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  • PANGAEA  (222)
  • ASLO (Association for the Sciences of Limnology and Oceanography)  (2)
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  • 1
    Publication Date: 2019-02-01
    Description: Large quantities of the greenhouse gas methane (CH4) are stored in the seafloor. The flux of CH4 from the sediments into the water column and finally to the atmosphere is mitigated by a series of microbial methanotrophic filter systems of unknown efficiency at highly active CH4-release sites in shallow marine settings. Here, we studied CH4-oxidation and the methanotrophic community at a high-CH4-flux site in the northern North Sea (well 22/4b), where CH4 is continuously released since a blowout in 1990. Vigorous bubble emanation from the seafloor and strongly elevated CH4 concentrations in the water column (up to 42 µM) indicated that a substantial fraction of CH4 bypassed the highly active (up to ∼2920 nmol cm−3 d−1) zone of anaerobic CH4-oxidation in sediments. In the water column, we measured rates of aerobic CH4-oxidation (up to 498 nM d−1) that were among the highest ever measured in a marine environment and, under stratified conditions, have the potential to remove a significant part of the uprising CH4 prior to evasion to the atmosphere. An unusual dominance of the water-column methanotrophs by Type II methane-oxidizing bacteria (MOB) is partially supported by recruitment of sedimentary MOB, which are entrained together with sediment particles in the CH4 bubble plume. Our study thus provides evidence that bubble emission can be an important vector for the transport of sediment-borne microbial inocula, aiding in the rapid colonization of the water column by methanotrophic communities and promoting their persistence close to highly active CH4 point sources.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 2
    Publication Date: 2019-09-24
    Description: Large quantities of methane are stored in hydrates and permafrost within shallow marine sediments in the Arctic Ocean. These reservoirs are highly sensitive to climate warming, but the fate of methane released from sediments is uncertain. Here, we review the principal physical and biogeochemical processes that regulate methane fluxes across the seabed, the fate of this methane in the water column, and potential for its release to the atmosphere. We find that, at present, fluxes of dissolved methane are significantly moderated by anaerobic and aerobic oxidation of methane. If methane fluxes increase then a greater proportion of methane will be transported by advection or in the gas phase, which reduces the efficiency of the methanotrophic sink. Higher freshwater discharge to Arctic shelf seas may increase stratification and inhibit transfer of methane gas to surface waters, although there is some evidence that increased stratification may lead to warming of sub-pycnocline waters, increasing the potential for hydrate dissociation. Loss of sea-ice is likely to increase wind speeds and seaair exchange of methane will consequently increase. Studies of the distribution and cycling of methane beneath and within sea ice are limited, but it seems likely that the sea-air methane flux is higher during melting in seasonally ice-covered regions. Our review reveals that increased observations around especially the anaerobic and aerobic oxidation of methane, bubble transport, and the effects of ice cover, are required to fully understand the linkages and feedback pathways between climate warming and release of methane from marine sediments.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 3
    Publication Date: 2015-05-11
    Repository Name: EPIC Alfred Wegener Institut
    Type: PANGAEA Documentation , notRev
    Format: application/zip
    Format: application/zip
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  • 4
    Publication Date: 2023-04-27
    Keywords: Black Sea; Center for Marine Environmental Sciences; Danube deep sea fan; DEPTH, sediment/rock; Device type; gas hydrate; GeoB22603-1; light hydrocarbons; M142; M142_03-1; MARUM; MeBo200; Meteor (1986); Methane; Method/Device of event; Optional event label; pore water; RV Meteor; Sample type; Submarine Gas Hydrate Resources; SUGAR; SUGAR project; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 68 data points
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  • 5
    Publication Date: 2023-04-27
    Keywords: Black Sea; Center for Marine Environmental Sciences; Danube deep sea fan; DEPTH, sediment/rock; Device type; gas hydrate; GeoB22620-1; light hydrocarbons; M142; M142_21-1; MARUM; MeBo200; Meteor (1986); Methane; Method/Device of event; Optional event label; pore water; RV Meteor; Sample type; Submarine Gas Hydrate Resources; SUGAR; SUGAR project; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 12 data points
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  • 6
    Publication Date: 2023-04-27
    Keywords: Black Sea; Center for Marine Environmental Sciences; Danube deep sea fan; DEPTH, sediment/rock; Device type; gas hydrate; GeoB22605-1; light hydrocarbons; M142; M142_06-1; MARUM; MeBo200; Meteor (1986); Methane; Method/Device of event; Optional event label; pore water; RV Meteor; Sample type; Submarine Gas Hydrate Resources; SUGAR; SUGAR project; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 52 data points
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  • 7
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    PANGAEA
    In:  Supplement to: Bahr, André; Pape, Thomas; Bohrmann, Gerhard; Mazzini, Adriano; Haeckel, Matthias; Reitz, Anja; Ivanov, Michael (2009): Authigenic carbonate precipitates from the NE Black Sea: a mineralogical, geochemical, and lipid biomarker study. International Journal of Earth Sciences, 98, 677-695, https://doi.org/10.1007/s00531-007-0264-1
    Publication Date: 2023-05-12
    Description: Carbonate precipitates recovered from 2,000 m water depth at the Dolgovskoy Mound (Shatsky Ridge, north eastern Black Sea) were studied using mineralogical, geochemical and lipid biomarker analyses. The carbonates differ in shape from simple pavements to cavernous structures with thick microbial mats attached to their lower side and within cavities. Low d13C values measured on carbonates (-41 to -32 per mill V-PDB) and extracted lipid biomarkers indicate that anaerobic oxidation of methane (AOM) played a crucial role in precipitating these carbonates. The internal structure of the carbonates is dominated by finely laminated coccolith ooze and homogeneous clay layers, both cemented by micritic high-magnesium calcite (HMC), and pure, botryoidal, yellowish low-magnesium calcite (LMC) grown in direct contact to microbial mats. d18O measurements suggest that the authigenic HMC precipitated in equilibrium with the Black Sea bottom water while the yellowish LMC rims have been growing in slightly 18O-depleted interstitial water. Although precipitated under significantly different environmental conditions, especially with respect to methane availability, all analysed carbonate samples show lipid patterns that are typical for ANME-1 dominated AOM consortia, in the case of the HMC samples with significant contributions of allochthonous components of marine and terrestrial origin, reflecting the hemipelagic nature of the primary sediment.
    Keywords: BS346GR; Center for Marine Environmental Sciences; Dolgovskoy mound; GeoB9908-1; MARUM; Professor Logachev; Television-Grab; TTR-15; TVG
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 8
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    PANGAEA
    In:  Supplement to: Haffert, Laura; Haeckel, Matthias (2019): Quantification of non-ideal effects on diagenetic processes along extreme salinity gradients at the Mercator mud volcano in the Gulf of Cadiz. Geochimica et Cosmochimica Acta, 244, 366-382, https://doi.org/10.1016/j.gca.2018.09.038
    Publication Date: 2023-01-13
    Description: Presented is an example of the transport-reaction code (TRACTION) applied to the simulation of pore water species in the seawater mixing zone at Mercator Mud volcano in the Gulf of Cadiz. TRACTION was specifically designed to account for non-ideal transport effects in the presence of thermodynamic (e.g. salinity or temperature) gradients. The model relies on the most fundamental concept of solute diffusion, which states that the chemical potential gradient (Maxwell's model) rather than the concentration gradient (Fick's law) is the driving force for diffusion. In turn, this requires accounting for species interactions by applying Pitzer's method to derive species chemical potentials and Onsager coefficients instead of using the classical diffusion coefficients. Electrical imbalances arising from varying diffusive fluxes in multicomponent systems, like seawater, are avoided by applying an electrostatic gradient as an additional transport contribution.
    Type: Dataset
    Format: application/zip, 1.4 MBytes
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  • 9
    Publication Date: 2023-02-24
    Description: The SUGAR Toolbox contains scripts coded in MATLAB for calculating various thermodynamic, kinetic, and geologic properties of substances occurring in the marine environment, particularly gas hydrate and seep systems. Brief descriptions of the toolbox scripts and some notes on the underlying basic theory as well as tables of additional property values can be found in the accompanying documentation.
    Keywords: GEOMAR; Helmholtz Centre for Ocean Research Kiel
    Type: Dataset
    Format: application/zip, 3.4 MBytes
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  • 10
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    PANGAEA
    In:  Supplement to: Kossel, Elke; Bigalke, Nikolaus; Piñero, Elena; Haeckel, Matthias (2013): The SUGAR Toolbox - A library of numerical algorithms and data for modelling of gas hydrate systems and marine environments. GEOMAR Report (N. Ser.), 8, 160 pp., https://doi.org/10.3289/geomar_rep_ns_8_2013
    Publication Date: 2023-02-24
    Description: The SUGAR Toolbox contains scripts coded in MATLAB for calculating various thermodynamic, kinetic, and geologic properties of substances occurring in the marine environment, particularly gas hydrate and seep systems. Brief descriptions of the toolbox scripts and some notes on the underlying basic theory as well as tables of additional property values can be found in the accompanying documentation.
    Keywords: GEOMAR; Helmholtz Centre for Ocean Research Kiel
    Type: Dataset
    Format: application/zip, 3.7 MBytes
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