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  • 1
    Online-Ressource
    Online-Ressource
    Newark :John Wiley & Sons, Incorporated,
    Schlagwort(e): Nanostructured materials. ; Electronic books.
    Materialart: Online-Ressource
    Seiten: 1 online resource (491 pages)
    Ausgabe: 1st ed.
    ISBN: 9781119651161
    Sprache: Englisch
    Anmerkung: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 Application of MOFs and Their Derived Materials in Sensors -- 1.1 Introduction -- 1.2 Application of MOFs and Their Derived Materials in Sensors -- 1.2.1 Optical Sensor -- 1.2.1.1 Colorimetric Sensor -- 1.2.1.2 Fluorescence Sensor -- 1.2.1.3 Chemiluminescent Sensor -- 1.2.2 Electrochemical Sensor -- 1.2.2.1 Amperometric Sensor -- 1.2.2.2 Impedimetric, Electrochemiluminescence, and Photoelectrochemical Sensor -- 1.2.3 Field-Effect Transistor Sensor -- 1.2.4 Mass-Sensitive Sensor -- 1.3 Conclusion -- Acknowledgments -- References -- Chapter 2 Applications of Metal-Organic Frameworks (MOFs) and Their Derivatives in Piezo/Ferroelectrics -- 2.1 Introduction -- 2.1.1 Brief Introduction to Piezo/Ferroelectricity -- 2.2 Fundamentals of Piezo/Ferroelectricity -- 2.3 Metal-Organic Frameworks for Piezo/ Ferroelectricity -- 2.4 Ferro/Piezoelectric Behavior of Various MOFs -- 2.5 Conclusion -- References -- Chapter 3 Fabrication and Functionalization Strategies of MOFs and Their Derived Materials "MOF Architecture" -- 3.1 Introduction -- 3.2 Fabrication and Functionalization of MOFs -- 3.2.1 Metal Nodes -- 3.2.2 Organic Linkers -- 3.2.3 Secondary Building Units -- 3.2.4 Synthesis Methods -- 3.2.4.1 Hydrothermal and Solvothermal Method -- 3.2.4.2 Microwave Synthesis -- 3.2.4.3 Electrochemical Method -- 3.2.4.4 Mechanochemical Synthesis -- 3.2.4.5 Sonochemical (Ultrasonic Assisted) Method -- 3.2.4.6 Diffusion Method -- 3.2.4.7 Template Method -- 3.2.5 Synthesis Strategies -- 3.3 MOF Derived Materials -- 3.4 Conclusion -- References -- Chapter 4 Application of MOFs and Their Derived Materials in Molecular Transport -- 4.1 Introduction -- 4.2 MOFs as Nanocarriers for Membrane Transport -- 4.2.1 MIL-89 -- 4.2.2 MIL-88A -- 4.2.3 MIL-100 -- 4.2.4 MIL-101 -- 4.2.5 MIL-53 -- 4.2.6 ZIF-8. , 4.2.7 Zn-TATAT -- 4.2.8 BioMOF-1 (Zn) -- 4.2.9 UiO (Zr) -- 4.3 Conclusion -- References -- Chapter 5 Role of MOFs as Electro/-Organic Catalysts -- 5.1 What Is MOFs -- 5.2 MOFs as Electrocatalyst in Sensing Applications -- 5.3 MOFs as Organic Catalysts in Organic Transformations -- 5.4 Conclusion and Future Prospects -- References -- Chapter 6 Application of MOFs and Their Derived Materials in Batteries -- 6.1 Introduction -- 6.2 Metal-Organic Frameworks -- 6.2.1 Classification and Properties of Metal-Organic Frameworks -- 6.2.2 Potential Applications of MOFs -- 6.2.3 Synthesis of MOFs -- 6.3 Polymer Electrolytes -- 6.3.1 Historical Perspectives and Classification of Polymer Electrolytes -- 6.3.2 MOF Based Polymer Electrolytes -- 6.4 Ionic Liquids -- 6.4.1 Properties of Ionic Liquids -- 6.4.2 Ionic Liquid Incorporated MOF -- 6.5 Ion Transport in Polymer Electrolytes -- 6.5.1 General Description of Ionic Conductivity -- 6.5.2 Models for Ionic Transport in Polymer Electrolytes -- 6.5.3 Impedance Spectroscopy and Ionic Conductivity Measurements -- 6.5.4 Concept of Mismatch and Relaxation -- 6.5.5 Scaling of ac Conductivity -- 6.6 IL Incorporated MOF Based Composite Polymer Electrolytes -- 6.7 Conclusion and Perspectives -- References -- Chapter 7 Fine Chemical Synthesis Using Metal-Organic Frameworks as Catalysts -- 7.1 Introduction -- 7.2 Oxidation Reaction -- 7.2.1 Epoxidation -- 7.2.2 Sulfoxidation -- 7.2.3 Aerobic Oxidation of Alcohols -- 7.3 1,3-Dipolar Cycloaddition Reaction -- 7.4 Transesterification Reaction -- 7.5 C-C Bond Formation Reactions -- 7.5.1 Heck Reactions -- 7.5.2 Sonogashira Coupling -- 7.5.3 Suzuki Coupling -- 7.6 Conclusion -- References -- Chapter 8 Application of Metal Organic Framework and Derived Material in Hydrogenation Catalysis -- 8.1 Introduction -- 8.1.1 The Active Centers in Parent MOF Materials. , 8.1.2 The Active Centers in MOF Catalyst -- 8.1.3 Metal Nodes -- 8.2 Hydrogenation Reactions -- 8.2.1 Hydrogenation of Alpha-Beta Unsaturated Aldehyde -- 8.2.2 Hydrogenation of Cinnamaldehyde -- 8.2.3 Hydrogenation of Nitroarene -- 8.2.4 Hydrogenation of Nitro Compounds -- 8.2.5 Hydrogenation of Benzene -- 8.2.6 Hydrogenation of Quinoline -- 8.2.7 Hydrogenation of Carbon Dioxide -- 8.2.8 Hydrogenation of Aromatics -- 8.2.9 Hydrogenation of Levulinic Acid -- 8.2.10 Hydrogenation of Alkenes and Alkynes -- 8.2.11 Hydrogenation of Phenol -- 8.3 Conclusion -- References -- Chapter 9 Application of MOFs and Their Derived Materials in Solid-Phase Extraction -- 9.1 Solid-Phase Extraction -- 9.1.1 Materials in SPE -- 9.2 MOFs and COFs in Miniaturized Solid-Phase Extraction (µSPE) -- 9.3 MOFs and COFs in Miniaturized Dispersive Solid-Phase Extraction (D-µSPE) -- 9.4 MOFs and COFs in Magnetic-Assisted Miniaturized Dispersive Solid-Phase Extraction (m-D-µSPE) -- 9.5 Concluding Remarks -- Acknowledgments -- References -- Chapter 10 Anticancer and Antimicrobial MOFs and Their Derived Materials -- 10.1 Introduction -- 10.2 Anticancer MOFs -- 10.2.1 MOFs as Drug Carriers -- 10.2.2 MOFs in Phototherapy -- 10.3 Antibacterial MOFs -- 10.4 Antifungal MOFs -- References -- Chapter 11 Theoretical Investigation of Metal-Organic Frameworks and Their Derived Materials for the Adsorption of Pharmaceutical and Pe -- 11.1 Introduction -- 11.2 General Synthesis Routes -- 11.2.1 Hydrothermal Synthesis -- 11.2.2 Solvothermal Synthesis of MOFs -- 11.2.3 Room Temperature Synthesis -- 11.2.4 Microwave Assisted Synthesis -- 11.2.5 Mechanochemical Synthesis -- 11.2.6 Electrochemical Synthesis -- 11.3 Postsynthetic Modification in MOF -- 11.4 Computational Method -- 11.5 Results and Discussion. , 11.5.1 Binding Behavior Between MIL-100 With the Adsorbates (Diclofenac, Ibuprofen, Naproxen, and Oxybenzone) -- 11.6 Conclusion -- References -- Chapter 12 Metal-Organic Frameworks and Their Hybrid Composites for Adsorption of Volatile Organic Compounds -- 12.1 Introduction -- 12.2 VOCs and Their Potential Hazards -- 12.2.1 Other Sources of VOCs -- 12.3 VOCs Removal Techniques -- 12.4 Fabricated MOF for VOC Removal -- 12.4.1 MIL Series MOFs -- 12.4.2 Isoreticular MOFs -- 12.4.2.1 Adsorption Comparison of the Isoreticular MOFs -- 12.4.3 NENU Series MOFs -- 12.4.4 MOF-5, Eu-MOF, and MOF-199 -- 12.4.5 Amine-Impregnated MIL-100 -- 12.4.6 Biodegradable MOFs MIL-88 Series -- 12.4.7 Catalytic MOFs -- 12.4.8 Photo-Degradating MOFs -- 12.4.9 Some Other Studied MOFs -- 12.5 MOF Composites -- 12.5.1 MIL-101 Composite With Graphene Oxide -- 12.5.2 MIL-101 Composite With Graphite Oxide -- 12.6 Generalization Adsorptive Removal of VOCs by MOFs -- 12.7 Simple Modeling the Adsorption -- 12.7.1 Thermodynamic Parameters -- 12.7.2 Dynamic Sorption Methods -- 12.8 Factor Affecting VOCs Adsorption -- 12.8.1 Breathing Phenomena -- 12.8.2 Activation of MOFs -- 12.8.3 Applied Pressure -- 12.8.4 Relative Humidity -- 12.8.5 Breakthrough Conditions -- 12.8.6 Functional Group of MOFs -- 12.8.7 Concentration, Molecular Size, and Type of VOCs -- 12.9 Future Perspective -- References -- Chapter 13 Application of Metal-Organic Framework and Their Derived Materials in Electrocatalysis -- List of Abbreviations -- 13.1 Introduction -- 13.2 Perspective Synthesis of MOF and Their Derived Materials -- 13.3 MOF for Hydrogen Evolution Reaction -- 13.4 MOF for Oxygen Evolution Reaction -- 13.5 MOF for Oxygen Reduction Reaction -- 13.6 MOF for CO2 Electrochemical Reduction Reaction -- 13.6.1 Electrosynthesis of MOF for CO2 Reduction -- 13.6.2 Composite Electrodes as MOF for CO2 Reduction. , 13.6.3 Continuous Flow Reduction of CO2 -- 13.6.4 CO2 Electrochemical Reduction in Ionic Liquid -- 13.7 MOF for Electrocatalytic Sensing -- 13.8 Electrocatalytic Features of MOF -- 13.9 Conclusion -- Acknowledgment -- References -- Chapter 14 Applications of MOFs and Their Composite Materials in LightDriven Redox Reactions -- 14.1 Introduction -- 14.1.1 MOFs as Photocatalysts -- 14.1.2 Charge Transfer Mechanisms -- 14.1.3 Methods of Synthesis -- 14.2 Pristine MOFs and Their Application in Photocatalysis -- 14.2.1 Group 4 Metallic Clusters -- 14.2.2 Groups 8, 9, and 10 Metallic Clusters -- 14.2.3 Group 11 Metallic Clusters -- 14.2.4 Group 12 Metallic Clusters -- 14.3 Metal Nanoparticles-MOF Composites and Their Application in Photocatalysis -- 14.3.1 Ag-MOF Composites -- 14.3.2 Au-MOF Composites -- 14.3.3 Cu-MOF Composites -- 14.3.4 Pd-MOF Composites -- 14.3.5 Pt-MOF Composites -- 14.4 Semiconductor-MOF Composites and Their Application in Photocatalysis -- 14.4.1 TiO2-MOF Composites -- 14.4.2 Graphitic Carbon Nitride-MOF Composites -- 14.4.3 Bismuth-Based Semiconductors -- 14.4.4 Reduced Graphene Oxide-MOF Composites -- 14.4.5 Silver-Based Semiconductors -- 14.4.6 Other Semiconductors -- 14.5 MOF-Based Multicomponent Composites and Their Application in Photocatalysis -- 14.5.1 Semiconductor-Semiconductor-MOF Composites -- 14.5.2 Semiconductor-Metal-MOF Composites -- 14.6 Conclusions -- References -- Index -- Also of Interest -- Check out these other forthcoming and published titles from Scrivener Publishing -- EULA.
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  • 2
    Online-Ressource
    Online-Ressource
    Newark :John Wiley & Sons, Incorporated,
    Schlagwort(e): Geochemistry. ; Electronic books.
    Materialart: Online-Ressource
    Seiten: 1 online resource (208 pages)
    Ausgabe: 1st ed.
    ISBN: 9781119710080
    DDC: 551.9
    Sprache: Englisch
    Anmerkung: Cover -- Half-Title Page -- Series Page -- Title Page -- Copyright Page -- Contents -- Preface -- 1 Toxic Geogenic Contaminants in Serpentinitic Geological Systems: Occurrence, Behavior, Exposure Pathways, and Human Health Risks -- 1.1 Introduction -- 1.2 Serpentinitic Geological Systems -- 1.2.1 Nature, Occurrence, and Geochemistry -- 1.2.2 Occurrence and Behavior of Toxic Contaminants -- 1.3 Human Exposure Pathways -- 1.3.1 Occupational Exposure -- 1.3.2 Non-Occupational Exposure Routes -- 1.4 Human Health Risks and Their Mitigation -- 1.4.1 Health Risks -- 1.4.2 Mitigating Human Exposure and Health Risks -- 1.5 Future Perspectives -- 1.6 Conclusions -- Acknowledgements -- References -- 2 Benefits of Geochemistry and Its Impact on Human Health -- 2.1 Introduction -- 2.2 General Overview of Geochemistry and Human Health -- 2.2.1 Types of Geochemistry -- 2.2.2 Some Beneficial Effect of Some Mineral With Health Benefits -- 2.2.3 Application of Geochemistry on Human Health -- 2.3 Conclusion and Recommendations -- References -- 3 Applications of Geochemistry in Livestock: Health and Nutritional Perspective -- 3.1 Introduction -- 3.2 General and Global Perspective About Geochemistry in Livestock -- 3.3 Types of Geochemistry and Their Numerous Benefits -- 3.3.1 Analytical Geochemistry -- 3.3.2 Isotope Geochemistry -- 3.3.3 Low Temperature Geochemistry -- 3.3.4 Organic and Petroleum Geochemistry -- 3.4 Application of Geochemistry in Livestock -- 3.5 Geochemistry and Animal Health -- 3.6 General Overview of Geochemistry in Livestock's Merits of Geochemistry/Essential Minerals in Livestocks -- 3.6.1 Specific Examples of Authors That Have Used Essential Minerals in Livestock -- 3.6.2 Livestock in Relation to Geominerals -- 3.6.3 Trace Minerals Parallel Importance in Livestock -- 3.6.4 Heavy Metals Impact Livestock -- 3.7 Conclusion and Recommendations. , References -- 4 Application in Geochemistry Toward the Achievement of a Sustainable Agricultural Science -- 4.1 Introduction -- 4.2 General Overview on the Utilization of Geochemistry and Their Wide Application on Agriculture -- 4.2.1 Classification -- 4.2.2 Chemical Composition of Rocks -- 4.2.3 Effect of Some Beneficial Minerals in Agriculture -- 4.2.4 Beneficial Mineral Nutrients That are Crucial to the Development of Plants -- 4.3 Role of Geochemistry in Agriculture -- 4.4 Geochemical Effects of Heavy Metals on Crops Health -- 4.5 Conclusion and Recommendations -- References -- 5 Geochemistry, Extent of Pollution, and Ecological Impact of Heavy Metal Pollutants in Soil -- 5.1 Introduction -- 5.2 Material and Methods -- 5.2.1 Review Process -- 5.2.2 Ecological Risk Index -- 5.3 Toxic Heavy Metal and Their Impact to the Ecosystems -- 5.3.1 Arsenic -- 5.3.2 Cadmium -- 5.3.3 Chromium -- 5.3.4 Copper -- 5.3.5 Lead -- 5.3.6 Nickel -- 5.3.7 Zinc -- 5.4 Metal Pollution in Soil Across the Globe -- 5.5 Ecological and Human Health Risk Impacts of Heavy Metals -- 5.6 Conclusion -- References -- 6 Isotope Geochemistry -- 6.1 Introduction -- 6.2 Basic Definitions -- 6.2.1 The Notation -- 6.2.2 The Fractionation Factor -- 6.2.3 Isotope Fractionation -- 6.2.4 Mass Dependent and Independent Fractionations -- 6.3 Application of Traditional Isotopes in Geochemistry -- 6.3.1 Geothermometer -- 6.3.2 Isotopes in Biological System -- 6.3.3 Isotopes in Archaeology -- 6.3.4 Isotopes in Fossils and the Earliest Life -- 6.3.5 Isotopes in Hydrothermal and Ore Deposits -- 6.4 Non-Traditional Isotopes in Geochemistry -- 6.4.1 Application in Tracing of Source -- 6.4.2 Application in Process Tracing -- 6.4.3 Biological Cycling -- 6.5 Conclusion -- References -- 7 Environmental Geochemistry -- 7.1 Introduction -- 7.2 Overview of the Environmental Geochemistry -- 7.3 Conclusions. , 7.4 Abbreviations -- Acknowledgment -- References -- 8 Medical Geochemistry -- 8.1 Introduction -- 8.2 The Evolution of Geochemistry -- 8.3 This Science has Expanded Considerably to Become Distinct Branches -- 8.3.1 Cosmochemistry -- 8.3.2 The Economic Importance of Geochemistry -- 8.3.3 Analytical Geochemistry -- 8.3.4 Geochemistry of Radioisotopes -- 8.3.5 Medical Geochemistry and Human Health -- 8.3.6 Environmental Health and Safety -- 8.4 Conclusion -- References -- 9 Inorganic Geochemistry -- 9.1 Introduction -- 9.2 Elements and the Earth -- 9.2.1 Iron -- 9.2.2 Oxygen -- 9.2.3 Silicon -- 9.2.4 Magnesium -- 9.3 Geological Minerals -- 9.3.1 Quartz -- 9.3.2 Feldspar -- 9.3.3 Amphibole -- 9.3.4 Pyroxene -- 9.3.5 Olivine -- 9.3.6 Clay Minerals -- 9.3.7 Kaolinite -- 9.3.8 Bentonite, Montmorillonite, Vermiculite, and Biotite -- 9.4 Characterization Techniques -- 9.4.1 Powder X-Ray Diffraction -- 9.4.2 X-Ray Fluorescence Spectra -- 9.4.3 X-Ray Photoelectron Spectra -- 9.4.4 Electron Probe Micro-Analysis -- 9.4.5 Inductively Coupled Plasma Spectrometry -- 9.4.6 Fourier Transform Infrared Spectroscopy -- 9.4.7 Scanning Electron Microscopy Analysis -- 9.4.8 Energy Dispersive X-Ray Analysis -- 9.5 Conclusion -- References -- 10 Introduction and Scope of Geochemistry -- 10.1 Introduction -- 10.1.1 Periodic Table and Electronic Configuration -- 10.2 Periodic Properties -- 10.2.1 Ionization Enthalpy -- 10.2.2 Electron Affinity -- 10.2.3 Electro-Negativity -- 10.3 Chemical Bonding -- 10.3.1 Ionic Bond -- 10.3.2 Covalent Bond -- 10.3.3 Metallic Bond -- 10.3.4 Hydrogen Bond -- 10.3.5 Van der Waals Forces -- 10.4 Geochemical Classification and Distribution of Elements -- 10.4.1 Lithophiles -- 10.4.2 Siderophiles -- 10.4.3 Chalcophiles -- 10.4.4 Atmophiles -- 10.4.5 Biophiles -- 10.5 Chemical Composition of the Earth -- 10.6 Classification of Earth's Layers. , 10.6.1 Based on Chemical Composition -- 10.6.2 Based on Physical Properties -- 10.7 Spheres of the Earth -- 10.7.1 Geosphere/Lithosphere -- 10.7.2 Hydrosphere -- 10.7.3 Biosphere -- 10.7.4 Atmosphere -- 10.7.5 Troposphere -- 10.7.6 Stratosphere -- 10.7.7 Mesosphere -- 10.7.8 Thermosphere and Ionosphere -- 10.7.9 Exosphere -- 10.8 Sub-Disciplines of Geochemistry -- 10.9 Scope of Geochemistry -- 10.10 Conclusion -- References -- Index -- EULA.
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