Publication Date:
2018-03-06
Description:
New complexes of hexavalent U, Np, and Pu of the composition [UO 2 (bipy)(cbc) 2 ] ( I ) and [AnO 2 (bipy)(cbc) 2 ]·0.5(bipy) [An = Np ( II ) and Pu ( III )] with cyclobutanecarboxylic acid anions C 4 H 7 COO – and 2,2′-bipyridine (bipy) were synthesized, and their structures were studied. The An atoms in I–III have the coordination surrounding in the form of distorted hexagonal bipyramids with the О atoms of AnO 2 2+ cations in the apical positions. The equatorial plane of the bipyramids is constituted by the O atoms of two C 4 H 7 COO – anions and N atoms of bipy.
Print ISSN:
1066-3622
Electronic ISSN:
1608-3288
Topics:
Chemistry and Pharmacology