In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2019, No. 33 ( 2019-09-08), p. 3769-3775
Abstract:
We report the synthesis, characterization, solid‐state structure and solution behavior of simple lanthanide trifluoromethanesulfonate complexes supported by a hexadentate tetrakis(2‐pyridylmethyl)ethylenediamine ligand. The complexes' solid‐state structures exhibit different trifluoromethanesulfonate coordination, correlating with the size difference of the lanthanide ions. The ligand is capable of sensitizing Nd, Sm, Eu, Tb, Dy, and Yb yielding metal‐centered emission with moderate quantum yields.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2019.33
DOI:
10.1002/ejic.201900609
Language:
English
Publisher:
Wiley
Publication Date:
2019
detail.hit.zdb_id:
1475009-0