Description: Compound-specific radiocarbon dating often requires working with small sample sizes (〈 100 µgC). This makes the radiocarbon dates of biomarker compounds very sensitive to biases caused by extraneous carbon of unknown composition, which is introduced to the samples during processing (i.e., isolating single compounds from a heterogeneous mixture) prior to AMS measurements (procedure blank). Contamination sources include solvents, column bleed (from preparative HPLC and GC), carry-over and atmospheric carbon during combustion and vacuum line handling. Reporting accurate radiocarbon dates thus requires a correction for the procedure blank. We present our approach to assess the F14C and the mass of the blanks introduced during the preparation procedures of lipid biomarkers and lignin phenols. The treatments of these compound classes differ significantly which may lead to different F14Cblank and mblank. In order to assess the procedure blanks, we isolated fatty acids and lignin phenols from differently sized aliquots (20-80 µgC) obtained from standard materials with known F14C. Each compound class was extracted from two standard materials (one fossil, one modern). The measured F14C of the processed aliquots were graphically correlated to 1/mass of the respective sample. For aliquots of both, fossil and modern standard materials, this yielded an inverse linear relationship between the F14C and the sample size. The intercept of the regression lines obtained from the aliquots of fossil and modern standards is used to infer F14Cblank and mblank. The uncertainties of F14Cblank (σF14Cblank) and mblank (σmblank) were determined by the regression coefficients R2 of the linear regressions. Assuming constant contamination during processing of individual samples, the F14Cblank and mblank can be used to correct AMS results of lignin and lipid samples by isotopic mass balance.

Description: The last deglaciation was characterized by rising concentration in atmospheric CO2 (CO2atm) and a decrease in its radiocarbon content (Δ14Catm). Mobilization of 14C-depleted terrestrial organic carbon, which was previously frozen in extensive boreal permafrost soils, might have contributed to both changes, and was potentially caused by coastal erosion during deglacial sea-level rise and warming. Since parts of this potentially mobilized organic carbon was reburied in marine sediments, records of accumulation of terrigenous biomarkers and their compound-specific radiocarbon ages can provide insights into the timing and controls on permafrost decomposition. We present data from three marine sediment cores, two cores off the Amur River draining into the Sea of Okhotsk, and one core from the Northeastern Bering Sea adjacent to the Bering shelf (one the largest shelf areas flooded during the deglaciation) receiving input from the Yukon River. During the Last Glacial Maximum all catchments were completely covered with permafrost. Today, the Amur drainage basin is free of permafrost while the Yukon catchment is covered by discontinuous permafrost. All sites show three distinct deglacial maxima (at 16.5, 14.5, 11.5 ka BP) in accumulation of old terrigenous biomarkers (5-20 kyr old at the time of deposition). The peaks occurred during meltwater pulses suggesting that sea-level rise remobilized old terrestrial carbon from permafrost on the flooded shelfs. In the Bering Sea fossil, mature organic matter, mobilized by erosion of organic rich rocks during the retreat of Brooks Range glaciers and the Laurentide ice sheet additionally contributed to the first peak via increased fluvial runoff. Deglacial changes in abundance ratios of long-chain n-alkanes record gradual changes in vegetation type and wetland extent in the Amur-river catchment. Since wetland expansion is closely linked to permafrost thaw this implies that permafrost decomposition in the Amur drainage basin was a gradual process. By contrast sea-level rise caused abrupt decomposition events across the Okhotsk and Bering Shelfs. We extrapolate our localized findings to an overall potential carbon release during deglaciation of 285 PgC from coastal erosion in the Arctic Ocean and the related permafrost decomposition. By analysing some idealized scenarios using the global carbon cycle model BICYCLE we estimate the impact of such a release on the atmosphere. We find that it might have accounted for a deglacial rise in CO2atm of up to 15 ppm, and to a decline in ∆14Catm of 15‰. These results, if restricted to the three peak events connected to rapid sea-level rise, as supported by our data, might have contributed particularly to abrupt changes in CO2atm and ∆14Catm, corresponding to 15-20% of both, the observed rise in CO2atm of ~90 ppm, and the residual in ∆14Catm that is unexplained by changes in the 14C production rate.

Description: In November 2016, the first Mini-Carbon-Dating-System (MICADAS) manufactured by Ionplus AG was delivered and installed at the Alfred-Wegener-Institute (AWI), Germany. The new facility includes a graphitization unit (AGE3) connected with an elementar analyser (EA), a carbonate handling system (CHS), and a gas inlet system (GIS). The main goal for the facility at AWI will be the precise and independent dating of carbonaceous materials in marine sediments, sea-ice, and water to address various processes of the global carbon cycling. A particular focus will be on sediments from the high latitude oceans, in which radiocarbon-based age models are often difficult to obtain due to the scarcity of carbonate microfossils. One advantage of the MICADAS is the potential to analyse samples, which contain only a small amount of carbon as CO2 gas. For example, it will be possible to determine 14C ages of samples of foraminifera from carbonate-lean sediments, allowing for paleoclimate reconstructions in key locations for Earth’s climate system such as the Southern ocean. Likewise, compound-specific 14C analyses receive growing attention in carbon cycle studies and require handling of small samples of typically 〈100µg carbon. The wide range of applications encompassing gas analyses of foraminifera and compound-specific analysis as well as analyses of graphite targets requires establishing routine protocols of various methods of sample preparation, as well as thorough assessment of the respective carbon blanks. We report on our standard procedures for samples of organic matter from sediments or water including carbonate removal, combustion and graphitization using the AGE3 coupled to the EA, as well as on the methodology applied for carbonate samples using the CHS system and the GIS. We have investigated different sample preparation protocols and present the initial results using materials of known age. Additionally, we present the first results of our assessment of process blanks.

Description: Compound-specific radiocarbon (14C) dating often requires working with small samples of 〈 100 μg carbon (μgC). This makes the radiocarbon dates of biomarker compounds very sensitive to biases caused by extraneous carbon of unknown composition, a procedural blank, which is introduced to the samples during the steps necessary to prepare a sample for radiocarbon analysis by accelerator mass spectrometry (i.e., isolating single compounds from a heterogeneous mixture, combustion, gas purification and graphitization). Reporting accurate radiocarbon dates thus requires a correction for the procedural blank. We present our approach to assess the fraction modern carbon (F14C) and the mass of the procedural blanks introduced during the preparation procedures of lipid biomarkers (i.e. n-alkanoic acids) and lignin phenols. We isolated differently sized aliquots (6–151 μgC) of n-alkanoic acids and lignin phenols obtained from standard materials with known F14C values. Each compound class was extracted from two standard materials (one fossil, one modern) and purified using the same procedures as for natural samples of unknown F14C. There is an inverse linear relationship between the measured F14C values of the processed aliquots and their mass, which suggests constant contamination during processing of individual samples. We use Bayesian methods to fit linear regression lines between F14C and 1/mass for the fossil and modern standards. The intersection points of these lines are used to infer F14Cblank and mblank and their associated uncertainties. We estimate 4.88 ± 0.69 μgC of procedural blank with F14C of 0.714 ± 0.077 for n-alkanoic acids, and 0.90 ± 0.23 μgC of procedural blank with F14C of 0.813 ± 0.155 for lignin phenols. These F14Cblank and mblank can be used to correct AMS results of lipid and lignin samples by isotopic mass balance. This method may serve as a standardized procedure for blank assessment in small-scale radiocarbon analysis.

Description: In times of global warming a profound understanding of the climate system is necessary to develop mitigation strategies. Studying episodes of climate change during the Earth’s history (e.g. Glacial-Interglacial cycles) allows insights into the climate system and its feedback processes. In the subarctic Northwest Pacific (NW Pacific) and adjacent Northeast Siberia (NE Siberia) mean climate changes between the Last Glacial Maximum and the Holocene are poorly understood since climate records (e.g. temperature records) spanning the full LGM-Holocene transition are sparse. This thesis shall contribute to a better understanding of climate and environmental change since the LGM and the controlling mechanisms in the region by investigating the development of temperature, glaciation and export of terrigenous organic matter into the North Pacific (N Pacific). Biomarkers in sediment cores from the Western Bering Sea and the NW Pacific/continental margin off Siberia are applied as palaeoclimate archives. In the first part of the thesis LGM-to-Holocene sea surface temperature (SST) records for the marginal Northwest Pacific and the Western Bering Sea are established using the TEXL86 (Tetraether IndeX)-SST proxy. It focusses on the LGM and the early deglaciation since existing deglacial SST records from the region do not reach beyond 15 ka BP. TEXL86-based SSTs in both settings closely follow millennial-scale climate fluctuations known from Greenland ice-cores until 15 ka BP, confirming other SST-records from the region which point to rapid atmospheric teleconnections with abrupt climate changes in the North Atlantic (N Atlantic). During Heinrich Stadial 1 (HS1), Western Bering Sea SSTs decline, similar to the N Atlantic realm, suggesting the Bering Sea was connected to the N Atlantic climate change. Progressively rising SSTs in the NW Pacific differ from the Western Bering Sea and the N Atlantic climate. Similarities between the climate in the Gulf of Alaska and the NW Pacific suggest that the Alaskan Stream accumulated in the NW Pacific during the LGM connecting the climates of the eastern and western N Pacific. Deviating trends in the climate from 12-10 ka onwards point to reduced influence of the Alaskan Stream in the NW Pacific and the end of the oceanic linkage. The second part of the thesis investigates the LGM-to-Holocene evolution of mean air temperature (MAT) of the Kamchatka Peninsula. Climate archives, existing in Kamchatka, do not reach beyond 12 ka BP, so the climate evolution since the LGM is fairly unknown. Using the CBT/MBT’-palaeothermometry (Cyclisation of Branched Tetreathers and the Methylation of Branched Tetraethers indices) a continuous record in summer MAT is provided for the past 20 ka. It is found that glacial summers were as warm as at present. This is in line with summer conditions in continental Siberia but contrasts with the SST-development of the surrounding seas. Likely, strong southerly winds, associated with a pronounced North Pacific High pressure system (NPH) over the subarctic NW Pacific, accounted for the warm conditions on Kamchatka. A comparison with an Earth System Model reveals discrepancies between proxy-based inferences for temperature and atmospheric circulation. The deglacial temperature development was characterized by abrupt millennial-scale temperature oscillations. The Bølling/Allerød warm-phase (B/A) and the Younger Dryas cold-spell (YD) are pronounced events, providing evidence for a strong impact of N Atlantic climate variability on southeastern Siberia, at least during the past 15 ka BP. During HS1, similarities with the NW Pacific SST imply that the Alaskan Stream determined temperature change on the Peninsula rather than teleconnections with the N Atlantic. Considering that NE-Siberian glaciation is supposed to have been more extensive than at present but restricted to mountain ranges during the LGM, the warm glacial-summers of Siberia suggest that summer temperature may have been an important limiting factor for ice sheet growth in the region. In the third part of the thesis, mass balance calculations for the LGM-glaciers on Kamchatka and the Kankaren Range (NE Siberia) are performed by degree-day-modelling in order to estimate the precipitation needed to sustain the glaciers under warm summer conditions. It is found that precipitation at least must have equaled or even exceeded the modern average. The precipitation estimates confirm the hypothesis that summer temperature limited ice-sheet expansion in NE Russia during the LGM, thereby countering the prevailing view that increased aridity (relative to present) hampered ice-sheet growth. The fourth part of the thesis contributes to an ongoing debate about the sources of old, (14C-depleted) carbon dioxide (CO2) which increased atmospheric CO2-levels (CO2atm) and concurrently decreased the atmospheric radiocarbon signature (Δ14Catm) during the deglaciation. Permafrost-decomposition in the Northern Hemisphere (NH) triggered by deglacial warming and sea-level rise is considered as one possible source of 14C-depleted CO2, particularly at the onset of the B/A-interstadial (14.6 ka BP). However, the timing of carbon mobilization in permafrost areas of the NH is underconstrained. In order to investigate the potential role of permafrost decomposition in the subarctic N Pacific realm in the atmospheric, changes mass accumulation rates and the radiocarbon signature (Δ14C) of leaf-wax lipids are analyzed in order to identify intervals of intensified export of 14C-depleted terrigenous OM into the Western Bering Sea and the NW Pacific. Enhanced burial of nearly 14C-free carbon commenced during the HS1 and was likely triggered by increased runoff in the Yukon River due to retreating American ice-sheets. Since the B/A mobilization of 14C-depleted seems to have been dominantly controlled by sea-level rise and thus by erosion of permafrost-covered shelves. Enhanced OM-export associated with permafrost-thaw on Kamchatka likely initiated during the second half of the B/A-interstadial and peaked during the YD-stadial. Lagging the rapid CO2atm/Δ14Catm changes at 14.6 ka BP, the permafrost degradation in the Kamchatka region was probably irrelevant for the atmosphere. Instead, enhanced OM-export in the region coincided with abrupt CO2atm/Δ14Catm changes during the YD suggesting that permafrost may have contributed to the atmospheric carbon-pool at that time.

Description: It has been proposed that North Pacific sea surface temperature (SST) evolution was intimately linked to North Atlantic climate oscillations during the last glacial-interglacial transition. However, during the early deglaciation and the Last Glacial Maximum, the SST development in the subarctic northwest Pacific and the Bering Sea is poorly constrained as most existing deglacial SST records are based on alkenone paleothermometry, which is limited prior to 15 ka B.P. in the subarctic North Pacific realm. By applying the TEXL86 temperature proxy we obtain glacial-Holocene-SST records for the marginal northwest Pacific and the Western Bering Sea. Our TEXL86-based records and existing alkenone data suggest that during the past 15.5 ka, SSTs in the northwest Pacific and the Western Bering Sea closely followed millennial-scale climate fluctuations known from Greenland ice cores, indicating rapid atmospheric teleconnections with abrupt climate changes in the North Atlantic. Our SST reconstructions indicate that in the Western Bering Sea SSTs drop significantly during Heinrich Stadial 1 (HS1), similar to the known North Atlantic climate history. In contrast, progressively rising SST in the northwest Pacific is different to the North Atlantic climate development during HS1. Similarities between the northwest Pacific SST and climate records from the Gulf of Alaska point to a stronger influence of Alaskan Stream waters connecting the eastern and western basin of the North Pacific during this time. During the Holocene, dissimilar climate trends point to reduced influence of the Alaskan Stream in the northwest Pacific.

Description: During the last glacial termination atmospheric carbon dioxide (CO2atm) rose about 100 ppm and atmospheric radiocarbon activity (Δ14C) concurrently dropped by about ca. 400 ‰. Global warming likely triggered large-scale thawing of permafrost soils in the northern hemisphere resulting in release of 14C-depleted carbon which may have contributed to the changes in CO2atm and Δ14C1. However, the timing and duration of the thawing as well as regional differences regarding these points are poorly understood. In order to unravel the evolution of permafrost decomposition and its role within the glacial-interglacial climate change a profound understanding of the deglacial carbon-turnover and temperature development in subarctic and arctic regions are of great importance. Working with two sediment cores from the continental margin off Kamchatka Peninsula, western Bering Sea (WBS, site SO201-2-114KL) & Northwest Pacific (NW Pacific, site SO201-2-12KL) we establish Glacial to Holocene records in sea surface temperature (SST) and mean air temperature (MAT) using the TEXL86 (SST) and CBT/MBT (MAT) temperature proxies that are based on marine and terrigenous biomarkers (Glycerol dialkyl glycerol tetraethers). The hydrogen isotopic composition (δD) of plant-wax derived lipid biomarkers (long-chain n-alkanes and long-chain n-fatty acids) is another tool for reconstructing air temperature but can also provide information of the provenance of terrigenous organic matter (OM). The radiocarbon activity of the lipid biomarkers is applied to reconstruct changes in terrestrial residence times of terrigenous OM. Our records in SST and CBT/MBT-based MAT are interpreted as summer temperatures. From the Bølling/Allerød interstadial (B/A) to the present they show temperature fluctuations similar to Greenland ice core records including a warming at the onset of the B/A and a cooling during the Younger Dryas (YD) followed by a warming into the Preboreal (PB) suggesting an atmospheric coupling between N-Atlantic and N-Pacific, East Siberian/Kamchatka temperature development. However, during Heinrich Stadial 1 (HS1) where WBS SST and Kamchatka MAT cool down synchronously with Greenland temperatures, the NW-Pacific SST rises gradually and seems to be decoupled from the N-Atlantic. Since the gradual warming trend and the subsequent synchronization with Greenland ice core data during B/A is known from SST records from the Gulf of Alaska2 (GOA) surface conditions in the NW Pacific likely are controlled by the Alaskan Stream overprinting the atmospheric effect and the influence of the East Kamchatka Current. Asynchronous development of our TEXL86 record and the GOA records during the Holocene indicate that the AS weakenes over the deglaciation. For the time-span of the Last Glacial Maximum to the onset of the B/A interstadial, the CBT/MBT temperature proxy may be seasonally biased as it produces improbably high summer temperatures that level Holocene conditions. In contrast to the CBT/MBT-based temperatures the δD of n-fatty acids does not show clear stadial-interstadial fluctuations and remains on a stable level during the deglaciation instead. During the Holocene, δD increases progressively, which may have resulted from a gradual warming trend. Comparing the radiocarbon activity of the n-fatty acids to the Δ14C-signature of the atmosphere at the time of deposition the dimension of the terrestrial residence time prior to the deposition (ΔΔ14C) can be estimated. High ΔΔ14C values during deglaciation indicate that the plat-wax biomarkers are strongly pre-aged which may bias the δD-temperature record. Gradually decreasing ΔΔ14C imply declining terrestrial residence times from late glacial to late Holocene and argue for major changes in the relative contribution of weakly and strongly pre-aged OM. Possible sources for strongly pre-aged OM include permafrost decomposition and the congruent mobilization of 14C-depleted carbon but also the erosion of basal tills from the North-American or Kamchatka ice sheets that bear OM dating back to times prior to the glaciation. The n-C25/n-C25+n-C27 ratio, an indicator for the relative contribution of sphagnum spp.3, is on a stable level over most parts of the deglaciation indicating a constant composition of the vegetation and/or a constant carbon source. Between 16.5-14.6 kaBP the record shows a sharp excursions towards higher values congruent with a sharp increase in the δD of n-alkanes that is not evident in the δD of n-fatty acids. Coevally, lowered CPI-values (carbon preference index) point to a major contribution of fossil carbon at that time. Thus, our sites may be subject to a change in the carbon source. It coincides with melting events of the N-American ice sheets4 which may indicate that large amounts of OM from eastern Beringia accumulated in the WBS/NW Pacific during HS1. 1. S. A. Zimov, E. A. G.Schuur & F. S. Chapin III (2006). Permafrost and the global carbon budget.- Science, 312, p. 1612-1613 2. J. E. Vonk & Ö. Gustaffsson (2009). Calibrating n-alkanes Sphagnum proxies in sub-Arctic Scandinavia.- Organic Geochemistry, 40, p. 1085-1090. 3. S. K. Praetorius & A. C. Mix (2014). Synchronization of North Pacific and Greenland climates preceded abrupt deglacial warming.- Science, 345, p. 444-448. 4. I. L. Hendy & T. Cosma (2009).Vulnerability of the Cordilleran Ice Sheet to iceberg calving during late Quaternary rapid climate change events.- Paleoceanography, 23, p. PA2101

Description: The Northern Bay of Bengal (NBoB) is a globally important region for deep-sea organic matter (OM) deposition due to massive fluvial discharge from the Ganges-Brahmaputra-Meghna (G-B-M) rivers and moderate to high surface productivity. Previous studies have focused on carbon burial in turbiditic sediments of the Bengal Fan. However, little is known about the storage of carbon in pelagic and hemipelagic sediments of the Bay of Bengal over millennial time scales. This study presents a comprehensive history of OM origin and fate as well as a quantification of carbon sediment storage in the Eastern Bengal Slope (EBS) during the last 18 ka. Bulk organic proxies (TOC, TIC, TN, δ13CTOC, δ15NTN) and content and composition of total hydrolysable amino acids (THAA) in a sediment core (SO188-342KL) from the EBS were analyzed. Three periods of high OM accumulation were identified: the Late Glacial (LG), the Bölling/Alleröd (B/A), and the Early Holocene Climatic Optimum (EHCO). Lower eustatic sea level before 15 ka BP allowed a closer connection between the EBS and the fluvial debouch, favoring high terrestrial OM input to the core site. This connection was progressively lost between 15 and 7 ka BP as sea level rose to its present height and terrestrial OM input decreased considerably. Export and preservation of marine OM was stimulated during periods of summer monsoon intensification (B/A and EHCO) as a consequence of higher surface productivity enhanced by cyclonic-eddy nutrient pumping and fluvial nutrient delivery into the photic zone. Changes in the THAA composition indicate that the marine plankton community structure shifted from calcareous-dominated before 13 ka BP to siliceous-dominated afterwards. They also indicate that the relative proportion of marine versus terrestrial OM deposited at site 342KL was primarily driven by relative sea level and enlarged during the Holocene. The ballasting effect of lithogenic particles during periods of high coastal proximity and/or enhanced fluvial discharge promoted the export and preservation of OM. The high organic carbon accumulation rates in the EBS during the LG (18–17 ka BP) were 5-fold higher than at present and comparable to those of glacial upwelling areas. Despite the differences in sediment and OM transport and storage among the Western and Eastern sectors of the NBoB, this region remains important for global carbon sequestration during sea level low-stands. In addition, the summer monsoon was a key promotor of terrestrial and marine OM export to the deep-ocean, highlighting its relevance as regulator of the global carbon budget.

Description: The Indian Summer Monsoon (ISM) is a major global climatic phenomenon. Long-term precipitation proxy records of the ISM, however, are often fragmented and discontinuous, impeding an estimation of the magnitude of precipitation variability from the Last Glacial to the present. To improve our understanding of past ISM variability, we provide a continuous reconstructed record of precipitation and continental vegetation changes from the lower Ganges-Brahmaputra-Meghna catchment and the Indo-Burman ranges over the last 18,000 years (18 ka). The records derive from a marine sediment core from the northern Bay of Bengal (NBoB), and are complemented by numerical model results of spatial moisture transport and precipitation distribution over the Bengal region. The isotopic composition of terrestrial plant waxes (dD and d13C of n-alkanes) are compared to results from an isotope-enabled general atmospheric circulation model (IsoCAM) for selected time slices (pre-industrial, mid-Holocene and Heinrich Stadial 1). Comparison of proxy and model results indicate that past changes in the dD of precipitation and plant waxes were mainly driven by the amount effect, and strongly influenced by ISM rainfall. Maximum precipitation is detected for the Early Holocene Climatic Optimum (EHCO; 10.5 - 6 ka BP), whereas minimum precipitation occurred during the Heinrich Stadial 1 (HS1; 16.9 - 15.4 ka BP). The IsoCAM model results support the hypothesis of a constant moisture source (i.e. the NBoB) throughout the study period. Relative to the pre-industrial period the model reconstructions show 20% more rain during the mid-Holocene (6 ka BP) and 20% less rain during the Heinrich Stadial 1 (HS1), respectively. A shift from C4-plant dominated ecosystems during the glacial to subsequent C3/C4-mixed ones during the interglacial took place. Vegetation changes were predominantly driven by precipitation variability, as evidenced by the significant correlation between the dD and d13C alkane records. When compared to other records across the ISM domain, precipitation and vegetation changes inferred from our records and the numerical model results provide evidence for a coherent regional variability of the ISM from the Last Glacial to the present.

Description: Polar regions are strongly affected by global climate change since warming is projected to be strongest in high latitudes. Understanding temperature changes is crucial to unravel the impact of climate change there. Rising sea surface temperatures (SST) modify oceanographic conditions of the polar and subpolar seas. In the northern hemisphere, increasing mean annual air temperatures (MAAT) lead to thawing of permafrost soils which may initiate release of vast amounts of fossil carbon to the environment. In order to study changes in SST, MAAT and the intensity of carbon export from East Siberia to the adjacent NW Pacific and Bering Sea over the last deglaciation we analyzed terrigenous and marine biomarkers (n-alkanes, branched GDGT & isoprenoid GDGTs) from two sediment cores recovered at the continental margin off Kamchatka peninsula (NW Pacific), and from the western Bering Sea. We test the applicability of TEX86 as a tool for SST-reconstructions over the last deglaciation and thereby produce a TEX86 based SST-record in the Bering Sea. The results are compared to Uk’37 and Mg/Ca based SST. The TEX86 record is interpreted to reflect summer subsurface temperatures. We further investigate the CBT/MBT indices calculated from the branched GDGTs as well as δD of n-alkanes as tools for the reconstruction of MAAT. MAAT based on CBT/MBT shows a pattern similar to Greenland ice core temperature records with cooling events during the Heinrich Event 1 (HE1) and the Younger Dryas (YD). The results for the late Holocene match the modern MAAT of Kamchatka peninsula. However, from the Last Glacial Maximum to the onset of the Bølling/Allerød interstadial (B/A) CBT/MBT produces unrealistic temperatures that are as high as during Holocene. Possibly the record shows summer temperatures during LGM and the early deglaciation and reflects the annual mean at the beginning of the B/A. When interpreting these findings one has to keep in mind that concentrations of branched GDGT are very low (BIT lower than 0.1). Thus it is questionable whether CBT/MBT can be used as temperature proxy since the signal may be affected by in-situ production. In contrast to the CBT/MBT our δD records have hardly no similarity with Greenland ice core data. The B/A does not differ from LGM conditions but there is a slight decrease during YD. While the record of the Bering Sea shows an abrupt increase of 40 ‰ during the early Holocene the NW-Pacific shows a gradual increase of the same magnitude over the whole Holocene period. During the HE1 both records show a sharp increase reaching the Holocene level. This indicates interglacial-like temperatures which is unrealistic for stadial conditions. Coeval changes in the CPI and n-C23/n-C27 indicate that δD is overprinted by a change in the carbon source. Potential explanations include redeposition of material mobilized during deglacial sea-level rise, or release of fossil carbon from permafrost. Terrigenous biomarkers were quantified and used to study the history of carbon export. Accumulation rates of n-alkanes and branched GDGT increase during the YD and are strikingly high during the Preboreal indicating enhanced carbon mobilization. Decomposing permafrost soils in East Siberia and on the Kamchatka peninsula is a likely carbon source.