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Synthesis and crystal structure of An(VI) complexes with cyclobutanecarboxylic acid anions and 2,2′-bipyridine [An(VI) = U, Np, Pu] (2018)

Springer

In: Radiochemistry

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Publikationsdatum: 2018-03-06

Beschreibung: New complexes of hexavalent U, Np, and Pu of the composition [UO 2 (bipy)(cbc) 2 ] ( I ) and [AnO 2 (bipy)(cbc) 2 ]·0.5(bipy) [An = Np ( II ) and Pu ( III )] with cyclobutanecarboxylic acid anions C 4 H 7 COO – and 2,2′-bipyridine (bipy) were synthesized, and their structures were studied. The An atoms in I–III have the coordination surrounding in the form of distorted hexagonal bipyramids with the О atoms of AnO 2 2+ cations in the apical positions. The equatorial plane of the bipyramids is constituted by the O atoms of two C 4 H 7 COO – anions and N atoms of bipy.

Print ISSN: 1066-3622

Digitale ISSN: 1608-3288

Thema: Chemie und Pharmazie

Publiziert von Springer

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