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  • 1
    Publikationsdatum: 2019-09-23
    Beschreibung: Incorporation of boron into foraminiferal shells is thought to be primarily governed by the carbonate chemistry of the ambient seawater, suggesting that it can be reconstructed from B/Ca ratios. To this end, B/Ca ratios of the benthic foraminifer Planulina wuellerstorfi from South Atlantic core top samples have been analyzed using laser ablation−inductively coupled plasma−mass spectroscopy (LA-ICP-MS) to provide additional information on intratest trace element heterogeneity. Results show that boron is heterogeneously distributed within and between shells, with content variations of approximately ±43% displayed within a single shell. B/Ca is higher in the youngest chambers, opposite to the observed between-chamber variability of Mg/Ca. This may be explained by ontogenetic changes of physiological processes that increase the pH of the calcifying fluid and thus the borate concentration while decreasing Mg/Ca to promote calcification. Despite this heterogeneity, mean B/Ca ratios are positively correlated with the deepwater calcite saturation state (Δ[CO32–]), in line with previous studies. We apply this empirical relationship to reconstruct Δ[CO32–] for the late Pleistocene to Holocene using samples from a depth transect in the equatorial Atlantic. Reconstructed Δ[CO32–] values confirm previous studies suggesting that CaCO3-oversaturated North Atlantic Deep Water was reduced during glacial periods, whereas CaCO3-undersaturated Antarctic Bottom Water expanded vertically and propagated northwards. In summary, our data demonstrate that bulk B/Ca in P. wuellerstorfi reliably reflects variations in Δ[CO32–], despite the strong physiological control of boron incorporation.
    Materialart: Article , PeerReviewed
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  • 2
    Publikationsdatum: 2019-09-23
    Beschreibung: The active continental margin off south-central Chile (36° to 40°S) is transitional between the tectonically erosive, empty-trench margin north of Juan Fernandez Ridge and the accretionary, trench-filled margin south of the Chile Triple Junction. The small width of the presently active accretionary wedge (maximum width of 25 to 50 km) argues for past phases of tectonic erosion. At present, this sector shows indications of contemporaneous accretion, subduction, and underplating of sediment, as well as readjustment of the slope by various mass-wasting processes. In this context, this study aims to examine the Neogene sedimentary processes on the continental margin from dredge samples recovered during R/V SONNE cruise SO161-5 within this transitional domain using lithology, sandstone petrology, shale mineralogy, and analysis of sedimentary structures. Our results yield that the principal transport of material occurs in high-energy turbidity currents and debris flows via submarine canyons deeply cutting the continental slope, whereas sediment on the shelf is transported by strong coast-parallel bottom currents and trapped by submarine canyons cutting into the shelf. A wide range of mass-wasting processes including slumping, debris flows, evolving to low-density turbidity currents and mud flows, rework the slope sediments. In contrast, thick undisturbed sequences of mostly hemipelagic sediments accumulate in active slope basins, which are largely protected from mass movements. XRD analyses revealed early diagenetic lithification and overall burial depths of up to ∼ 230 mbsf, suggesting a shallow-subsurface cycle of sedimentation, subsidence, diagenesis, uplift, erosion, and resedimentation. The composition of sandstones is dominated by volcanic rock fragments of Andean provenance. Along-strike modal changes reflect a southward increase in glacially denudation and rainfall, the combination of which caused more intense erosion of volcanic rocks and exposure, weathering and, as a result, increased fluvial transport of metamorphic and plutonic rocks to the sea.
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  • 3
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    Unbekannt
    AGU (American Geophysical Union)
    In:  Geochemistry, Geophysics, Geosystems, 12 (6). Q06019.
    Publikationsdatum: 2018-03-13
    Beschreibung: The ocean plays a major role in the global carbon cycle, and attempts to reconstruct past changes in the marine carbonate system are increasing. The speciation of dissolved uranium is sensitive to variations in carbonate system parameters, and previous studies have shown that this is recorded in the uranium-to-calcium ratio (U/Ca) of the calcite shells of planktonic foraminifera. Here we test whether U/Ca ratios of deep-sea benthic foraminifera are equally suited as an indicator of the carbonate system. We compare U/Ca in two common benthic foraminifer species (Planulina wuellerstorfi and Cibicidoides mundulus) from South Atlantic core top samples with the calcite saturation state (Δ[CO32−] = [CO32−]in situ − [CO32−]sat) of the ambient seawater and find significant negative correlations for both species. Compared with planktonic foraminifera, the sensitivity of U/Ca in benthic foraminifera to changes in Δ[CO32−] is about 1 order of magnitude higher. Although Δ[CO32−] exerts the dominant control on the average foraminiferal U/Ca, the intertest and intratest variability indicates the presence of additional factors forcing U/Ca.
    Materialart: Article , PeerReviewed
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  • 4
    Publikationsdatum: 2024-02-07
    Beschreibung: A new matrix-matched reference material has been developed – NFHS-2-NP (NIOZ Foraminifera House Standard-2-Nano-Pellet) – with element mass fractions, and isotope ratios resembling that of natural foraminiferal calcium carbonate. A 180–355 µm size fraction of planktic foraminifera was milled to nano-particles and pressed to pellets. We report reference and information values for mass fractions of forty-six elements measured by six laboratories as well as for 87Sr/86Sr (three laboratories), δ13C, δ18O (five laboratories), and 206,207,208Pb/204Pb isotope ratios (one laboratory) determined by ICP-MS, ICP-OES, MC-ICP-MS, IRMS, WD-XRF and TIMS. Inter- and intra-pellet elemental homogeneity was tested using multiple LA-ICP-MS analyses in two laboratories applying spot sizes of 60 and 70 µm. The LA-ICP-MS results for most of the elements relevant as proxies for palaeoclimate research show RSD values 〈 3%, demonstrating a satisfactory homogeneous composition. Homogeneity of 87Sr/86Sr ratios of the pellet was verified by repeated LA-MC-ICP-MS by two laboratories. Information values are reported for Pb isotope ratios and δ13C, δ18O values. The homogeneity for these isotope systems remains to be tested by LA-MC-ICP-MS and SIMS. Overall, our results confirm the suitability of NFHS-2-NP for calibration or monitoring the quality of in situ geochemical techniques.
    Materialart: Article , PeerReviewed
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  • 5
    Publikationsdatum: 2024-02-23
    Beschreibung: The geological record encodes the relationship between climate and atmospheric carbon dioxide (CO 2 ) over long and short timescales, as well as potential drivers of evolutionary transitions. However, reconstructing CO 2 beyond direct measurements requires the use of paleoproxies and herein lies the challenge, as proxies differ in their assumptions, degree of understanding, and even reconstructed values. In this study, we critically evaluated, categorized, and integrated available proxies to create a high-fidelity and transparently constructed atmospheric CO 2 record spanning the past 66 million years. This newly constructed record provides clearer evidence for higher Earth system sensitivity in the past and for the role of CO 2 thresholds in biological and cryosphere evolution. Editor’s summary The concentration of atmospheric carbon dioxide is a fundamental driver of climate, but its value is difficult to determine for times older than the roughly 800,000 years for which ice core records are available. The Cenozoic Carbon dioxide Proxy Integration Project (CenCO2PIP) Consortium assessed a comprehensive collection of proxy determinations to define the atmospheric carbon dioxide record for the past 66 million years. This synthesis provides the most complete record yet available and will help to better establish the role of carbon dioxide in climate, biological, and cryosphere evolution. — H. Jesse Smith
    Materialart: Article , PeerReviewed
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  • 6
    Publikationsdatum: 2023-05-26
    Beschreibung: Workshop report - Bergen, Norway, 4 September 2022 Atmospheric carbon dioxide (CO2) is the key driver of global temperatures over geological time, but calculating the exact sensitivity of Earth’s climate to CO2, and hence the trajectory of anthropogenic climate change, requires accurate quantification of past CO2. Determining past CO2 and fluxes among Earth's carbon reservoirs is difficult, particularly prior to ice-core records of the last 800 kyrs. Attempts have been made to compile multi-proxy atmospheric CO2 proxy data through time (Foster et al. 2017; Hönisch 2021; Rae et al. 2021) which have gained considerable traction, including in the Intergovernmental Panel on Climate Change reports (IPCC 2021). However, many of these compilations can include inaccuracies and apparent contradictions arising from differing assumptions and auxiliary inputs used when translating proxy data to CO2. To move forward as a community, ensuring the robustness of future CO2 data contributions and reducing noise in a crucial dataset, such inconsistencies must be minimized, and uncertainties systematically accounted for (Fig. 1).
    Materialart: Article , NonPeerReviewed
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