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    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Nanotechnology. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (282 pages)
    Edition: 1st ed.
    ISBN: 9783030049492
    Series Statement: Environmental Chemistry for a Sustainable World Series ; v.31
    DDC: 541.395
    Language: English
    Note: Intro -- Preface -- Contents -- Contributors -- Chapter 1: Nanophotocatalysts for Fuel Production -- 1.1 Introduction -- 1.2 Quantum Dot Semiconductors -- 1.3 Synthesis of Quantum Dots -- 1.4 Application of Quantum Dots for Fuel Production -- 1.5 Conclusion -- References -- Chapter 2: Highly Stable Metal Oxide-Based Heterostructured Photocatalysts for an Efficient Photocatalytic Hydrogen Production -- 2.1 Photocatalysis -- 2.1.1 Photocatalytic Mechanism -- 2.1.2 Band Edge Positions -- 2.2 Semiconducting Metal Oxides for Photocatalytic Water Splitting -- 2.2.1 Metal Oxide-Based Heterostructured Photocatalysts -- 2.2.1.1 Energy Structure of TiO2 -- 2.2.1.2 Lattice Structure of TiO2 -- 2.3 The Challenges in Photocatalytic H2 Production Using TiO2 Particulate Systems -- 2.4 Strategies for Improving TiO2 Photocatalytic Activity -- 2.4.1 Addition of Sacrificial Reagents -- 2.4.2 TiO2-Based Semiconductors Under UV Light Irradiation -- 2.4.3 Photocatalytic Performance of TiO2 Under Visible Irradiation -- 2.4.4 Functionalization of TiO2 with Carbon Nanomaterials -- 2.4.4.1 Carbon Nanotubes -- 2.4.4.2 Graphene Oxide/Reduced Graphene Oxide (RGO) -- 2.5 Future Scope/Conclusions -- References -- Chapter 3: Novelty in Designing of Photocatalysts for Water Splitting and CO2 Reduction -- 3.1 Introduction -- 3.2 CO2 Reduction -- 3.2.1 Principles of CO2 Reduction -- 3.2.2 By-Products of CO2 Reduction -- 3.2.3 Synthesis of Nanoparticles -- 3.2.3.1 Doping of Photocatalyst -- 3.2.4 Commercial Challenges of CO2 Reduction -- 3.3 Water Splitting -- 3.3.1 The Basic Principle of Water Splitting -- 3.3.2 Photocatalyst for Water Splitting -- 3.3.2.1 Oxide-Based Photocatalyst -- 3.3.2.2 Nitride-Based Photocatalyst -- 3.3.3 Commercial Challenges of Water Splitting -- 3.4 Conclusion and Way Forward -- References. , Chapter 4: Z-Scheme Photocatalysts for the Reduction of Carbon Dioxide: Recent Advances and Perspectives -- 4.1 Introduction -- 4.2 Basic Principles of the Z-Scheme Reduction of CO2 -- 4.3 Advances in Z-Scheme Photocatalytic Reduction of CO2 -- 4.3.1 Z-Scheme Systems with Aqueous Shuttle Redox Mediator -- 4.3.2 All-Solid-State Z-Scheme Systems -- 4.3.3 Semiconductor/Metal-Complex Hybrid Z-Scheme Systems -- 4.3.4 Light Harvesting of Photocatalysts Utilized for the Z-Scheme CO2 Reduction -- 4.3.5 Cocatalyst Strategies for Z-Scheme CO2 Reduction -- 4.4 Summary and Outlook -- References -- Chapter 5: Photocatalysts for Artificial Photosynthesis -- 5.1 Introduction -- 5.2 General Photosynthesis Mechanism -- 5.3 Covalently Linked Molecular Systems for Artificial Photosynthesis -- 5.3.1 Porphyrin-Based Donor-Acceptor Molecular Systems -- 5.3.2 Subphthalocyanine-Based Light-Harvesting Complexes -- 5.3.3 BODIPY-Based Light-Harvesting Systems -- 5.4 Supramolecular Artificial Photosynthetic Systems -- 5.4.1 Metal-Ligand Interactions of Porphyrins/Naphthalocyanines with Electron Acceptors -- 5.4.2 Supramolecular Photosynthetic Complexes Via Crown Ether-Ammonium Cation Interactions -- 5.5 Conclusion -- References -- Chapter 6: Polymeric Semiconductors as Efficient Photocatalysts for Water Purification and Solar Hydrogen Production -- 6.1 Introduction -- 6.2 Photocatalysis -- 6.2.1 Basic Principles of Photocatalytic Reaction -- 6.2.2 Photocatalytic Properties -- 6.2.3 Photocatalytic Mechanism -- 6.3 Photocatalytic Functional Materials: Synthesis, Properties and Applications -- 6.3.1 Graphitic Carbon Nitride (g-C3N4) -- 6.3.1.1 Synthesis of Polymeric g-C3N4 -- 6.3.1.2 Photocatalytic Mechanism of g-C3N4 -- 6.3.1.3 Photodegradation of Chemical Pollutants Using g-C3N4 -- 6.3.1.4 Graphene Oxide-Based Hybrid Photocatalysts. , 6.3.2 Metal-Organic Framework (MOF)-Based Photocatalysts -- 6.3.2.1 Principles -- 6.3.2.2 Photocatalytic Applications of MOFs -- 6.3.3 TiO2-Based Hybrid Photocatalysts -- 6.3.3.1 Principles -- 6.3.3.2 Different Forms of TiO2 and Its Physicochemical Properties -- 6.3.3.3 Structure of TiO2 -- 6.3.3.4 Photocatalytic Mechanism of TiO2 -- 6.3.3.5 Hybrid Photocatalysts Based on TiO2 and Organic Conjugated Polymers -- 6.3.3.5.1 Properties of Polythiophene -- 6.3.3.5.2 Properties of Polyaniline -- 6.3.3.5.3 Properties of Polypyrrole -- 6.3.3.5.4 Synthesis of TiO2-Based Hybrid Photocatalysts with Different Organic Conjugated Polymers -- 6.3.3.5.5 Characterization of TiO2/Conjugated Polymer-Based Hybrid Catalysts -- 6.3.3.5.6 Antibacterial Activity of Photocatalysts -- 6.3.3.6 Environmental Application of Different Photocatalysts -- 6.3.3.6.1 Water Purification -- 6.3.4 Graphene Oxide (GO)-Based Photocatalyst for Dye Degradation and H2 Evolution -- 6.3.4.1 Photodegradation of Chemical Pollutants -- 6.3.4.2 Hydrogen (H2) Evolution Reaction by g-C3N4-Based Functional Photocatalysts -- 6.4 Conclusion -- References -- Chapter 7: Advances and Innovations in Photocatalysis -- 7.1 Introduction -- 7.2 Photocatalysts for Hydrogen Production -- 7.2.1 Nature of Different Sacrificial Agents and Typical Mechanism of Photoreforming -- 7.2.1.1 Methanol as a Sacrificial Agent -- 7.2.1.2 Ethanol as a Sacrificial Agent -- 7.2.1.3 Glycerol as a Sacrificial Agent -- 7.2.1.4 Glucose as a Sacrificial Agent -- 7.2.2 Hydrogen Production from Photocatalytic Wastewater Treatment -- 7.3 Photocatalysts Developed for the Synthesis of Organic Compounds in Mild Conditions -- 7.3.1 The Starting Point -- 7.3.2 The Effect of Supporting Metal Oxides on Titania on Selectivity -- 7.3.3 The Effect of Titania Dopant -- 7.3.4 The Effect of Titania Surface Area. , 7.3.5 The Effect of Substituting Titania -- 7.3.6 The Effect of Reactor and Illumination -- 7.3.7 Cyclohexanol and Cyclohexanone by Gas-Phase Photocatalytic Oxidation? -- 7.4 Photocatalytic Membrane Reactors -- 7.5 Concluding Remarks -- References -- Chapter 8: Solar Light Active Nano-photocatalysts -- 8.1 Introduction -- 8.2 Mechanism of Semiconductor-Mediated Photocatalysis -- 8.2.1 Nano-TiO2 as Photocatalysts -- 8.2.2 Nano-ZnO as Photocatalysts -- 8.2.3 Graphitic Carbon Nitride as Photocatalysts -- 8.2.4 Titanates as Photocatalysts -- 8.2.5 Nano-metal Sulphides as Photocatalysts -- 8.3 Strategies for Making Solar/Visible Light Active Photocatalysts -- 8.3.1 Metal/Non-metal Doping -- 8.3.2 Addition of Photosensitive Materials -- 8.3.3 Construction of Heterojunctions/Composites -- 8.3.4 Construction of Nanohybrid Materials -- 8.3.5 Surface Modification -- 8.4 Conclusion -- References -- Chapter 9: High-Performance Photocatalysts for Organic Reactions -- 9.1 Introduction -- 9.2 Photocatalytic Oxidation of Alcohols -- 9.3 Selective Oxidation and Oxidative Coupling of Amines -- 9.4 Photocatalytic Cyanation -- 9.5 Photocatalytic Cycloaddition and C-C Bond Formation Reactions -- 9.6 Miscellaneous Reactions -- 9.7 Outlook -- 9.8 Conclusion -- References -- Index.
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