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  • Center for Marine Environmental Sciences; MARUM  (6)
  • 2010-2014  (6)
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  • 1
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    Hydrogen isotopic composition of sediment cores from a transect off western Africa (2013)
    PANGAEA
    In:  Supplement to: Collins, James A; Schefuß, Enno; Mulitza, Stefan; Prange, Matthias; Werner, Martin; Tharammal, Thejna; Paul, André; Wefer, Gerold (2013): Estimating the hydrogen isotopic composition of past precipitation using leaf-waxes from western Africa. Quaternary Science Reviews, 65, 88-101, https://doi.org/10.1016/j.quascirev.2013.01.007
    Details
    Publication Date: 2023-03-03
    Description: The hydrogen isotopic composition of plant leaf-wax n-alkanes (dDwax) is a novel proxy for estimating dD of past precipitation (dDp). However, vegetation life-form and relative humidity exert secondary effects on dDwax, preventing quantitative estimates of past dDp. Here, we present an approach for removing the effect of vegetation-type and relative humidity from dDwax and thus for directly estimating past dDp. We test this approach on modern day (late Holocene; 0-3 ka) sediments from a transect of 9 marine cores spanning 21°N-23°S off the western coast of Africa. We estimate vegetation type (C3 tree versus C4 grass) using d13C of leaf-wax n-alkanes and correct dDwax for vegetation-type with previously-derived apparent fractionation factors for each vegetation type. Late Holocene vegetation-corrected dDwax (dDvc) displays a good fit with modern-day dDp, suggesting that the effects of vegetation type and relative humidity have both been removed and thus that dDvc is a good estimate of dDp. We find that the magnitude of the effect of C3 tree - C4 grass changes on dDwax is small compared to dDp changes. We go on to estimate dDvc for the mid-Holocene (6-8 ka), the Last Glacial Maximum (LGM; 19-23 ka) and Heinrich Stadial 1 (HS1; 16-18.5 ka). In terms of past hydrological changes, our leaf-wax based estimates of dDp mostly reflect changes in wet season intensity, which is complementary to estimates of wet season length based on leaf-wax d13C.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 2 datasets
    Location Call Number Limitation Availability
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    DATA PANGAEA
  • 2
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    Distribution and stable isotopic compositions of hydrogen and carbon of plant-wax derived n-C29 and -C31 alkanes in terrestrial, coastal and offshore surface sediments (2013)
    PANGAEA
    In:  Supplement to: Leider, Arne; Hinrichs, Kai-Uwe; Schefuß, Enno; Versteegh, Gerard J M (2013): Distribution and stable isotopes of plant wax derived n-alkanes in lacustrine, fluvial and marine surface sediments along an Eastern Italian transect and their potential to reconstruct the hydrological cycle. Geochimica et Cosmochimica Acta, 117, 16-32, https://doi.org/10.1016/j.gca.2013.04.018
    Details
    Publication Date: 2023-03-03
    Description: Reconstructing terrestrial water budgets is of prime importance for understanding past climate and environment. To shed more light on how plant-wax derived n-alkanes may be used for this purpose we investigated the distribution and stable isotopic compositions of hydrogen (dD) and carbon (d13C) of plant-wax derived n-C29 and -C31 alkanes in terrestrial, coastal and offshore surface sediments in relation to hydrology along a NW-SE transect east of the Italian Apennines from the Po River to the Eastern Gulf of Taranto. The plant wax average chain length increases southward and may relate to increasing temperature and/or aridity. The plant wax dD of the terrestrial and coastal samples also increases southward and mainly reflects changes in the dD of precipitation. The d13C of plant waxes is primarily interpreted in terms of C3 vegetation changes rather than varying contributions by C4 plants. The plant wax d13C-dD composition of the Po River and Apennine rivers differs considerably from that in southern Italy, and suggests a mainly southern source for plant waxes in marine sediments of the Gulf of Taranto. This calibration provides a basis for the reconstruction of past changes in the Italian water balance and n-alkane source areas.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 3 datasets
    Location Call Number Limitation Availability
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    DATA PANGAEA
  • 3
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    Compound specific stable isotopes, BIT, pollen and spores of Miocene to Pliocene sediments of ODP Hole 175-1085A (2013)
    PANGAEA
    In:  Supplement to: Dupont, Lydie M; Rommerskirchen, Florian; Mollenhauer, Gesine; Schefuß, Enno (2013): Miocene to Pliocene changes in South African hydrology and vegetation in relation to the expansion of C4 plants. Earth and Planetary Science Letters, 375, 408-417, https://doi.org/10.1016/j.epsl.2013.06.005
    Details
    Publication Date: 2023-03-03
    Description: Pollen and stable carbon (d13C) and hydrogen (dD) isotope ratios of terrestrial plant wax from the South Atlantic sediment core, ODP Site 1085, is used to reconstruct Miocene to Pliocene changes of vegetation and rainfall regime of western southern Africa. Our results reveal changes in the relative amount of precipitation and indicate a shift of the main moisture source from the Atlantic to the Indian Ocean during the onset of a major aridification 8 Ma ago. We emphasise the importance of declining precipitation during the expansion of C4 and CAM (mainly succulent) vegetation in South Africa. We suggest that the C4 plant expansion resulted from an increased equator-pole temperature gradient caused by the initiation of strong Atlantic Meridional Overturning Circulation following the shoaling of the Central American Seaway during the Late Miocene.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 3 datasets
    Location Call Number Limitation Availability
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    DATA PANGAEA
  • 4
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    Sedimentary climate indicators of sediment core MD08-3167 and GeoB1711-4, southwestern Africa (2014)
    PANGAEA
    In:  Supplement to: Collins, James A; Schefuß, Enno; Govin, Aline; Mulitza, Stefan; Tiedemann, Ralf (2014): Insolation and glacial–interglacial control on southwestern African hydroclimate over the past 140 000 years. Earth and Planetary Science Letters, 398, 1-10, https://doi.org/10.1016/j.epsl.2014.04.034
    Details
    Publication Date: 2023-03-03
    Description: The past climate evolution of southwestern Africa is poorly understood and interpretations of past hydrological changes are sometimes contradictory. Here we present a record of leaf-wax dD and View the MathML source taken from a marine sediment core at 23°S off the coast of Namibia to reconstruct the hydrology and C3 versus C4 vegetation of southwestern Africa over the last 140 000 years (140 ka). We find lower leaf-wax dD and higher View the MathML source (more C4 grasses), which we interpret to indicate wetter Southern Hemisphere (SH) summer conditions and increased seasonality, during SH insolation maxima relative to minima and during the last glacial period relative to the Holocene and the last interglacial period. Nonetheless, the dominance of C4 grasses throughout the record indicates that the wet season remained brief and that this region has remained semi-arid. Our data suggest that past precipitation increases were derived from the tropics rather than from the winter westerlies. Comparison with a record from the Congo Basin indicates that hydroclimate in southwestern Africa has evolved in antiphase with that of central Africa over the last 140 ka.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 9 datasets
    Location Call Number Limitation Availability
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    DATA PANGAEA
  • 5
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    n-Alkane analyses from an transect of marine surface sediments off southwest Africa (2012)
    PANGAEA
    In:  Supplement to: Vogts, Angela; Schefuß, Enno; Badewien, Tanja; Rullkötter, Jürgen (2012): n-Alkane parameters from a deep sea sediment transect off Southwest Africa reflect continental vegetation and climate conditions. Organic Geochemistry, 47, 109-119, https://doi.org/10.1016/j.orggeochem.2012.03.011
    Details
    Publication Date: 2023-03-03
    Description: An isobathic transect of marine surface sediments from 1°N to 28°S off southwest Africa was used to further evaluate the potential of the chain length distribution and carbon stable isotope composition of higher plant n-alkanes as proxies for continental vegetation and climate conditions. We found a strong increase in the n-C29-33 weighted mean average d13C values from -33 per mil near the equator to around -26 per mil further south. Additionally, C25-35n-alkanes reveal a southward trend of increasing average chain length from 30.0 to 30.5. The data reflect the changing contribution of plants employing different photosynthetic pathways (C3 and C4) and/or being differently influenced by the environmental conditions of their habitat. The C4 plant proportions calculated from the data (ca. 20% for rivers draining the rainforest, to ca. 70% at higher latitude) correspond to the C4 plant abundance in continental catchment areas postulated by considering prevailing wind systems and river outflows. Furthermore, the C4 plant contribution to the sediments correlates with the mean annual precipitation and aridity at selected continental locations in the postulated catchment areas, suggesting that the C4 plant fraction in marine sediments can be used to assess these environmental parameters.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 7 datasets
    Location Call Number Limitation Availability
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    DATA PANGAEA
  • 6
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    Magnetic properties, grain sizes, XRF Scanner Data of sediment core GeoB9307-3 (2014)
    PANGAEA
    In:  Supplement to: Just, Janna; Schefuß, Enno; Kuhlmann, Holger; Stuut, Jan-Berend W; Pätzold, Jürgen (2014): Climate induced sub-basin source-area shifts of Zambezi River sediments over the past 17ka. Palaeogeography, Palaeoclimatology, Palaeoecology, 410, 190-199, https://doi.org/10.1016/j.palaeo.2014.05.045
    Details
    Publication Date: 2023-06-15
    Description: Geochemical and mineralogical proxies for paleoenvironmental conditions have the underlying assumption that climate variations have an impact on terrestrial weathering conditions. Varying properties of terrigenous sediments deposited at sea are therefore often interpreted in terms of paleoenvironmental change. Also in gravity core GeoB9307-3 (18° 33.99' S, 37° 22.89' E), located off the Zambezi River, environmental changes during Heinrich Stadial 1 (HS 1) and the Younger Dryas (YD) are accompanied by changing properties of the terrigenous sediment fraction. Our study focuses on the relationship of variability in the hydrological system and changes in the magnetic properties, major element geochemistry and granulometry of the sediments. We propose that changes in bulk sedimentary properties concur with environmental change, although not as a direct response of climate driven pedogenic processes. Spatial varying rainfall intensities on a sub-basin scale modify sediment export from different parts of the Zambezi River basin. During humid phases, such as HS 1 and the YD, sediment was mainly exported from the coastal areas, while during more arid phases sediments mirror the hinterland soil and lithological properties and are likely derived from the northern Shire sub-basin. We propose that a de-coupling of sedimentological and organic signals with variable discharge and erosional activity can occur.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 6 datasets
    Location Call Number Limitation Availability
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    DATA PANGAEA
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