Keywords:
Electronic books.
Type of Medium:
Online Resource
Pages:
1 online resource (286 pages)
Edition:
1st ed.
ISBN:
9781536147254
Series Statement:
Advances in Chemistry Research Series
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=5683880
Language:
English
Note:
Intro -- Contents -- Preface -- Chapter 1 -- Mass Spectrometric Experimental and Theoretical Quantification of Reaction Kinetics, Thermodynamics and Diffusion of Piperazine Heterocyclics in Solution -- Abstract -- Introduction -- 1. Mass Spectrometric Data -- 1.1. Theoretical Concepts of the Electrospray Ionization Mass Spectrometry -- 1.2. Mass Spectrometric Qualitative Analysis of Nitrogen-Containing Aliphatic Heterocyclics -- 1.3. Mass Spectrometric Reaction Kinetics -- 1.4. Mass Spectrometric Thermodynamics -- 1.5. Mass Spectrometric Diffusion Parameters -- 1.6. Mass Spectrometric Method Performances -- 2. Quantum Chemical Data -- 2.1. Theoretical Thermo Chemistry -- 2.2. Theoretical Diffusion Parameters - A Correlative Analysis with Experiment -- 2.3. Reaction Mechanisms -- 3. Crystallographic Data -- 4. Experimental Section, Theory and Computations -- 4.1. Synthesis -- 4.2. Physical Methods -- 4.3. Computations/Theory -- 4.4. Chemometrics -- Conclusion -- Acknowledgments -- References -- Chapter 2 -- Analytical Techniques for the Assay of Sulfacetamide, Its Degradation Products, and Other Sulfonamides: A Review -- Abstract -- 1. Introduction -- 2. Analytical Techniques -- 2.1. Chromatographic Techniques -- 2.1.1. Paper Chromatography (PC) -- 2.1.2. Thin-Layer Chromatography (TLC) -- 2.1.3. Column Chromatography (CC) -- 2.1.4. Gas Chromatography (GC) -- 2.1.5. High-Performance Liquid Chromatography (HPLC) -- 2.1.6. Sequential Injection Chromatography (SIC) -- 2.1.7. Micellar Electrokinetic Capillary Chromatography (MECC) -- 2.2. Spectrometric Techniques -- 2.2.1. Colorimetry -- 2.2.2. Ultraviolet-Visible (UV-vis) Spectrometry -- 2.2.3. Spectrofluorimetry -- 2.2.4. Infrared (IR) Spectrometry -- 2.2.5. Nuclear Magnetic Resonance (NMR) Spectrometry -- 2.2.6. Mass Spectrometry (MS) -- 2.2.7. Atomic Absorption Spectrometry.
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2.3. Electrochemical Techniques -- 2.3.1. Potentiometric Titration -- 2.3.2. Amperometric Titration -- 2.3.3. Coulometric Titration -- 2.3.4. Voltammetry -- 2.3.5. Differential Pulse Polarography (DPP) -- 2.4. Titrimetric Techniques -- 2.4.1. Diazotization Titration -- 2.4.2. Non-Aqueous Titration -- 2.4.3. Bromometric Titration -- 2.4.4. Complexometric Titration -- 2.5. Miscellaneous Techniques -- 2.5.1. Chemiluminescence Detection -- 2.5.2. Continuous Addition of Reagent (CAR) -- 2.5.3. Supported Liquid Membrane (SLM) Extraction -- 2.5.4. Capillary Zone Electrophoresis (CZE) -- 2.5.5. Thermal Techniques -- Conclusion -- References -- Chapter 3 -- Stereoselective C-Acylation Reactions and Their Applications to Bioactive Compounds -- Abstract -- 1. Introduction -- 2. Diastereoselective Acylation -- 3. Stereoselective Acylation Using Chiral Auxiliaries -- 4. Chiral Acyl Anion Equivalent -- 5. Chiral Acyl Radical Equivalent -- 6. Enantioselective Acylation -- Conclusion -- Acknowledgments -- References -- Biographical Sketch -- Chapter 4 -- Environmentally Benign N-Alkylation of Amines, Ammonia, and Related Compounds Catalyzed by Ir Complexes Using Alcohols as Alkylating Reagents -- Abstract -- 1. Introduction -- 2. Alkylation of Alkyl or Aryl Amines -- 2.1. Intramolecular N-Alkylation for the Synthesis of N-Heterocycles -- 2.2. Intermolecular N-Alkylation -- 2.3. Consecutive Inter/Intramolecular N-Alkylation for the Synthesis of Cyclic Amines -- 3. Alkylation of Other Amine Derivatives -- 3.1. Alkylation Using Ammonium Salts -- 3.2. Alkylation Using Amide, Carbamate, and Sulfonamide -- 4. Recent Advance: Reaction in Water -- Conclusion -- References -- About the Authors -- Contents of Earlier Volumes -- Index -- Blank Page.
