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  • 1
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    Impact of hydrothermal alteration processes on element mobility and potential environmental implications at the Sousaki solfataric field (Corinthia - Greece) (2020)
    Details
    Publication Date: 2023-10-26
    Description: Samples of efflorescences and encrustations of hydrothermal origin were collected at Sousaki (Greece) and analysed for their mineralogical (XRD) and chemical composition. Solutions obtained both from mineralization with HNO3 and from leaching with deionised water were analysed for major (ICP-OES), minor and trace metals (ICP-MS) and sulfate contents (IC). Results evidence the dependence of the chemical and mineralogical composition on micro-environmental conditions i.e. humidity, oxygen-rich or -poor environment, exposed or sheltered from meteoric agents. In fact, the presence of highly soluble sulfate minerals with elevated contents of many metals (e.g. Mg, Al, Fe, Mn, Cr, Ni, etc.) further underscores the important influence of hydrothermal activity on elements' mobility, whilst the sometimes very high concentrations in toxic elements like Al, Cr, Ni suggest also possible environmental impacts.
    Description: Published
    Description: 107121
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Hydrothermal alteration products ; Sulfates ; Toxic metals ; Elements' mobility ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Chemical characterisation of the gases released at Gyali Island, Dodecanese, Greece and preliminary estimation of the CO2 output (2021)
    SGI
    Details
    Publication Date: 2023-10-26
    Description: Greece belongs to the most geodynamically active regions of the world and as such, it has to be considered an area of intense geogenic degassing. In terms of carbon, the territory is characterized by the high hydrothermal and volcanic activity of the South Aegean Active Volcanic Arc (SAAVA), and by widespread geological seeps of buried carbon dioxide and methane. In the present work, we investigate the island of Gyali located in the volcanic system Kos-Gyali-Nisyros. Nine gas samples have been collected on the island of Gyali in areas found both on land, in a small lake (~2000 m2) along its beach, and in the sea close to the shore at shallow depths (〈20 m). Results show that CO2 is the prevailing gas species with concentrations above 833,000 μmol/mol, whilst minor enrichments in N2 are noticed in some of the samples. Helium isotope ratio suggests an up to 70% mantle origin (considering a MOR type source) with the contribution of the atmospheric component being negligible, whereas C presents a mixed mantle-limestone origin with organic sediment being unimportant. Such isotope values fall in the range that characterizes the Kos-Gyali-Nisyros Volcanic Field. First estimations on the CO2 release suggest an output in the range from 18 to 28 t/d for Gyali Island, which is much lower than the total output of Kos ~75 t/d and Nisyros ~100 t/d. However, such results highlight that Gyali is an active system and, despite its small size, its degassing is not trivial.
    Description: Published
    Description: 16-28
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: flux measurements ; carbon degassing ; SAAVA ; 05.09. Miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Atmospheric Deposition around the Industrial Areas of Milazzo and Priolo Gargallo (Sicily-Italy)-Part A: Major Ions (2023)
    MDPI
    Details
    Publication Date: 2023-08-29
    Description: The chemical composition of rainwater was studied in two highly-industrialised areas in Sicily (southern Italy), between June 2018 and July 2019. The study areas were characterised by large oil refining plants and other industrial hubs whose processes contribute to the release of large amounts of gaseous species that can affect the chemical composition of atmospheric deposition As in most of the Mediterranean area, rainwater acidity (ranging in the study area between 3.9 and 8.3) was buffered by the dissolution of abundant geogenic carbonate aerosol. In particular, calcium and magnesium cations showed the highest pH-neutralizing factor, with ~92% of the acidity brought by SO42- and NO3- neutralized by alkaline dust. The lowest pH values were observed in samples collected after abundant rain periods, characterised by a less significant dry deposition of alkaline materials. Electrical Conductivity (ranging between 7 µS cm-1 and 396 µS cm-1) was inversely correlated with the amount of rainfall measured in the two areas. Concentrations of major ionic species followed the sequence Cl- 〉 Na+ 〉 SO42- ≃ HCO3- 〉 ≃ Ca2+ 〉 NO3- 〉 Mg2+ 〉 K+ 〉 F-. High loads of Na+ and Cl- (with a calculated R2 = 0.99) reflected proximity to the sea. Calcium, potassium, and non-sea-salt magnesium had a prevalent crustal origin. Non-sea salt sulphate, nitrate, and fluoride can be attributed mainly to anthropogenic sources. Mt. Etna, during eruptive periods, may be also considered, on a regional scale, a significant source for fluoride, non-sea salt sulphate, and even chloride.
    Description: Published
    Description: 3898
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: acidity neutralization ; anthropogenic source ; atmospheric deposition ; major ions ; marine source ; 01.01. Atmosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    Atmospheric Deposition around the Industrial Areas of Milazzo and Priolo Gargallo (Sicily–Italy)—Part B: Trace Elements (2023)
    MDPI
    Details
    Publication Date: 2023-08-29
    Description: The concentrations of trace elements in atmospheric bulk depositions (wet plus dry) were investigated from two highly industrialised areas of Sicily (southern Italy) from June 2018 to July 2019, in order to recognise the main natural and anthropogenic sources. A side objective of this study was to improve the common sampling procedures and analytical methods used for monitoring trace elements in atmospheric deposition. The trace element VWM (Volume-Weighted Mean) concentrations ranged from less than 0.01 µg L-1 for trace elements such as Cs, Tl, and U, up to 24 µg L-1 for minor elements (Al, Zn, Sr), in the filtered aliquot, while they reached concentrations up to 144 µg L-1 for the same elements, in the unfiltered aliquot. Therefore, significant differences in concentrations between these two aliquots were found, particularly for Al, Fe, Ti, Zn, Cr, Pb, Se, Cs, and U. This implies that filtering operations may produce a consistent underestimation of concentrations of certain ‘constituents’ of the atmospheric deposition. Natural (marine spray, local and regional geogenic input, volcanic emanations) and anthropogenic sources (industrial emissions, auto vehicular traffic, and diffuse background pollution) which influence rainwater chemistry were identified. Enrichment factors (EFs), with respect to the upper crust composition, provided clear evidence of the different sources above mentioned: Ti, Fe, Al, Cs, Cr, Rb, and Co have low EFs (〈1), and are referable to the (local and/or regional) geogenic input, while Se, Sb, Zn, B, Cd, Cu, Mo, Sr, As, with high EFs (〉10), highlight the influence of marine and/or industrial sources. The study produced a novel dataset on the atmospheric deposition rate of several trace elements, which had never been studied in the investigated areas. Finally, a comparison of trace element deposition rates in the studied areas with the atmospheric deposition reported for 53 different sites, belonging to 20 different European nations, was made. The comparison showed that some elements, such as Al, V, Zn, and Mo had higher median deposition fluxes in the Sicilian sites than in European monitoring sites.
    Description: Published
    Description: 737
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: atmospheric deposition ; rainwater ; industrial pollution ; trace elements ; anthropogenic contribution ; 01.01. Atmosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Characterization of trace elements in thermal and mineral waters of Greece (2023)
    Springer
    Details
    Publication Date: 2023-08-29
    Description: Natural thermal and mineral waters are widely distributed along the Hellenic region and are related to the geodynamic regime of the country. The diverse lithological and tectonic settings they are found in reflect the great variability in their chemical and isotopic composition. The current study presents 276 (published and unpublished) trace element water data and discusses the sources and processes affecting the water by taking into consideration the framework of their geographic distribution. The dataset is divided in groups using temperature- and pH-related criteria. Results yield a wide range of concentrations, often related to the solubility properties of the individual elements and the factors impacting them (i.e. temperature, acidity, redox conditions and salinity). Many elements (e.g. alkalis, Ti, Sr, As and Tl) present a good correlation with temperature, which is in cases impacted by water rock interactions, while others (e.g. Be, Al, Cu, Se, Cd) exhibit either no relation or an inverse correlation with T possibly because they become oversaturated at higher temperatures in solid phases. A moderately constant inverse correlation is noticed for the vast majority of trace elements and pH, whereas no relationship between trace element concentrations and Eh was found. Seawater contamination and water-rock interaction seem to be the main natural processes that influence both salinity and elemental content. All in all, Greek thermomineral waters exceed occasionally the accepted limits representing in such cases serious harm to the environment and probably indirectly (through the water cycle) to human health.
    Description: Published
    Description: 78376–78393
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Greece ; Hydrogeochemistry ; Mineral waters ; Natural contaminants ; Trace elements ; Water-rock interaction ; Thermal waters ; 03.04. Chemical and biological
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
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    Hellenic karst waters: geogenic and anthropogenic processes affecting their geochemistry and quality (2023)
    Nature PG
    Details
    Publication Date: 2023-08-29
    Description: Karst hydrosystems represent one of the largest global drinking water resources, but they are extremely vulnerable to pollution. Climate change, high population density, intensive industrial, and agricultural activities are the principal causes of deterioration, both in terms of quality and quantity, of these resources. Samples from 172 natural karst springs were collected in the whole territory of Greece. To identify any geogenic contamination and/or anthropogenic pollution, analyses of their chemical compositions, in terms of major ions and trace elements, were performed and compared to the EU limits for drinking water. Based on chloride content, the collected karst springs were divided into two groups: low-chloride (〈 100 mg L-1) and high-chloride content (〉 100 mg L-1). An additional group of springs with calcium-sulfate composition was recognised. Nitrate concentrations were always below the EU limit (50 mg L-1), although some springs presented elevated concentrations. High contents in terms of trace elements, such as B, Sr, As, and Pb, sometimes exceeding the limits, were rarely found. The Greek karst waters can still be considered a good quality resource both for human consumption and for agriculture. The main issues derive from seawater intrusion in the aquifers along the coasts. Moreover, the main anthropogenic pollutant is nitrate, found in higher concentrations mostly in the same coastal areas where human activities are concentrated. Finally, high levels of potentially harmful trace elements (e.g. As, Se) are very limited and of natural origin (geothermal activity, ore deposits, etc.).
    Description: Published
    Description: 11191
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Greece ; Hydrogeochemistry ; trace elements ; water quality ; karst springs ; 03.04. Chemical and biological
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
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    Hydrogeochemistry of trace and rare earth elements in the Caviahue-Copahue Volcanic Complex (2024)
    Elsevier
    Details
    Publication Date: 2024-05-16
    Description: The Caviahue-Copahue Volcanic Complex is one of the most studied active volcanic systems in the South American Andean range, and yet little research has focused on trace and rare-earth elements of waters, especially during an eruptive cycle. In this study, we sampled and investigated natural waters from 23 sites (involving the crater lake, hot springs, streams, rivers, and bubbling pools) in two campaigns in 2017 and 2018, using physi cochemical parameters, major, trace and rare-earth elements concentrations. With this novel dataset, it was possible to identify, characterize and compare three groups of waters with distinctive hydrofacies. Indeed, the normalization of water compositions against host rock concentrations showed a particular trace element pattern for each group of waters. Although the absolute concentrations of the elements in each sampling site changed from 2017 to 2018, the normalized patterns did not. Boron, As, Cd, Tl, Se, and Te, commonly recognized as volatile, are the main trace elements that magmatic gases supply to the system headwaters, whereas elements such as Ca, K, and Ba are affected by precipitation of secondary minerals (gypsum, anhydrite, barite, jarosite, and alunite). Furthermore, the main river draining the summit volcano shows a steep decrease in As, Cr, and V concentrations correlated to the precipitation of Fe and Al hydroxysulfates (schwertmannite and basaluminite, respectively). Moreover, it is the first time that a comparison between the different water groups is made using the patterns of the rare-earth elements, allowing us to identify and separate depletion patterns due to dilution processes from those due to precipitation processes.
    Description: Published
    Description: 121602
    Description: JCR Journal
    Keywords: Copahue volcano ; Hydrological system ; Geothermal ; Trace elements ; Rare earth elements
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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