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  • 1
    Publication Date: 2017-04-10
    Description: A high-resolution multiparameter stratigraphy allows the identification of late Quaternary glacial and interglacial cycles in a central Arctic Ocean sediment core. Distinct sandy layers in the upper part of the otherwise fine-grained sediment core from the Lomonosov Ridge (lat 87.5°N) correlate to four major glacials since ca. 0.7 Ma. The composition of these ice-rafted terrigenous sediments points to a glaciated northern Siberia as the main source. In contrast, lithic carbonates derived from North America are also present in older sediments and indicate a northern North American glaciation since at least 2.8 Ma. We conclude that large-scale northern Siberian glaciation began much later than other Northern Hemisphere ice sheets.
    Type: Article , PeerReviewed
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  • 2
    Publication Date: 2017-05-18
    Description: We report here the discovery of Miocene, Pliocene, and early Pleistocene shallow-marine carbonates on Mayaguana Island (southeastern Bahamas) that have so far not been observed on any other Bahamian island. Spanning more than 17 m.y., but 〈12 m thick, this stratigraphic succession only occurs along the northern coast of the island, indicating that the Mayaguana Bank underwent minor subsidence throughout the late Cenozoic and was tilted toward the south during the Quaternary. In addition to considerably extending the stratigraphic record of the Bahamas Islands, our findings demonstrate that these carbonate banks were at different elevations and subsided at different rates during the Neogene. The young age of the tilting event detected on Mayaguana further shows that parts of the southeastern margin of North America have recently undergone tectonic activity a long way from its actual boundary with the Caribbean plate.
    Type: Article , PeerReviewed
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  • 3
    Publication Date: 2017-07-28
    Description: Early diagenetic dolomite formation in methanogenic marine sediments is enigmatic because acidifi cation by CO2, a by-product of methanogenesis, should lead to carbonate dissolution and not precipitation. However, petrographic relationships indicate that dolomite breccia layers with δ13C values of ~+15‰, recovered from the lower slope of the Peru continental margin (Ocean Drilling Program Site 1230), formed deep in the methanogenic zone during tectonic activity of a décollement. Based on radiogenic Sr isotope ratios (87Sr/86Sr 〉 0.711) and positive δ18O values (+6‰), we present evidence that the dolomite breccias mainly formed from fl uids originating from deep sedimentary units within the accretionary prism, where they interacted with continental crust and/or siliciclastic rocks of continental affi nity. Due to silicate alteration and dehydration, such fl uids are likely alkaline and thus have the potential to neutralize the acidifi cation imposed by the high dissolved CO2 concentrations. This scenario provides a potential mechanism by which dolomite formation can be induced deep in a highly active methanogenic zone.
    Type: Article , PeerReviewed
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  • 4
    Publication Date: 2017-05-24
    Description: Largely continuous millennial-scale records of benthic delta O-18, Mg/Ca-based temperature, and salinity variations in bottom waters were obtained from Deep Sea Drilling Project (DSDP) Site 548 (East Atlantic continental margin near Ireland, 1250 m water depth) for the period 3.7-3.0 Ma ago. High epsilon(Nd) values of -10.7 to -9 show that this site monitored changes in Mediterranean Outflow Water (MOW) throughout the mid-Pliocene. Bottom water variability at Ocean Drilling Progam (ODP) Site 978 (Alboran Sea, 1930 m water depth) provides a complementary record of MOW composition near its West Mediterranean source. Both sites show a singular and persistent rise in bottom water salinities by 0.7-1.4 psu, and in densities by similar to 1 kg m(-3) from 3.5 to 3.3 Ma ago, which is matched by an similar to 3 degrees C increase in bottom water temperature at Site 548. This event suggests the onset of strongly enhanced deep-water convection in the Mediterranean Sea and a related increase in MOW flow as a result of major aridification in the Mediterranean source region. In harmony with model suggestions, the enhanced MOW flow has possibly intensified Upper North Atlantic Deep Water formation.
    Type: Article , PeerReviewed
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  • 5
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    GSA, Geological Society of America
    In:  Geology, 27 . pp. 1147-1150.
    Publication Date: 2017-09-26
    Description: Two Nd and Pb isotope time series of hydrogenous ferromanganese crusts, one from the Tehuantepec Ridge in the deep eastern equatorial Pacific and the other from Blake Plateau in the shallow northwestern Atlantic, which cover the past 7–8 m.y., show no variations coincident with the final closure of the Panama gateway, estimated as ca. 3.5 Ma. The record of the Atlantic crust located in the present-day Gulf Stream shows a shift in isotope composition from ca. 8 to 5 Ma that is explained by a diminishing supply of Pacific water. It is argued that the major restriction of water-mass exchange through the Panama gateway occurred before 5 Ma and thus cannot serve as a direct cause of the onset of Northern Hemisphere glaciation. The absence of a significant signature in the isotope records from the Pacific crust suggests that the volume of water exchanged with the Atlantic through shallow archipelagic straits of the gateway during the 3–4 m.y. prior to closure was too small to influence the radiogenic isotope composition of Pacific deep water.
    Type: Article , PeerReviewed
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  • 6
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 19 (2004): PA1018, doi:10.1029/2003PA000939.
    Description: There is increasing evidence indicating that syndepositional redistribution of sediment on the seafloor by bottom currents is common and can significantly affect sediment mass accumulation rates. Notwithstanding its common incidence, this process (generally referred to as sediment focusing) is often difficult to recognize. If redistribution is near synchronous to deposition, the stratigraphy of the sediment is not disturbed and sediment focusing can easily be overlooked. Ignoring it, however, can lead to serious misinterpretations of sedimentary fluxes, particularly when past changes in export flux from the overlying water are inferred. In many instances, this problem can be resolved, at least for sediments deposited during the late Quaternary, by normalizing to the flux of 230Th scavenged from seawater, which is nearly constant and equivalent to the known rate of production of 230Th from the decay of dissolved 234U. We review the principle, advantages and limitations of this method. Notwithstanding its limitations, it is clear that 230Th normalization does provide a means of achieving more accurate interpretations of sedimentary fluxes and eliminates the risk of serious misinterpretations of sediment mass accumulation rates.
    Description: R. Francois and M. P. Bacon acknowledge support from the National Science Foundation. M. Frank thanks the Swiss Science Foundation for support.
    Keywords: Paleoflux ; Sediment focusing ; Paleoproductivity
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 7
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Geochemical Cycles 26 (2012): GB2035, doi:10.1029/2011GB004141.
    Description: The fractionation of silicon (Si) stable isotopes by biological activity in the surface ocean makes the stable isotope composition of silicon (δ30Si) dissolved in seawater a sensitive tracer of the oceanic biogeochemical Si cycle. We present a high-precision dataset that characterizes the δ30Si distribution in the deep Atlantic Ocean from Denmark Strait to Drake Passage, documenting strong meridional and smaller, but resolvable, vertical δ30Si gradients. We show that these gradients are related to the two sources of deep and bottom waters in the Atlantic Ocean: waters of North Atlantic and Nordic origin carry a high δ30Si signature of ≥+1.7‰ into the deep Atlantic, while Antarctic Bottom Water transports Si with a low δ30Si value of around +1.2‰. The deep Atlantic δ30Si distribution is thus governed by the quasi-conservative mixing of Si from these two isotopically distinct sources. This disparity in Si isotope composition between the North Atlantic and Southern Ocean is in marked contrast to the homogeneity of the stable nitrogen isotope composition of deep ocean nitrate (δ15N-NO3). We infer that the meridional δ30Si gradient derives from the transport of the high δ30Si signature of Southern Ocean intermediate/mode waters into the North Atlantic by the upper return path of the meridional overturning circulation (MOC). The basin-scale deep Atlantic δ30Si gradient thus owes its existence to the interaction of the physical circulation with biological nutrient uptake at high southern latitudes, which fractionates Si isotopes between the abyssal and intermediate/mode waters formed in the Southern Ocean.
    Description: This work was supported by Swiss National Science Foundation grants 200021-116473 and 200020-130361.
    Description: 2012-12-19
    Keywords: Atlantic Ocean ; Southern Ocean ; Silicon isotopes
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 8
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 21(2), (2020): e2019GC008414, doi:10.1029/2019GC008414.
    Description: X‐ray fluorescence (XRF) core scanning of marine and lake sediments has been extensively used to study changes in past environmental and climatic processes over a range of timescales. The interpretation of XRF‐derived element ratios in paleoclimatic and paleoceanographic studies primarily considers differences in the relative abundances of particular elements. Here we present new XRF core scanning data from two long sediment cores in the Andaman Sea in the northern Indian Ocean and show that sea level related processes influence terrigenous inputs based proxies such as Ti/Ca, Fe/Ca, and elemental concentrations of the transition metals (e.g., Mn). Zr/Rb ratios are mainly a function of changes in median grain size of lithogenic particles and often covary with changes in Ca concentrations that reflect changes in biogenic calcium carbonate production. This suggests that a common process (i.e., sea level) influences both records. The interpretation of lighter element data (e.g., Si and Al) based on low XRF counts is complicated as variations in mean grain size and water content result in systematic artifacts and signal intensities not related to the Al or Si content of the sediments. This highlights the need for calibration of XRF core scanning data based on discrete sample analyses and careful examination of sediment properties such as porosity/water content for reliably disentangling environmental signals from other physical properties. In the case of the Andaman Sea, reliable extraction of a monsoon signal requires accounting for the sea level influence on the XRF data.
    Description: The staff at the Bremen Core Repository is thanked for their help with core handling and Sam Müller at the University of Kiel provided technical assistance with the XRF scanner. We thank two anonymous reviewers for their insightful comments that improved the manuscript significantly. This work was partially funded through DFG Grant HA 5751/3. P. A. and K. N.‐K. acknowledge support from UK‐IODP and Natural and Environment Research Council, UK. The authors express their thanks to all those who contributed to the success of the National Gas Hydrate Program Expedition 01 (NGHP01) and Expedition 353. The data set supporting the conclusions of this article is available in the PANGEA repository (doi: https://doi.pangaea.de/10.1594/PANGAEA.910533).
    Description: 2020-07-10
    Repository Name: Woods Hole Open Access Server
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  • 9
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 22 (2007): PA1216, doi:10.1029/2005PA001235.
    Keywords: Paleoflux ; Th-230
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 10
    Publication Date: 2022-05-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Bretschneider, L., Hathorne, E. C., Huang, H., Luebbers, J., Kochhann, K. G. D., Holbourn, A., Kuhnt, W., Thiede, R., Gebregiorgis, D., Giosan, L., & Frank, M. Provenance and weathering of clays delivered to the Bay of Bengal during the middle Miocene: linkages to tectonics and monsoonal climate. Paleoceanography and Paleoclimatology, 36(2), (2021): e2020PA003917, https://doi.org/10.1029/2020PA003917.
    Description: Tectonics and regional monsoon strength control weathering and erosion regimes of the watersheds feeding into the Bay of Bengal, which are important contributors to global climate evolution via carbon cycle feedbacks. The detailed mechanisms controlling the input of terrigenous clay to the Bay of Bengal on tectonic to orbital timescales are, however, not yet well understood. We produced orbital‐scale resolution geochemical records for International Ocean Discovery Program Site U1443 (southern Bay of Bengal) across five key climatic intervals of the middle to late Miocene (15.8–9.5 Ma). Our new radiogenic Sr, Nd, and Pb isotope time series of clays transported to the Ninetyeast Ridge suggest that the individual contributions from different erosional sources overall remained remarkably consistent during the Miocene despite major tectonic reorganizations in the Himalayas. On orbital timescales, however, high‐resolution data from the five investigated intervals show marked fluctuations of all three isotope systems. Interestingly, the variability was much higher within the Miocene Climatic Optimum (around 16–15 Ma) and across the major global cooling (~13.9–13.8 Ma) until ~13.5 Ma, than during younger time intervals. This change is attributed to a major restriction on the supply of High Himalayan erosion products due to migration of the peak precipitation area toward the frontal domains of the Himalayas and the Indo‐Burman Ranges. The transient excursions of the radiogenic isotope signals on orbital timescales most likely reflect climatically driven shifts in monsoon strength.
    Description: This research used samples and data provided by the International Ocean Discovery Program and was funded by the German Research Foundation (DFG) (grants HA 5751/6‐1 and HA 5751/6‐2, KU 649/36‐1, and TH 1317‐8 and TH 1317‐9). Open access funding enabled and organized by Projekt DEAL.
    Repository Name: Woods Hole Open Access Server
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