymers Wrapping of CNTs Toward Sensing -- 11.2.4 CNTs Decorated with Metal Nanoparticles Toward Sensing -- 11.3 Electrochemical Sensing Applications of CNTs -- 11.3.1 CNT‐Based Sensors for Environment Protection -- 11.3.2 CNT‐Based Sensors for Pharmaceutical Applications -- 11.3.3 Monitoring of Biomolecular Compounds -- 11.3.3.1 Glucose Sensor -- 11.3.3.2 DNA Sensor -- 11.3.4 CNTs‐Based Sensors for Real Sample Analysis -- 11.4 Summary and Outlook -- References -- Chapter 12 Chemically Modified Carbon Nanotubes for Lab on Chip Devices -- Abbreviations -- 12.1 Introduction -- 12.2 Allotropes of Carbon -- 12.2.1 Diamond -- 12.2.2 Graphite -- 12.2.3 Fullerenes -- 12.2.4 Carbon Nanotubes -- 12.2.4.1 SWCNT: Various Synthesis Methods -- 12.2.4.2 Growth Catalysts for SWCNT -- 12.2.4.3 Approach of Introducing the Catalyst on SWCNTs (CVD) Growth -- 12.2.5 Double‐Walled Carbon Nanotubes (DWCNTs) -- 12.2.5.1 Development of DWCNTs. , 12.2.5.2 Purification of DWCNTs.

Note: Front Cover -- Inorganic Anticorrosive Materials -- Copyright Page -- Contents -- List of contributors -- I. Overview on metal oxides -- 1 Nanomaterials as corrosion inhibitors -- 1.1 Introduction -- 1.1.1 Corrosion and its consequences -- 1.1.2 Corrosion inhibition -- 1.2 Nanomaterials -- 1.2.1 General introduction, types, and synthesis methods -- 1.2.1.1 Bottom-up method -- 1.2.1.2 Top-down approach -- 1.2.2 Characterization of nanomaterials -- 1.3 Nanomaterials as anticorrosive materials -- 1.3.1 Metal/metal oxide nanoparticles as corrosion inhibitors -- 1.3.2 Quantum dots as corrosion inhibitors -- 1.3.3 Nanotubes as corrosion inhibitors -- 1.3.4 Nanofibers as corrosion inhibitors -- 1.3.5 Nano containers as corrosion inhibitors -- 1.3.6 Nanocomposites as corrosion inhibitors -- 1.4 Challenges facing the use of nanomaterials as corrosion inhibitors -- 1.4.1 Toxicity -- 1.4.2 Agglomeration -- 1.4.3 Prediction of mechanism -- 1.5 Conclusion -- 1.6 Future research directions -- Useful links -- References -- 2 Metal oxides: Advanced inorganic materials -- 2.1 Outline of chapter -- 2.2 Introduction to metal oxide and its materials -- 2.2.1 Inorganic oxides -- 2.2.2 Metal oxide -- 2.2.3 Mixed metal oxide -- 2.2.4 Nanotechnology -- 2.3 Synthetic methodologies of metal oxides -- 2.3.1 Physical methods -- 2.3.1.1 Physical vapor deposition -- 2.3.1.2 Milling -- 2.3.1.3 Spray pyrolysis -- 2.3.1.4 Laser ablation -- 2.3.1.5 Inert gas condensation -- 2.3.1.6 Arc discharge -- 2.3.1.7 Thermolysis -- 2.3.2 Chemical methods -- 2.3.2.1 Sol-gel method -- 2.3.2.2 Chemical vapor deposition -- 2.3.2.3 Polyol method -- 2.3.2.4 Electrochemical synthesis -- 2.3.2.5 Sonochemical synthesis -- 2.3.3 Green synthesis or biological methods -- 2.3.3.1 Green synthesis using plant extracts -- 2.3.3.2 Green synthesis using microorganisms. , 2.3.3.3 Green synthesis using biomolecules -- 2.4 Fundamental science and properties of nanometal oxide as advanced material -- 2.4.1 Properties of nanoparticulated oxides -- 2.4.1.1 Optical properties-surface plasmon resonance -- 2.4.1.2 Transport properties -- 2.4.1.3 Mechanical properties -- 2.4.1.4 Chemical properties -- 2.4.1.5 Quantum effects -- 2.5 Review of metal oxide nanomaterials used for varied applications in different fields of research -- 2.6 Application, discussion and future claims -- 2.6.1 Environmental and solar applications -- 2.6.2 Corrosion and electrochemical applications -- 2.6.2.1 Corrosion of Steel in Acidic Solution and Inhibition Mechanism -- 2.6.2.2 Mechanism -- 2.6.2.3 Potential with zero charge -- 2.6.2.4 Factors affecting the efficiency of inhibitors -- 2.6.2.4.1 Disperability-nano metal oxide -- 2.6.3 Biomedical applications -- 2.6.3.1 Drug delivery -- 2.7 Conclusion -- References -- 3 Molecularly imprinted magnetite nanomaterials and its application as corrosion inhibitors -- 3.1 Introduction -- 3.1.1 Effects of coating on magnetite by the silica (Fe3O4/SiO2) nanomaterials -- 3.1.2 Molecularly imprinted nanomaterials (Fe3O4/SiO2/Thermosensitive/EDTA) -- 3.1.2.1 Coupling of chitosan on functionalized EDTA graftted thermosensetive modified magnetite molecularly imprinted nanom... -- 3.1.3 General principle of molecularly imprinted nanomaterials -- 3.1.4 Structure of magnetite nanomaterials -- 3.2 Distinctive synthetic approach of molecularly imprinted magnetite nanomaterials -- 3.2.1 Coprecipitation method -- 3.2.2 Reverse micellar method -- 3.2.3 Sonochemical technique -- 3.2.4 Hydrothermal technique -- 3.2.5 Thermal decomposition technique -- 3.2.6 Sol-gel technique -- 3.3 Functionalization of molecularly imprinted magnetite nanoparticles -- 3.3.1 Silica -- 3.3.2 Metal or nonmetal. , 3.3.3 Metal oxides and metal sulfides -- 3.3.4 Coating of organic compounds on the surface of the magnetite nanoparticles -- 3.3.5 Polymers -- 3.3.6 Biological molecules -- 3.4 Characterization techniques -- 3.4.1 XRD analysis -- 3.4.2 Surface morphology and elemental analysis -- 3.4.3 Vibrating sample magnetometer -- 3.4.4 Dynamic light scattering -- 3.5 Conclusions -- Author declaration -- References -- Further reading -- 4 Basics of metal oxides: properties and applications -- 4.1 Introduction -- 4.2 Properties of metal oxide -- 4.3 Application of metal oxides -- 4.3.1 Cupric oxide -- 4.3.2 Zinc oxide (ZnO) -- 4.3.3 Cobolt oxide (II, III)/Co3O4 -- 4.4 Titanium oxide -- 4.5 Conclusion and future directions -- References -- 5 Recent developments in properties and applications of metal oxides -- 5.1 Introduction -- 5.2 Properties of metal oxides nanoparticles -- 5.3 Diverse applications of metal oxides nanoparticles -- 5.3.1 Gas sensing -- 5.3.2 Batteries -- 5.3.3 Solar cells -- 5.4 Supercapacitor -- 5.4.1 Anticorrosive -- 5.4.2 Photocatalysis -- 5.4.3 Basic principle of TiO2 based photocatalysts -- 5.5 Summary -- References -- 6 Functionally integrated metal oxides for corrosion protection -- 6.1 Introduction -- 6.2 Corrosion protection process -- 6.3 Electrochemical characterization and evaluation techniques -- 6.3.1 Open circuit potential -- 6.3.2 Polarization techniques -- 6.3.2.1 Linear polarization resistance -- 6.3.2.2 Potentiodynamic polarization -- 6.3.2.3 Tafel extrapolation method -- 6.3.2.4 Cyclic polarization -- 6.3.3 Electrochemical impedance spectroscopy -- 6.4 Different transition metals and their characteristics -- 6.4.1 Titanium dioxide (TiO2) -- 6.4.2 Zirconium dioxide (ZrO2) -- 6.4.3 Zinc oxide (ZnO) -- 6.4.4 MoO2 and MoO3 -- 6.5 Coating techniques for the synthesis of corrosion protection -- 6.5.1 Physical vapor deposition. , 6.5.2 Chemical vapor deposition -- 6.5.3 Microarc oxidation -- 6.5.4 Electrodeposition coating -- 6.5.5 Sol-gel coating -- 6.5.6 Thermal spray coating -- 6.5.7 High-velocity oxy-fuel coating -- 6.5.8 Plasma spray coating -- 6.6 Factors affecting the efficiency of mixed metal oxide as corrosion protection -- 6.7 Mixed metal oxide coatings studied for corrosion protection -- 6.7.1 TiO2-ZnO -- 6.7.2 TiO2-ZrO2 -- 6.7.3 MoO2-ZrO2, MoO2-TiO2 -- 6.7.4 Early studies for trimetallic oxides ZrO2-ZnO-TiO2 -- 6.8 Summary -- Useful links -- References -- 7 A prospective utilization of metal oxides for self-cleaning and antireflective coatings -- 7.1 Introduction -- 7.1.1 Classification of metal oxides -- 7.1.1.1 Ferroelectric metal oxides -- 7.1.1.2 Magnetic metal oxides -- 7.1.1.3 Multiferroic metal oxides -- 7.1.2 Nanocomposite metal oxides -- 7.1.3 Properties of metal oxides -- 7.2 Electrical and dielectric properties -- 7.3 Electrochemical properties -- 7.3.1 Metal oxides as self-cleaning and antireflective coatings -- 7.3.2 Application of metal oxides -- 7.3.2.1 Biomedical and healthcare -- 7.3.2.2 Solar energy -- 7.3.2.3 Water purification membranes -- 7.3.2.4 Application in machining and automotive -- 7.4 Conclusion -- References -- II. Metal oxides as corrosion inhibitors -- 8 CeO as corrosion inhibitors -- 8.1 An overview -- 8.2 Cerium (IV) oxide as corrosion inhibitor -- 8.3 Utilization of cerium IV oxide as corrosion inhibitor in the past decade -- Useful links -- References -- 9 Utilization of ZnO-based materials as anticorrosive agents: a review -- 9.1 Introduction -- 9.1.1 Corrosion inhibitors and coatings -- 9.2 Properties of ZnO -- 9.2.1 Corrosion resistance of ZnO nanoparticles -- 9.3 Corrosion resistance of ZnO-based corrosion inhibitors -- 9.4 Corrosion resistance of ZnO-based nanocomposite coatings. , 9.5 Corrosion resistance of ZnO/mixed nanocomposites -- 9.6 Conclusion -- Useful links -- References -- 10 MgO as corrosion inhibitor -- 10.1 Introduction -- 10.2 Synthesis, properties and applications of magnesium oxide -- 10.3 Application of MgO and its composites as a corrosion inhibitor for the protection of metallic materials -- 10.4 Application of MgO and its composites as corrosion inhibitors for the protection of magnesium alloy -- 10.5 Application of MgO and its composites as corrosion inhibitors for the protection of iron and its alloys -- 10.6 Application of MgO and its composites as corrosion inhibitors for protection of cemented carbide -- 10.7 Application of MgO and its composites as corrosion inhibitors for the protection of metallic materials in bioscience -- 10.8 ZnMgO solid solution nanolayer as anticorrosion material -- 10.9 Drawbacks -- 10.10 Conclusion and future perspective -- References -- 11 Copper oxide as a corrosion inhibitor -- 11.1 Introduction -- 11.2 Metallic deterioration and its protection from corrosive environment -- 11.3 Copper oxide as corrosion inhibitor -- 11.4 Summary and future perspective -- References -- 12 Corrosion inhibition by aluminum oxide -- 12.1 Introduction -- 12.2 What is corrosion? -- 12.3 Consequences of corrosion -- 12.4 Methods of controlling corrosion -- 12.5 Corrosion inhibitors -- 12.5.1 Definition of corrosion inhibitors -- 12.5.2 Classification -- 12.5.2.1 Organic inhibitors -- 12.5.2.2 Inorganic inhibitors -- 12.6 Aluminum oxide -- 12.6.1 Influence of pH on aluminum passivation -- 12.6.2 Mechanism of corrosion of aluminum -- 12.7 Potential - pH diagrams -- 12.8 Case study -- 12.8.1 Inhibition of corrosion of aluminum in well water by polyvinyl alcohol, carboxymethyl cellulose, and Zn2+ -- 12.8.2 Electrochemical studies -- 12.8.2.1 Polarization study. , 12.8.2.1.1 Aluminum in well water system (pH 10, adjusted with NaOH).

Note: Cover -- Title Page -- Copyright -- Contents -- Preface -- About the Editors -- Chapter 1 Organometallic Compounds: The Fundamental Aspects -- 1.1 Introduction -- 1.1.1 Organometallic Chemistry -- 1.1.2 Organometallic Compounds -- 1.1.3 Structure of Organometallic Compound -- 1.2 Milestones in Organometallic Compounds -- 1.2.1 Equation (1.1): Synthesis of First Organometallic Compound -- 1.2.2 Equation (1.2): Preparation of Zeise's Salt -- 1.2.3 Equations (1.3)-(1.5): Preparation of Organochlorosilane Compound -- 1.2.4 Equation (1.6): Synthesis of First Metal Carbonyl Compound -- 1.2.5 Equation (1.7): Synthesis of First Binary Metal Carbonyl Complex -- 1.2.6 Equation (1.8): Barbier Reaction -- 1.2.7 Equation (1.9): Synthesis of Organic Compound Using a Grignard Reagent -- 1.2.8 Equations (1.10) and (1.11): Synthesis of Alkyllithium Compound -- 1.2.9 Equations (1.12) and (1.13): Synthesis of Organolithium Compound -- 1.2.10 Equation (1.14): Hydroformylation Reaction -- 1.2.11 Equation (1.15): Synthesis of Organochlorosilane Compound -- 1.2.12 Equation (1.16): Trimerization of Acetylene -- 1.2.13 Equation (1.17): Synthesis of Ferrocene -- 1.2.14 Equation (1.18): Asymmetric Catalysis Reaction -- 1.2.15 Equation (1.19): Palladium Catalyzed Suzuki Coupling Reaction -- 1.2.16 Equation (1.20): Synthesis of Bucky Ferrocene -- 1.3 Stability of Organometallic Compounds -- 1.4 Properties of Organometallic Compounds -- 1.5 Basic Concepts in Organometallic Compounds -- 1.5.1 18‐Electron Rule -- 1.5.1.1 Statement of 18 Electron Rule -- 1.5.1.2 Examples -- 1.5.2 Π -Back Bonding or Back Donation -- 1.5.3 Hapticity ηx -- 1.6 Hapticity of Ligands -- 1.7 Change in Hapticity -- 1.8 Hapticity Verses Denticity -- 1.9 Counting of Electrons and Finding out Metal-Metal Bonds -- 1.9.1 Calculating the Number of Metal-Metal Bonds. , 1.9.2 Writing the Probable Structure of Compound -- 1.9.3 How to Draw the Probable Structure of Ni(η1‐C3H5) (η3‐C3H5) -- 1.9.4 How to Draw the Probable Structure of (μ‐CO)‐[η5‐CpRh]3(CO) -- 1.10 Metals of Organometallic Compounds -- 1.10.1 Organometallic Compounds of Transition Metals -- 1.10.2 The Bonding and Structure in Different Metal complexes -- 1.10.2.1 Alkene Complexes -- 1.10.2.2 Allyl Complexes -- 1.10.2.3 Carbonyl Complexes -- 1.10.2.4 Metallocenes -- 1.10.2.5 Dihydrogen Complexes -- 1.10.2.6 Transition Metal Carbene Complex -- 1.11 Importance of Organometallic Compounds -- 1.11.1 Types of Organometallic Compounds -- 1.11.2 Uses of Organometallic Compounds -- 1.12 Conclusions -- References -- Chapter 2 Nomenclature of Organometallic Compounds -- 2.1 Introduction -- 2.2 Aim of the Nomenclature -- 2.3 Type of Nomenclature System -- 2.3.1 Binary Nomenclature -- 2.3.2 Substitutive Nomenclature -- 2.3.3 Additive Nomenclature or Coordination nomenclature -- 2.4 Concepts and Conventions -- 2.4.1 Oxidation Number -- 2.4.2 Coordination Number -- 2.4.3 Chelation -- 2.4.4 Ligands -- 2.4.5 Specifying Connectivity - The Kappa (κ) Convention -- 2.4.6 Bridging Ligands - The Mu (μ) Convention -- 2.4.7 Hapticity - The Eta (η) Convention -- 2.5 Regulations Concerning the Nomenclature of Transition Element Organometallic Compounds -- References -- Chapter 3 Classification of Organometallic Compounds -- 3.1 Introduction -- 3.2 Classification of Organometallic Compound -- 3.2.1 Sigma‐Bonded Organometallic Compound -- 3.2.2 π‐Bonded Organometallic Compounds -- 3.2.3 Ionic Bonded Organometallic Compounds -- 3.2.4 Multicentered Bonded Organometallic Compounds -- 3.2.4.1 Based on Heptacity (η1 to η8): -- 3.3 Grignard Reagent (G.R.) -- 3.3.1 Physical Properties -- 3.3.2 Chemical Properties -- 3.3.2.1 Alkanes -- 3.3.2.2 Alkenes -- 3.3.2.3 Alkynes -- 3.3.2.4 Ethers. , 3.3.2.5 Reaction with carbon dioxide -- 3.3.2.6 Insertion Reaction -- 3.3.2.7 Synthesis of Silicones -- 3.3.2.8 Nucleophilic Substitution -- 3.4 Organozinc Compounds -- 3.4.1 Physical Properties -- 3.4.2 Chemical Properties -- 3.5 Organolithium Compounds -- 3.5.1 Reaction Resembling Grignard Reagents -- 3.5.2 Reactions Different from Grignard Reagents -- 3.6 Organosulfur Compounds -- 3.6.1 Physical Properties -- 3.6.2 Chemical Properties -- 3.6.3 Properties Different from Alcohols -- 3.7 Conclusion -- References -- Chapter 4 Synthesis Methods of Organometallic Compounds -- 4.1 Introduction -- 4.2 Synthesis Methods of Organometallic Compounds -- 4.2.1 Electrochemical Methods for the Synthesis of Organometallic Compounds -- 4.2.1.1 Synthesis of Cyano Cu(I) Complexes in the Electrochemical Cell -- 4.2.1.2 Synthesis of an Organorhenium Cyclopentadienyl Complex in the Electrochemical Cell -- 4.2.1.3 Synthesis of N‐heterocyclic Carbene Complexes in the Electrochemical Cell -- 4.2.1.4 Synthesis of Organocopper (I) π‐Complexes in the Electrochemical Cell -- 4.2.1.5 Synthesis of Organonickel σ‐Complexes in the Electrochemical Cell -- 4.2.2 Synthesis of Organic Compounds in the Electrochemical Cell by Metal organic Catalysts -- 4.2.2.1 The Synthesis of Organic Compounds in the Electrochemical Cell by the Ni‐Organic Catalyze -- 4.2.2.2 The Synthesis of Organic Compounds in the Electrochemical Cell by the Pd‐Organic Catalyses -- 4.2.2.3 Synthesis of Organic Compounds in the Electrochemical Cell by the Sm‐Organic Catalyses -- 4.2.3 Synthesis of Organometallic Nucleosides -- 4.2.3.1 A Category: Main Compounds -- 4.2.3.2 A1 Subcategory: Main Compounds -- 4.2.3.3 B Category: Main Compounds -- 4.2.3.4 C Category: Main Compounds -- 4.2.3.5 C1 Subcategory: Main Compounds -- 4.2.3.6 D Categories: Main Compounds -- 4.3 Conclusions -- Acknowledgment. , Authors Contributions -- Conflicts of Interest -- References -- Chapter 5 Metal Carbonyls: Synthesis, Properties, and Structure -- 5.1 Introduction -- 5.2 Classification of Metal Carbonyls -- 5.2.1 Classification Based on Coordinated Ligands -- 5.2.1.1 Homoleptic Carbonyls -- 5.2.1.2 Heteroleptic Carbonyls -- 5.2.2 Classification Based on Number of Metals and the Constitution of Carbonyls -- 5.2.2.1 Mononuclear Carbonyl Complexes -- 5.2.2.2 Polynuclear Carbonyl Complexes -- 5.3 Synthesis of Metal Carbonyls -- 5.3.1 Direct Reaction of Metal with Carbon Monoxide -- 5.3.2 Reductive Carbonylation -- 5.3.3 Photolysis and Thermolysis -- 5.3.4 Abstraction of CO from a Reactive Organic Carbonyl Compounds -- 5.4 Properties of Metal Carbonyls -- 5.4.1 Physical Properties -- 5.4.2 Chemical Properties -- 5.4.2.1 Ligand Substitution Reactions -- 5.4.2.2 Reaction with Sodium Metal -- 5.4.2.3 Reaction with Sodium Hydroxide -- 5.4.2.4 Reaction with Halogens -- 5.4.2.5 Reaction with Hydrogen -- 5.4.2.6 Reaction with Nitricoxide (NO) -- 5.4.2.7 Disproportionation -- 5.5 Structure of Metal Carbonyls -- 5.5.1 Structures of Some Mononuclear Carbonyl Complexes -- 5.5.2 Structures of Some Bi and Polynuclear Carbonyl Complexes -- 5.6 Bonding in Metal Carbonyls -- 5.6.1 Formation of Mixed Atomic Orbitals -- 5.7 Synergistic Effect -- 5.8 Conclusion -- Further Reading -- References -- Chapter 6 Metal-Carbon Multiple Bonded Compounds -- 6.1 Introduction -- 6.2 Nomenclature -- 6.3 Classifications -- 6.3.1 Metal-alkylidene Complexes -- 6.3.2 Metal-alkylidyne Complexes -- 6.4 Structure -- 6.4.1 Alkylidene (Carbene) -- 6.4.2 Carbyne (Alkylidyne) -- 6.5 Preparation Methods -- 6.5.1 Metal-alkylidene Complexes -- 6.5.1.1 By Nucleophilic Carbene -- 6.5.1.2 By Electrophilic Alkylidenes -- 6.5.2 Metal-alkylidyne Complexes -- 6.6 Important Reactions. , 6.6.1 Reaction of Alkylidene Metathesis -- 6.6.2 Important Reaction of Alkylidyne Metathesis -- 6.7 Applications -- References -- Chapter 7 Metallocene: Synthesis, Properties, and Structure -- 7.1 Introduction -- 7.2 Structure of Metallocene -- 7.3 Synthesis of Metallocene -- 7.4 Chemical Properties of Metallocene -- 7.4.1 Ferrocene and Its Derivatives -- 7.4.2 Other Metallocene Sandwiches -- 7.4.3 Main‐group Metallocene -- 7.4.4 Metal-bis‐arene Sandwich Complexes -- 7.4.4.1 General View -- 7.4.4.2 Structure -- 7.4.4.3 Reactions -- 7.5 Conclusion -- References -- Chapter 8 σ‐Complexes, π‐Complexes, and ηn‐CnRn Carbocyclic Polyenes‐Based Organometallic Compounds -- 8.1 Introduction -- 8.2 σ‐Bond Containing Organometallic Compounds -- 8.2.1 Metal Carbonyl -- 8.2.1.1 General Overview -- 8.2.1.2 Syntheses of Metal Carbonyls -- 8.2.1.3 Structure of Metal Carbonyls -- 8.2.1.4 Reactions of Metal Carbonyls -- 8.2.2 Metal-Alkyl, -Vinyl, and -Hydride Complexes -- 8.2.2.1 Metal Alkyls -- 8.2.2.2 Metal Vinyls -- 8.2.2.3 Metal Hydrides -- 8.2.2.4 Metal-Carbene Complexes -- 8.3 π‐Bond Containing Organometallic Compounds -- 8.3.1 Metal-Olefin Complexes -- 8.3.1.1 General Overview -- 8.3.1.2 Syntheses of Metal-Olefin Complexes -- 8.3.1.3 Reactions of Metal-Olefin Complexes -- 8.3.2 Metal-Diene Complexes -- 8.3.3 Metal-Alkyne Complexes -- 8.3.4 π-Allyl Complexes -- 8.3.4.1 Structure of π-Allyl Complexes -- 8.3.4.2 Syntheses of π-Allyl Complexes -- 8.3.4.3 Reactions of π-Allyl Complexes -- 8.4 ηn‐CnRn Carbocyclic Polyenes Containing Organometallic Compounds -- 8.4.1 Cyclopropenyls, η3‐C3R3 -- 8.4.2 Cyclobutadienes, η4‐C4R4 -- 8.4.3 Cyclopentadienyls, η5‐C5R5 -- 8.4.3.1 General Overview -- 8.4.3.2 Structure of Metallocene -- 8.4.3.3 Syntheses of Metallocene -- 8.4.3.4 Chemical Properties of Metallocene -- 8.4.3.5 Applications of Metallocene -- 8.5 Conclusion. , References.

Note: Front Cover -- Metal-Chalcogenide Nanocomposites -- Copyright Page -- Contents -- List of contributors -- About the editors -- Preface -- 1 Chalcogenides and their nanocomposites: fundamental, properties and applications -- 1.1 Introduction -- 1.1.1 Thin film-based supercapacitor -- 1.1.1.1 Thin film-based perovskite solar cells -- 1.2 Metal chalcogenide thin film-based solar cells -- 1.3 Antibacterial applications of thin films -- 1.4 Future perspective/outlook -- 1.5 Conclusion -- Acknowledgment -- References -- 2 Chalcogenides and their nanocomposites in environmental remediation -- 2.1 Introduction -- 2.2 Experimental -- 2.2.1 Hydrothermal method -- 2.2.2 Sonication method -- 2.2.3 Microemulsion method -- 2.2.4 Solvothermal method -- 2.2.5 Sol-gel method -- 2.3 Results and discussion -- 2.3.1 Sulfides (S) chalcogenides -- 2.3.2 Selenide (Se) chalcogenides -- 2.3.3 Tellurides (Te) chalcogenides -- 2.3.4 CO2 reduction -- 2.3.5 Heavy metal removal -- 2.4 Conclusion and future perspectives -- References -- 3 Chalcogenides and their nanocomposites in photocatalytic reactions -- 3.1 Introduction -- 3.2 Chalcogenides for the photocatalytic hydrogen evolution -- 3.2.1 General synthesis approaches of chalcogenides -- 3.2.2 Chalcogenides and their photocatalytic activities -- 3.2.2.1 Molybdenum-based chalcogenides -- 3.2.2.2 Zinc based chalcogenides -- 3.2.2.3 Copper based chalcogenides -- 3.2.2.4 Vanadium based chalcogenides -- 3.2.2.5 Cadmium based chalcogenides -- 3.2.2.6 Tin based chalcogenides -- 3.2.2.7 Titanium-based chalcogenides -- 3.3 Conclusions and perspectives -- References -- 4 Metal chalcogenides and their nanocomposites in water purification systems -- 4.1 Introduction -- 4.1.1 Background of chalcogenides -- 4.1.1.1 Methods of preparation -- Solvothermal method -- Electrospinning method -- Coprecipitation method. , 4.2 Removal of synthetic dyes using metal chalcogenide nanocomposites -- 4.3 Removal of toxic heavy metal ions using metal chalcogenides nanocomposites -- 4.4 Removal of residual antibiotics using metal chalcogenides nanocomposites -- 4.5 Future perspective/outlook -- 4.6 Conclusion -- References -- 5 Metal chalcogenides and their nanocomposites in industrial effluents treatments -- 5.1 Introduction -- 5.2 Role of metal chalcogenides -- 5.3 Conclusion -- References -- 6 Heterostructured transition metal chalcogenides photocatalysts for organic contaminants degradation -- 6.1 Introduction -- 6.2 Methods for wastewater treatment -- 6.2.1 Homogeneous photocatalysis -- 6.2.2 Heterogeneous photocatalysis -- 6.3 Transition metal chalcogenides -- 6.4 Synthesis methodologies -- 6.4.1 Hot-Plate method -- 6.4.2 One-pot heat-up method -- 6.4.3 Hydro/solvothermal method -- 6.4.4 Electrospinning -- 6.4.5 Sonochemical -- 6.5 Characterizations -- 6.6 TMCs as heterogeneous photocatalysts -- 6.7 Application for photocatalytic degradation of organic pollutants -- 6.7.1 Dyes -- 6.7.2 Pesticides and endocrine disruptors -- 6.7.3 Pharmaceuticals -- 6.8 Conclusion -- References -- 7 Chalcogenides and their nanocomposites in heavy metal decontamination -- 7.1 Introduction -- 7.2 Traditional heavy metal treatment -- 7.2.1 Ion exchange methods -- 7.2.2 Adsorption methods -- 7.3 Photocatalytic heavy metal treatment -- 7.4 Conclusion and future perspectives -- Acknowledgments -- Declaration of competing interest -- References -- 8 Chalcogenides and their nanocomposites in oxygen reduction -- 8.1 Introduction -- 8.2 Molybdenum based electrocatalysts -- 8.3 Ruthenium based electrocatalysts -- 8.4 Cobalt based chalcogenides -- 8.5 Rhenium based electrocatalysts -- 8.6 Iridium based electrocatalysts -- 8.7 Other electrocatalysts -- 8.8 Conclusion -- References. , 9 Nanocomposites of chalcogenides as super capacitive materials -- 9.1 Introduction -- 9.2 Chalcogenides as promising electrodes for SCs -- 9.2.1 Nickel-based chalcogenides and their composites for SCs -- 9.2.1.1 Copper-based selenides and their composites for SCs -- 9.2.1.1.1 Manganese-based chalcogenides and their composites for SCs -- 9.3 Conclusion -- References -- 10 Metal-chalcogenides nanocomposites as counter electrodes for quantum dots sensitized solar cells -- 10.1 Introduction -- 10.2 QD sensitizers -- 10.3 Counter electrodes -- 10.4 Interface modification layer -- 10.5 Conclusion -- Acknowledgments -- Author Contributions -- Notes -- References -- 11 II-VI semiconductor metal chalcogenide nanomaterials and polymer composites: fundamentals, properties, and applications -- 11.1 Introduction -- 11.2 Structure and chemical properties of II-VI chalcogenide nanomaterials -- 11.3 Different properties of II-VI chalcogenide nanomaterials -- 11.3.1 Electrical and optical properties -- 11.3.2 Thermal properties -- 11.3.3 Physical properties -- 11.3.3.1 Refractive index and dispersion -- 11.3.3.2 Linear loss mechanisms -- 11.3.3.3 Photo-induced phenomena -- 11.4 Chemical Synthesis of II-VI chalcogenide nanomaterials and polymer composites -- 11.4.1 Chemical route for preparation of II-VI chalcogenide nanocrystals in powder form -- 11.4.2 Synthesis of thin films embedded in polymers -- 11.5 Applications of chalcogenides nanomaterials -- 11.5.1 Applications of chalcogenide nanomaterials and heterostructures for quantum dot LEDs -- 11.5.2 Applications of chalcogenide nanomaterials and their heterostructures for photocatalysis -- 11.5.3 Applications of chalcogenides nanomaterials heterostructures for solar cell -- 11.5.3.1 Thin film photovoltaic cell -- 11.5.3.2 Polymer/quantum dot hybrid organic-inorganic solar cell. , 11.5.3.3 Chalcogenides nanostructures for hybrid photovoltaic cell -- 11.6 Summary and future scope -- References -- 12 Challenges and opportunities of chalcogenides and their nanocomposites -- 12.1 Introduction -- 12.1.1 Introduction to chalcogens -- 12.1.2 Introduction to chalcogenides -- 12.1.3 Classification of chalcogenides based on the number of elements -- 12.1.3.1 Binary chalcogenides -- 12.1.3.2 Ternary chalcogenides -- 12.1.3.3 Quaternary chalcogenides -- 12.1.4 Classification of chalcogenides based on the number of chalcogen ions -- 12.1.4.1 Mono-chalcogenides -- 12.1.4.2 Dichalcogenides -- 12.1.4.3 Trichalcogenides -- 12.1.5 Chalcogenide nanomaterials -- 12.1.5.1 Metal-based chalcogenides -- 12.1.5.2 Noble metal-based chalcogenides -- 12.1.5.3 Chalcogenide composites -- 12.2 Synthesis of metal chalcogenide and their nanocomposites -- 12.2.1 Hot-injection method -- 12.2.2 Hydrothermal method -- 12.2.3 Solvothermal method -- 12.2.4 Microwave method -- 12.2.5 Sonochemical method -- 12.2.6 Growth of metal chalcogenide nanostructure arrays on substrates -- 12.3 Preparation of chalcogenide nanocomposites -- 12.3.1 Preparation of metal chalcogenide nanocomposites with carbon materials -- 12.3.2 Preparation of chalcogenide nanocomposites with noble metals -- 12.3.3 Preparation of chalcogenide nanocomposites with metal oxides -- 12.4 Application of chalcogenide and their nanocomposites -- 12.4.1 Photocatalysts -- 12.4.2 Environmental remediation -- 12.4.3 Reduction of nitroaromatic compounds -- 12.4.4 Supercapacitors -- 12.4.5 Lithium-ion batteries -- 12.4.6 Water splitting -- 12.4.7 CO2 activation -- 12.5 Future prospects of chalcogenides -- 12.6 Conclusion -- References -- Index -- Back Cover.