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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2014. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Quaternary Science Reviews 121 (2015): 89-97, doi:10.1016/j.quascirev.2015.05.020.
    Description: Warming over Mongolia and adjacent Central Asia has been unusually rapid over the past few decades, particularly in the summer, with surface temperature anomalies higher than for much of the globe. With few temperature station records available in this remote region prior to the 1950s, paleoclimatic data must be used to understand annual-to-centennial scale climate variability, to local response to large-scale forcing mechanisms, and the significance of major features of the past millennium such as the Medieval Climate Anomaly (MCA) and Little Ice Age (LIA) both of which can vary globally. Here we use an extensive collection of living and subfossil wood samples from temperature-sensitive trees to produce a millennial-length, validated reconstruction of summer temperatures for Mongolia and Central Asia from 931 to 2005 CE. This tree-ring reconstruction shows general agreement with the MCA (warming) and LIA (cooling) trends, a significant volcanic signature, and warming in the 20th and 21st Century. Recent warming (2000-2005) exceeds that from any other time and is concurrent with, and likely exacerbated, the impact of extreme drought (1999-2002) that resulted in massive livestock loss across Mongolia.
    Description: This research was supported by the National Science Foundation under grants AGS-PRF #1137729, ATM0117442, and AGS0402474.
    Keywords: Mongolia ; Temperature ; Tree-ring ; Dendrochronology ; Reconstruction ; Global warming
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 4 (1991), S. 714-720 
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Three useful procedures for estimating the thermodynamic stability and charge distribution of moderately complex unknown species are illustrated by the successive nitration of cubane. (1) Five different, but interrelated, energy criteria are employed, which leads to mutually supportive conclusions that overcome deficiencies in any one of the single measures. (2) Mulliken charge and overlap populations can lead to correct bond strength trends if appropriate averaging over bond types is carried out. (3) Lewis - Langmuir atomic charges, an interpolation between the formal charges of Lewis dot structures and oxidation numbers which does not require use of computers, provides atomic charges similar to those from ab initio, wavefunctions. The simplicity of this scheme aids in identifying the chemical and topological origin of molecular charge distributions. Ab initio, calculations for the strain energies and heats of reaction for four different reaction sequences are reported, together with Mulliken atomic charges and overlap populations for the nitrocubanes. Trends in these measures suggest that hexa- and octa-nitrocubane are thermodynamically stable species.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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