Description: Paleoenvironmental studies and climate models demonstrate that fl uvial runoff and moisture availability in the Caribbean hinterland react very sensitively to climatic variations. Late Pleistocene and Holocene climate records document pronounced dry and wet periods over tropical South America mainly caused by shifts of the Intertropical Convergence Zone (ITCZ). However, forcing mechanisms for changes in the ITCZ position remain controversial. Here we present high-resolution foraminiferal Ba/Ca and δ18Oseawater records from a core located within the Orinoco River outfl ow documenting abrupt hydrological changes in the Orinoco catchment area during the deglacial and Holocene. Our data, obtained from the surface-dwelling foraminifera Globigerinoides ruber (pink), show an abrupt increase in Ba/ Ca ratios in the early Holocene, starting ~600 yr after the end of the Younger Dryas (YD) cold interval at ca. 10.8 ka and suggesting a massive reorganization of moisture sources in northern South America. In contrast, the salinity dependent δ18Oseawater from the same samples shows a gradual decrease starting at the end of the YD. The offset of our Ba/Ca peak excludes meltwater release in conjunction with the northern Andean glacier retreat well before the end of the YD as a forcing mechanism. We suggest that the Ba/Ca record documents an abrupt increase in Ba-rich waters of a northern Andean source caused by the insolation-driven shift of the ITCZ and/or enhanced monsoon activity.

Description: The Zambezi deep-sea fan, the largest of its kind along the east African continental margin, is poorly studied to date, despite its potential to record marine and terrestrial climate signals in the southwest Indian Ocean. Therefore, gravity core GeoB 9309-1, retrieved from 1219 m water depth, was investigated for various geophysical (magnetic susceptibility, porosity, colour reflectance) and geochemical (pore water and sediment geochemistry, Fe and P speciation) properties. Onboard and onshore data documented a sulphate/methane transition (SMT) zone at ~ 450–530 cm sediment depth, where the simultaneous consumption of pore water sulphate and methane liberates hydrogen sulphide and bi-carbonate into the pore space. This leads to characteristic changes in the sediment and pore water chemistry, as the reduction of primary Fe (oxyhydr)oxides, the precipitation of Fe sulphides, and the mobilization of Fe (oxyhydr)oxide-bound P. These chemical processes also lead to a marked decrease in magnetic susceptibility. Below the SMT, we find a reduction of porosity, possibly due to pore space cementation by authigenic minerals. Formation of the observed geochemical, magnetic and mineralogical patterns requires a fixation of the SMT at this distinct sediment depth for a considerable time—which we calculated to be ~ 10 000 years assuming steady-state conditions—following a period of rapid upward migration towards this interval. We postulate that the worldwide sea-level rise at the last glacial/interglacial transition (~ 10 000 years B.P.) most probably caused the fixation of the SMT at its present position, through drastically reduced sediment delivery to the deep-sea fan. In addition, we report an internal redistribution of P occurring around the SMT, closely linked to the (de)coupling of sedimentary Fe and P, and leaving a characteristic pattern in the solid P record. By phosphate re-adsorption onto Fe (oxyhydr)oxides above, and formation of authigenic P minerals (e.g. vivianite) below the SMT, deep-sea fan deposits may potentially act as long-term sinks for P.

Description: The Danube deep-sea fan complex in the north-western Black Sea, with its ancient channel-levee systems, hosts multiple bottom-simulating reflections (BSRs) that have been observedin high-resolution reflection seismic data. The multiple BSRs indicate the presence of gas hydrates and free gas. To image the distribution of free gas and gas hydrates on the western flank of the S2 canyon, simultaneously, ocean bottom seismometer (OBS) data and 2-D high-resolution multichannel reflection seismic (HRMRS) data were acquired during the R/V Maria S. Merian (MSM-34) expedition. Along two parallel HRMRS-OBS profiles we recorded the wave field for a wide range of incidence angles. The velocity-structure models for both, P-and S-wave traveltimes, cover a depth down to 1.2 km, providing seismic velocity information below the BSR. For identification of the P-wave phases from OBS to OBS, we aligned the OBS data at zero offset to the 2-D HRMS data at each OBS location. The P-wave velocities show a gradual increase with depth from 1510 m/s directly beneath the seafloor up to 1900 m/s at 1.2 km depth. As the S-waves travel at slower speed than P-waves, S-waves reflection could be traced only in a smallsource-receiver offset with a maximum of ~0.9 km. We assume the reflection horizon to be the point of P-to-S conversion. Seismic S-wave velocities increase from 140 m/s beneath the seafloor up to 860 m/s at 1.2 km depth. These observations allow the determination of the P-to-S-ratio that decreases from 10.6 beneath the seafloor down to 2.2 at 1.2 km depth. The seismic velocities and P-to-S-ratio exclude the presence of gas hydrates above the BSR, but endorse the accumulation of a low concentration of free gas below. The distribution of the gas is predominately controlled by lithology.

Description: R/V METEOR expedition M125 (“SAMBA”) focused on the influence of paleoceanographic changes off NE Brazil on the continental hydrological cycle. For this purpose, we obtained 202 m of gravity (24 stations) and piston cores (9) at seven sections on the shelf and continental slope close to river mouths from Cabo Frio in the south to the Rio Sao Francisco in the north. Coring stations were determined after intensive echosounder surveys (total: 1221 NM). On-board foraminiferal biostratigraphy, as well as color and XRF-scanning already provided first stratigraphic constraints, indicating the preservation of different regional paleoclimatic signals at the respective sections. Based on the preliminary stratigraphy, we retrieved high-resolution archives, covering Holocene sediments on the shelf and late Pleistocene sediments on the slope. These high-resolution archives are complemented by long-term records covering up to 900 ka of continuous sedimentation at deeper sites at smaller rivers. For proxy-calibration and the study of present-day sedimentation dynamics and biogeochemical processes, surface sediments were sampled via multicorer (47), Van Veen Grab (6) and box corer (3). Water samples for determination of the water chemistry (trace elements, stable and radiogenic isotopes) and nutrient composition were retrieved by 55 CTD/Rosette casts. In addition, we run multinet-hauls at seven stations to investigate the planktonic foraminiferal communities in the water column down to 700 m water depth, complemented by filtering water from the ship’s pump twice a day.

Description: Submarine groundwater discharge (SGD) into coastal areas is a common global phenomenon and is rapidly gaining scientific interest due to its influence on marine ecology, the coastal sedimentary environment and its potential as a future freshwater resource. We conducted an integrated study of hydroacoustic surveys combined with geochemical porewater and water column investigations at a well‐known groundwater seep site in Eckernförde Bay (Germany). We aim to better constrain the effects of shallow gas and SGD on high frequency multibeam backscatter data and to present acoustic indications for submarine groundwater discharge. Our high‐quality hydroacoustic data reveal hitherto unknown internal structures within the pockmarks in Eckernförde Bay. Using precisely positioned sediment core samples, our hydroacoustic‐geochemical approach can differentiate intra‐pockmark regimes that were formerly assigned to pockmarks of a different nature. We demonstrate that high‐frequency multibeam data, in particular the backscatter signals, can be used to detect shallow free gas in areas of enhanced groundwater advection in muddy sediments. Intriguingly, our data reveal relatively small (typically 〈15 m across) pockmarks within the much larger, previously mapped, pockmarks. The small pockmarks, which we refer to as “intra‐pockmarks”, have formed due to the localized ascent of gas and groundwater; they manifest themselves as a new type of ‘eyed’ pockmarks, revealed by their acoustic backscatter pattern. Our data suggest that, in organic‐rich muddy sediments, morphological lows combined with a strong multibeam backscatter signal can be indicative of free shallow gas and subsequent advective groundwater flow.

Description: The neodymium isotope proxy has become a valuable tool for the reconstruction of past ocean water mass provenance and mixing. For its accurate application, knowledge about the origin and preservation of Nd in sedimentary archives is crucial. Recently, concerns have emerged regarding the applicability of neodymium isotopes as a conservative palaeo water mass tracer, given potential Nd fluxes from sediments into bottom waters (Abbott et al., 2015a) and inferred relabelling of ocean waters by settling detrital material (Roberts and Piotrowski, 2015). Consequently, a decoupling of water mass provenance and proxy variations may arise. We investigate the mobility of Nd around extreme detrital sedimentation events such as glacial ice rafting pulses and turbidite deposition in the Northeast Atlantic. The constructed records from sediment leachates span extreme Nd isotope variations including volcanic (εNd ∼ 0) and Laurentian (εNd ∼ −27) sources. We find that Nd was released into pore waters from reactive detritus inside some detrital layers during early diagenesis, thereby overprinting any archived bottom water Nd signature and precluding the reconstruction of past water mass provenance during the affected time intervals. However, we do not observe any definite indication of diffusive vertical migration of Nd into adjacent layers. Furthermore, bottom water Nd isotope signatures were not modified to a measurable degree by any potential benthic flux of Nd during the deposition of these detrital sediment layers. Consequently, the Nd isotope composition of the pelagic glacial Northeast Atlantic water masses were resilient to such episodic large detrital fluxes. Apart from extreme local sedimentation events, we confirm the presence of detritally overprinted deep waters north of 47°N during the peak glacial from comparison of Northeast Atlantic depth transects. We furthermore suggest that the sensitivity of deep waters to this overprinting effect increased during periods of reduced Atlantic Meridional Overturning Circulation and elevated ice rafting. Overall, our study demonstrates that a thorough evaluation of the proportion of Nd originating from physical water mass advection versus in situ chemical inputs is crucial for the reliable application of Nd isotopes as a water mass tracer.