Description: The radiogenic isotope composition of dissolved trace metals in the ocean represents a set of relatively new and not yet fully exploited tracers with a large potential for oceanographic and paleoceanographic research on timescales from the present back to at least 60 Ma. The main topic of this review are those trace metals with oceanic residence times on the order of or shorter than the global mixing time of the ocean (Nd, Pb, Hf, and, in addition, Be). Their isotopic composition in the ocean has varied as a function of changes in paleocirculation, source provenances, style and intensity of weathering on the continents, as well as orogenic processes. The relative importance of these processes for each trace metal is evaluated, which is a prerequisite for reliable interpretation of their time series in terms of changes in paleocirculation or weathering inputs. This analysis of processes includes a discussion of the long-term isotopic evolution of Sr and Os, which are well mixed in the ocean and have thus not been influenced by circulation changes. The radiogenic isotope evolution of those trace metals with intermediate oceanic residence times can be used as paleoceanographic proxies to reconstruct paleocirculation and weathering inputs into the ocean. This is demonstrated by studies from different ocean basins, mainly carried out on ferromanganese crusts, which show that radiogenic trace metal isotopes provide important new insights and can complement results obtained by other well-established paleoceanographic tracers such as carbon isotopes.

Description: Permafrost is an Essential Climate Variable (ECV) within the Global Climate Observing System (GCOS), which is characterized by subsurface temperatures and the depth of the seasonal thaw layer. Complementing ground-based monitoring networks, the Permafrost CCI project funded by the European Space Agency (ESA) 2018-2021 will establish Earth Observation (EO) based products for the permafrost ECV spanning the last two decades. Since ground temperature and thaw depth cannot be directly observed from space-borne sensors, we will ingest a variety of satellite and reanalysis data in a ground thermal model, which allows to quantitatively characterize the changing permafrost systems in Arctic and High-Mountain areas. As recently demonstrated for the Lena River Delta in Northern Siberia, the algorithm uses remotely sensed data sets of Land Surface Temperature (LST), Snow Water Equivalent (SWE) and landcover to drive the transient permafrost model CryoGrid 2, which yields ground temperature at various depths, in addition to thaw depth. For the circumpolar CCI product, we aim for a spatial resolution between 10 and 1km, but ensemble runs will be performed for each pixel to represent the subgrid variability of snow and land cover. The performance of the transient algorithm crucially depends on the correct representation of ground properties, in particular ice and organic contents. Therefore, the project will compile a new subsurface stratigraphy product which also holds great potential for improving Earth System Model results in permafrost environments. We report on simulation runs for various permafrost regions and characterize the accuracy and ability to reproduce trends against ground-based data. Finally, we evaluate the feasibility of future “permafrost reanalysis” products, exploiting the information content of various satellite products to deliver the best possible estimate for the permafrost thermal state over a range of spatial scales.

Description: A Permafrost Information System (PerSys) has been setup as part of the GlobPermafrost ESA DUE GlobPermafrost project (2016-2019, www.globpermafrost.info). This includes a data catalogue as well as a WebGIS, both linked to the Pangaea repository for easy data access. The thematic products available include InSAR-based land surface deformation maps, rock glacier velocity fields, spatially distributed permafrost model outputs, land surface properties and changes, and ground-fast lake ice. Extended permafrost modelling (time series) is implemented in the new ESA CCI+ Permafrost project (2018-2021), which will provide the key for our understanding of the changes of surface features over time. Special emphasis in CCI+ Permafrost will be on the evaluation and development of land surface models to gain better understanding of the impact of climate change on permafrost and land-atmosphere exchange. Additional focus will be on documentation of kinematics from rock glaciers in several mountain regions across the world. We will present an overview on technical developments made within GlobPermafrost and demonstrate its utility and challenges for an area prone to change of permafrost features. We will focus on the central Yamal Peninsula and the unusually warm years of 2012 and 2016. Conditions of 2012 triggered widespread retrogressive thaw slumps and the development of a gas emission crater. Thaw slumps have been reactivated in 2016, the first year with extensive coverage of Sentinel-1 as well as Sentinel-2 data. We present the documentation of these developments based on InSAR subsidence, Landsat trend analyses, ground fast lake ice, Sentinel-2 landcover information as well as a time series of the first version of ground temperatures from the ESA CCI+ Permafrost project. While landcover documents the occurrence of disturbances, InSAR provides insight into soil properties and impacts of unusually warm conditions during the unfrozen period. These space-based observations have been evaluated by in situ measurements at the long-term monitoring site Vaskiny Datchi. Ground fast lake ice and ground temperature modelling results provide additional insight into interannual variability.

Description: The first full water column hafnium isotopic compositions of Atlantic seawater have been obtained at seven locations from the Labrador Sea to the Drake Passage. Despite subpicomolar concentrations in seawater, a precision of the Hf isotopic measurements of 〈0.7 epsilon-Hf units was achieved. An overall epsilon-Hf range between -3.1 in the Labrador Sea and +4.4 in Antarctic bottom water was determined, the distribution of which broadly reflects continental weathering inputs. Within particular water column profiles, significant differences of up to 4 epsilon-Hf units occur. Combined with Nd isotope data of the same samples, it is evident that the Hf isotopic composition of seawater is too radiogenic for a given Nd isotopic composition and that the largest difference between expected and measured Hf isotopic compositions in seawater occurs near the oldest continental crust in the Labrador Sea. This corroborates the previous proposition, which was mainly based on ferromanganese crust data, that the Hf isotopic composition of seawater is controlled by incongruent weathering of continental crust and possibly, to some extent, by hydrothermal contributions. Hafnium concentrations in the ocean do not increase along the deep ocean conveyer indicating an oceanic residence time of only a few hundred years, which is significantly shorter than previously assumed. The Hf isotopic composition of past seawater can therefore serve as a proxy for short distance, basin scale mixing processes and the regime and intensity of nearby continental weathering processes.

Description: We present dissolved neodymium and hafnium concentrations and radiogenic isotope compositions of surface and deep-water masses from the Bay of Biscay. Neodymium isotope signatures in surface waters of the Bay of Biscay are dominated by local weathering inputs from the surrounding continental margin. Subsurface Eastern North Atlantic Central Water (ENACW) shows a distinct Nd isotope signature (εNd≅‑12.0) at the southwestern-most station and is significantly diluted by mixing with more radiogenic waters on its way north along the European margin. Furthermore, the Nd isotope data clearly show a declining fraction of Mediterranean Outflow Water (MOW) at intermediate depths on its way north indicating that only 40% to 60% of MOW still present in the mixture at the Galician margin arrive at the stations further north in the Bay of Biscay. A potentially seasonal variability of the flow path of MOW is identified when comparing the results of the Nd isotope compositions and salinity data of this study with those of earlier studies from the area. In agreement with Nd isotope and concentration analyses Hf isotope composition of MOW is affected by large-scale inputs of terrigenous material into the Mediterranean as can be deduced from elevated Hf concentrations at the Galician margin. Hf isotope signatures of all water masses of the Bay of Biscay, moreover, are overprinted by local weathering inputs and do not reflect water mass mixing. However, combined dissolved Nd and Hf isotopes serve as a useful indicator of local weathering influences on signatures expected from long distance admixture.

Description: Biogenic particle fluxes from highly productive surface waters, boundary scavenging, and hydrothermal activity are the main factors influencing the deposition of radionuclides in the area of the Galapagos microplate, eastern Equatorial Pacific. In order to evaluate the importance of these three processes throughout the last 100 kyr, concentrations of the radionuclides 10Be, 230Th, and 231Pa, and of Mn and Fe were measured at high resolution in sediment samples from two gravity cores KLH 068 and KLH 093. High biological productivity in the surface waters overlying the investigated area has led to 10Be and 231Pa fluxes exceeding production during at least the last 30 kyr and probably the last 100 kyr. However, during periods of high productivity at the up welling centers off Peru and extension of the equatorial high-productivity zone, a relative loss of 10Be and 231Pa may have occurred in these sediment cores because of boundary scavenging. The effects of hydrothermal activity were investigated by comparing the 230Thex concentrations to the Mn/Fe ratios and by comparing the fluxes of 230Th and 10Be which exceed production. The results suggest an enhanced hydrothermal influence during isotope stages 4 and 5 and to a lesser extent during isotope stage 1 in core KLH 093. During isotope stages 2 and 3, the hydrothermal supply of Mn was deposited elsewhere, probably because of changes in current regime or deep water oxygenation. A strong increase of the Mn/Fe ratio at the beginning of climatic stage 1 which is not accompanied by an increase of the 230Thex concentration is interpreted to be an effect of Mn remobilization and reprecipitation in the sediment.