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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 305 (1960), S. 274-278 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: In continuation of investigations on tricarbonyl iron compounds of the type [Fe(CO)3X]2 (X = SC2H5, SeC2H5), the dipol moments of the isoelectronic dinitrosyl compounds [Fe(NO)2SC2H5]2 and [Fe(NO)2SeC2H5]2 have been determined. From these a dipol-free model of [Fe(NO)2SeC2H5]2 and of the dinitrosyl cobalt monohalides [Co(NO)2Cl]2 and [Co(NO)2Br]2 containing selenium and halogen bridges, respectively, can be deduced.
    Notes: Im Anschluß an Untersuchungen über Tricarbonyleisenverbindungen des Typs [Fe(CO)3X]2 (X = SC2H5, SeC2H5) wurden auch die Dipolmomente der isoelektronischen Dinitrosylverbindungen [Fe(NO)2SC2H5]2 und [Fe(NO)2SeC2H5]2 bestimmt. Hieraus kann für [Fe(NO)2SeC2H5]2. sowie für die Dinitrosylkobaltmonohalogenide [Co(NO)2Cl]2 und [Co(NO)2Br]2 ein dipolfreies Modell mit Selen- bzw. Halogenbrücken abgeleitet werden.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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