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  • 1
    Publikationsdatum: 2023-07-01
    Schlagwort(e): -; Alaska, USA; Area/locality; Carmacks_Yukon; Dawson_Yukon; Depth, bathymetric; Description; Event label; Fairbanks; MULT; Multiple investigations; Name; North_Seaw_Penins; Number; Yukon, Canada, North America; δ13C, carbon dioxide, aquatic; δ13C, carbon dioxide, standard deviation; δ13C, methane; δ13C, methane, standard deviation; δ18O, standard deviation; δ18O, water; δ Deuterium, methane; δ Deuterium, standard deviation; δ Deuterium, water
    Materialart: Dataset
    Format: text/tab-separated-values, 128 data points
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Publikationsdatum: 2023-07-01
    Schlagwort(e): Age, 14C AMS; Age, maximum/old; Age, minimum/young; Alaska, USA; Area/locality; Epoch; Event label; Fairbanks; MULT; Multiple investigations; North_Seaw_Penins; δ18O, water; δ Deuterium, water
    Materialart: Dataset
    Format: text/tab-separated-values, 35 data points
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    facet.materialart.
    Unbekannt
    PANGAEA
    In:  Supplement to: Brosius, Laura Susan; Walter Anthony, Katey M; Grosse, Guido; Chanton, Jeffrey P; Farquharson, Louise M; Overduin, Pier Paul; Meyer, Hanno (2012): Using the deuterium isotope composition of permafrost meltwater to constrain thermokarst lake contributions to atmospheric CH4 during the last deglaciation. Journal of Geophysical Research: Biogeosciences, 117(G1), G01022, https://doi.org/10.1029/2011JG001810
    Publikationsdatum: 2023-12-13
    Beschreibung: Thermokarst lakes are thought to have been an important source of methane (CH4) during the last deglaciation when atmospheric CH4 concentrations increased rapidly. Here we demonstrate that meltwater from permafrost ice serves as an H source to CH4 production in thermokarst lakes, allowing for region-specific reconstructions of dD-CH4 emissions from Siberian and North American lakes. dD CH4 reflects regionally varying dD values of precipitation incorporated into ground ice at the time of its formation. Late Pleistocene-aged permafrost ground ice was the dominant H source to CH4 production in primary thermokarst lakes, whereas Holocene-aged permafrost ground ice contributed H to CH4 production in later generation lakes. We found that Alaskan thermokarst lake dD-CH4 was higher (-334 ± 17 per mil) than Siberian lake dD-CH4 (-381 ± 18 per mil). Weighted mean dD CH4 values for Beringian lakes ranged from -385 per mil to -382 per mil over the deglacial period. Bottom-up estimates suggest that Beringian thermokarst lakes contributed 15 ± 4 Tg CH4 /yr to the atmosphere during the Younger Dryas and 25 ± 5 Tg CH4 /yr during the Preboreal period. These estimates are supported by independent, top-down isotope mass balance calculations based on ice core dD-CH4 and d13C-CH4 records. Both approaches suggest that thermokarst lakes and boreal wetlands together were important sources of deglacial CH4.
    Schlagwort(e): International Polar Year (2007-2008); IPY
    Materialart: Dataset
    Format: application/zip, 2 datasets
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    ISSN: 1745-6584
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Energietechnik , Geologie und Paläontologie
    Notizen: Two experiments were conducted on Long Key, Florida, United States, to examine the fate of waste water following sewage disposal in 10 to 30 m deep injection wells. This waste disposal practice introduces extraordinary amounts of nutrients into the ground water of the Florida Keys. In these experiments, artificial ground water tracers, sulfur hexafluoride (SF6) and radioiodine (131I) were used to determine transport rates and directions of soluble nonreactive substances injected into the saline ground water underlying the Keys. Two types of transport were observed: (1) rapid flow (0.20 to 2.20 m/hr) presumably due to the many conduits present in the limestone; and (2) slower flow (less than 0.003 to 0.14 m/hr) associated with the limestone's primary porosity. Vertical flow was comparable to horizontal flow due to either the density-driven buoyancy of the waste water plume or to preferential flowpaths that allow upward advection or combination of both. These experiments showed that conservative artificial tracers injected into the subsurface reach surface water in a matter of days and can remain in the immediate vicinity of the injection well for several months.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    ISSN: 1520-5126
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 37 (1990), S. 0 
    ISSN: 1365-3091
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Geologie und Paläontologie
    Notizen: Porewaters from a variety of Recent, Pleistocene, and Eocene lithified marine carbonate frameworks displayed similar chemical characteristics: highly depleted concentrations of dissolved oxygen (〉20 μM), elevated levels of dissolved methane (25-5000 nM), and near-seawater sulphate levels. These porewaters also had low pH values (7·5-7·9), and contained elevated concentrations of sulphide (4–10 μM), dissolved inorganic carbon (2·05–2·46 mM), and inorganic nutrients. Hydrocarbon composition data indicate that the methane is biogenic, whereas the methane δ13C values (–47·4 ± 2·7%0) suggest that it has been subject to oxidation. The porewater dissolved inorganic carbon δ13C values varied from –0·6 to –39%0, suggesting input of carbon dioxide from organic matter oxidation. We conclude that anaerobic diagenesis involving bacterial degradation of organic matter is a common process in lithified marine carbonates and hypothesize that it may be an important factor controlling their carbonate geochemistry.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    [s.l.] : Nature Publishing Group
    Nature 349 (1991), S. 229-231 
    ISSN: 1476-4687
    Quelle: Nature Archives 1869 - 2009
    Thema: Biologie , Chemie und Pharmazie , Medizin , Allgemeine Naturwissenschaft , Physik
    Notizen: [Auszug] Dense biological communities living on highly sulphidized sediments found at the 3,280-m-deep base of the Florida escarpment are supported by chemosynthetic processes1'3'4 that use reduced substrates seeping from the highly jointed limestone cliff forming the edge of the Florida platform2'5 (Fig. ...
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 8
    ISSN: 1573-515X
    Schlagwort(e): iron monosulfide ; acid volatile sulfide ; pyrite ; stannous chloride ; sediments
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract Iron monosulfides are important intermediates in pyrite formation, and are operationally defined as sulfides soluble in concentrated hydrochloric acid. A number of variations are currently employed in their isolation and quantification. In this study, the active distillation of acid volatile sulfide from sediment samples was studied to determine the effects of stannous chloride and heat. The addition of SnCl2 caused recovery of sulfide to increase by 20% during distillations performed at room temperature. If distillations with SnCl2 were then heated and boiled, recovery increased by up to 100%. Tests with 98% pure pyrite and elemental sulfur showed that these compounds were reduced to sulfide in solutions of 15% and 20% SnCI2 in boiling 6N HCI, and that these reactions were grain size dependent. The compounds were not significantly reduced by solutions of SnCI2 at room temperature, or by boiling 6N HCl not containing SnCl2.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Biogeochemistry 38 (1997), S. 189-205 
    ISSN: 1573-515X
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract Direct groundwater inputs are receiving increasingattention as a potential source of nutrients and otherdissolved constituents to the coastal ocean. Seepageinto St. George Sound, Florida was measuredextensively from 1992 to 1994 using seepage meters. Spatial and temporal variations were documented alonga 7-km stretch of coastline and up to 1 km from shore. Measurements were made at 3 transects perpendicular toshore and 1 transect parallel to shore. The generalresults indicated that seepage decreased with distancefrom shore (2 of 3 transects), and substantialtemporal and spatial variability was observed inseepage flow from nearshore sediments. In addition,trends in mean monthly integrated seepage rates weresimilar to precipitation patterns measured at a nearbycoastal weather station. Based on these measurements, weestimate that the magnitude of groundwater seepage intothe study area is substantial, representing from 0.23 to4.4 m3 ⋅ sec-1of flow through the sediments, approximately equivalentto a first magnitude spring. Although it is unknown howrepresentative this region is with respect to globalgroundwater discharge, it demonstrates thatgroundwater flow can be as important as riverine andspring discharge in some cases. Our subsurfacedischarge rates suggest groundwater is an importanthydrologic source term for this region and may beimportant to the coastal biogeochemistry as well.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 10
    ISSN: 1573-515X
    Schlagwort(e): methane emissions ; tropical floodplains ; Orinoco River ; floodplain forest ; wetlands
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Geologie und Paläontologie
    Notizen: Abstract Methane emissions were measured over a 17-monthinterval at 21 locations on the Orinoco fringingfloodplain and upper delta (total area,14,000 km2). Emissions totaled 0.17 Tgyr−1, or 7.1 mmol d−1 (114 mg d−1;standard deviation, ±18%) per m2 of watersurface. Ebullition accounted for 65% of emissions. Emission rates were about five times as high forfloodplain forest as for open water or macrophytemats. Emission rates were positively correlated withcarbon content of sediment and amount of methane inthe water column, and negatively correlated withdissolved oxygen, but the correlations were weak. Emission from floodplain soils occurred only when thewater content of soil exceeded 25%, which occurredwithin 20 m of standing water during floodplaindrainage (3 months/yr). Bare soils emitted 60mmol/day per m of shoreline length; soils covered bystranded macrophyte beds emitted five times thisamount. Total emissions were accounted for primarilyby flooded forest (94%); macrophyte mats, open water,and exposed soils made only small contributions. Theflux-weighted mean δ13C for the floodplainwas −62 ± 8‰; for δD the mean was −271 ± 27‰. The δ13C and δD were negativelycorrelated. Overall emission rates were notably lowerthan for the Amazon. The depth and duration offlooding are considerably less for the Orinoco thanfor the Amazon floodplain; oxygen over sediments isthe rule for the Orinoco but not for the Amazon. TheOrinoco data illustrate the difficulty of generalizingemission rates. Current information for tropicalAmerica, including revised estimates for inundatedarea along the Amazon, indicate that methane emissionsfrom tropical floodplains have been overestimated.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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