Description: Natural gas hydrates are considered a potential resource for gas production on industrial scales. Gas hydrates contribute to the strength and stiffness of the hydrate-bearing sediments. During gas production, the geomechanical stability of the sediment is compromised. Due to the potential geotechnical risks and process management issues, the mechanical behavior of the gas hydrate-bearing sediments needs to be carefully considered. In this study, we describe a coupling concept that simplifies the mathematical description of the complex interactions occurring during gas production by isolating the effects of sediment deformation and hydrate phase changes. Central to this coupling concept is the assumption that the soil grains form the load-bearing solid skeleton, while the gas hydrate enhances the mechanical properties of this skeleton. We focus on testing this coupling concept in capturing the overall impact of geomechanics on gas production behavior though numerical simulation of a high-pressure isotropic compression experiment combined with methane hydrate formation and dissociation. We consider a linear-elastic stress-strain relationship because it is uniquely defined and easy to calibrate. Since, in reality, the geomechanical response of the hydrate-bearing sediment is typically inelastic and is characterized by a significant shear-volumetric coupling, we control the experiment very carefully in order to keep the sample deformations small and well within the assumptions of poroelasticity. The closely coordinated experimental and numerical procedures enable us to validate the proposed simplified geomechanics-to-flow coupling, and set an important precursor toward enhancing our coupled hydro-geomechanical hydrate reservoir simulator with more suitable elastoplastic constitutive models.

Description: Research and regulations must be integrated to protect seafloor biota from future mining impacts Summary: As human use of rare metals has diversified and risen with global development, metal ore deposits from the deep ocean floor are increasingly seen as an attractive future resource. Japan recently completed the first successful test for zinc extraction from the deep seabed, and the number of seafloor exploration licenses filed at the International Seabed Authority (ISA) has tripled in the past 5 years. Seafloor-mining equipment is being tested, and industrial-scale production in national waters could start in a few years. We call for integrated scientific studies of global metal resources, the fluxes and fates of metal uses, and the ecological footprints of mining on land and in the sea, to critically assess the risks of deep-sea mining and the chances for alternative technologies. Given the increasing scientific evidence for long-lasting impacts of mining on the abyssal environment, precautionary regulations for commercial deep-sea mining are essential to protect marine ecosystems and their biodiversity.

Description: Geochemical data (CH4, SO42−, I−, Cl−, particulate organic carbon (POC), δ13C-CH4, and δ13C-CO2) are presented from the upper 30 m of marine sediment on a tectonic submarine accretionary wedge offshore southwest Taiwan. The sampling stations covered three ridges (Tai-Nan, Yung-An, and Good Weather), each characterized by bottom simulating reflectors, acoustic turbidity, and different types of faulting and anticlines. Sulfate and iodide concentrations varied little from seawater-like values in the upper 1–3 m of sediment at all stations; a feature that is consistent with irrigation of seawater by gas bubbles rising through the soft surface sediments. Below this depth, sulfate was rapidly consumed within 5–10 m by anaerobic oxidation of methane (AOM) at the sulfate-methane transition. Carbon isotopic data imply a mainly biogenic methane source. A numerical transport-reaction model was used to identify the supply pathways of methane and estimate depth-integrated turnover rates at the three ridges. Methane gas ascending from deep layers, facilitated by thrusts and faults, was by far the dominant term in the methane budget at all sites. Differences in the proximity of the sampling sites to the faults and anticlines mainly accounted for the variability in gas fluxes and depth-integrated AOM rates. By comparison, methane produced in situ by POC degradation within the modeled sediment column was unimportant. This study demonstrates that the geochemical trends in the continental margins offshore SW Taiwan are closely related to the different geological settings.

Description: Gashydrate sind eisähnliche Verbindungen, in denen Hydratbildner, z.B. Methan, in hoher Dichte gespeichert werden können. Methanhydrate sind nur bei hohen Drücken und tiefen Temperaturen sowie in Anwesenheit hoher Methankonzentrationen stabil. Diese Stabilitätsbedingungen sind unter bestimmten Voraussetzungen in marinen Sedimenten erfüllt, in denen Methan durch den mikrobiellen Abbau von abgelagerter Biomasse entsteht oder aus größeren Tiefen zugeführt wird. Die globale Menge an Methan in marinen Gashydraten überschreitet die Menge an Erdgas in konventionellen Lagerstätten vermutlich um ein Mehrfaches. Eine potenzielle Nutzung von Gashydraten als zukünftige Energiequelle wird daher gegenwärtig weltweit untersucht. Erste Feldtests in Permafrostregionen und marinen Lagerstätten haben gezeigt, dass eine Produktion von Methan aus Gashydraten prinzipiell möglich ist. Eine Förderung von Methan aus Gashydraten kann technisch realisiert werden mittels Druckabsenkung, durch thermische Stimulation oder chemische Aktivierung. Die Injektion von CO2, ebenfalls ein Hydratbildner, kann eine solche Aktivierung der natürlichen Hydrate bewirken und das Methan in der Hydratstruktur ersetzen. Infolgedessen erscheint eine verfahrenstechnische Kombination von Hydratabbau und CO2-Speicherung als besonders sinnvoll, da im Idealfall eine emissionsarme bis -freie Energiegewinnung ermöglicht würde. Untersuchungen zur Aufklärung mechanistischer und fluiddynamischer Aspekte der CH4-CO2-Hydratumwandlung sowie zur Entwicklung eines technischen Verfahrens werden in unterschiedlichen Hochdruckanlagen auf verschiedenen Skalen durchgeführt. Diese speziellen Systeme bieten die Möglichkeit, marine Druck-, Temperatur- und Durchflussbedingungen zu simulieren. Sie sind mit verschiedenen Sensoren und Messsystemen (z.B. CTD, IR, Raman, MRI) ausgerüstet, um den Prozessverlauf störungsfrei zu überwachen. Basierend auf derzeitigen Ergebnissen erscheint die Injektion von erwärmtem, überkritischem CO2 als vielversprechender technischer Baustein für die Verfahrensentwicklung. Die Zuführung von Wärmeenergie bewirkt die initiale Destabilisierung der Gashydrate und die Freisetzung von CH4, während nach Abkühlung das CO2 seinerseits Hydrate bildet und als feste, immobile Phase im Sediment zurückgehalten wird. Sowohl Methanproduktion als auch CO2-Speicherung sind dabei abhängig von der Reservoirtemperatur, so dass die Prozesseffizienz und -ausbeute bei mittleren Temperaturen (8°C) höher ist als bei niedrigeren (2°C) und höheren Temperaturen (10°C). Dies deutet darauf hin, dass der Gesamtprozess durch die Raten der jeweiligen Teilreaktionen der Hydratzersetzung und Hydratneubildung stark beeinflusst wird. Der experimentelle Vergleich unterschiedlicher Injektionsmodi zeigt, dass eine alternierende CO2-Injektion bestehend aus Injektions- und Reaktionsintervallen höhere Ausbeuten erreicht als eine kontinuierliche Injektion.

Description: Current estimates suggest that more than 60% of the global seafloor are covered by millions of abyssal hills and mountains. These features introduce spatial fluid-dynamic granularity whose influence on deep-ocean sediment biogeochemistry is unknown. Here we compare biogeochemical surface-sediment properties from a fluid-dynamically well-characterized abyssal hill and upstream plain: (1) In hill sediments, organic-carbon and -nitrogen contents are only about half as high as on the plain while proteinaceous material displays less degradation; (2) on the hill, more coarse-grained sediments (reducing particle surface area) and very variable calcite contents (influencing particle surface charge) are proposed to reduce the extent, and influence compound-specificity, of sorptive organic-matter preservation. Further studies are needed to estimate the representativeness of the results in a global context. Given millions of abyssal hills and mountains, their integrative influence on formation and composition of deep-sea sediments warrants more attention.

Description: Takahe seep, located on the Opouawe Bank, Hikurangi Margin, is characterized by a well-defined subsurface seismic chimney structure ca. 80,500 m2 in area. Sub-seafloor geophysical data based on acoustic anomaly layers indicated the presence of gas hydrate and free gas layers within the chimney structure. Reaction-transport modeling was applied to porewater data from 11 gravity cores to constrain methane turnover rates and benthic methane fluxes in the upper 10 m. Model results show that methane dynamics were highly variable due to transport and dissolution of ascending gas. The dissolution of gas (up to 3761 mmol m−2 yr−1) dwarfed the rate of methanogenesis within the simulated sediment column (2.6 mmol m−2 yr−1). Dissolved methane is mainly consumed by anaerobic oxidation of methane (AOM) at the base of the sulfate reduction zone and trapped by methane hydrate formation below it, with maximum rates in the central part of the chimney (946 and 2420 mmol m−2 yr−1, respectively). A seep-wide methane budget was constrained by combining the biogeochemical model results with geophysical data and led to estimates of AOM rates, gas hydrate formation and benthic dissolved methane fluxes of 3.68 × 104 mol yr−1, 73.85 × 104 mol yr−1and 1.19 × 104 mol yr−1, respectively. A much larger flux of methane probably escapes in gaseous form through focused bubble vents. The approach of linking geochemical model results with spatial geophysical data put forward here can be applied elsewhere to improve benthic methane turnover rates from limited single spot measurements to larger spatial scales.

Description: Our study presents a basin-scale 3D modeling solution, quantifying and exploring gas hydrate accumulations in the marine environment around the Green Canyon (GC955) area, Gulf of Mexico. It is the first modeling study that considers the full complexity of gas hydrate formation in a natural geological system. Overall, it comprises a comprehensive basin re-construction, accounting for depositional and transient thermal history of the basin, source rock maturation, petroleum components generation, expulsion and migration, salt tectonics and associated multi-stage fault development. The resulting 3D gas hydrate distribution in the Green Canyon area is consistent with independent borehole observations. An important mechanism identified in this study and leading to high gas hydrate saturation (〉 80 vol. %) at the base of the gas hydrate stability zone (GHSZ), is the recycling of gas hydrate and free gas enhanced by high Neogene sedimentation rates in the region. Our model predicts the rapid development of secondary intra-salt mini-basins situated on top of the allochthonous salt deposits which leads to significant sediment subsidence and an ensuing dislocation of the lower GHSZ boundary. Consequently, large amounts of gas hydrates located in the deepest parts of the basin dissociate and the released free methane gas migrates upwards to recharge the GHSZ. In total, we have predicted the gas hydrate budget for the Green Canyon area that amounts to ∼3,256 Mt of gas hydrate which is equivalent to ∼340 Mt of carbon (∼7 x 1011 m3 of CH4 at STP conditions), and consists mostly of biogenic hydrates.

Description: Cruise SO268 is fully integrated into the second phase of the European collaborative JPI-Oceans project MiningImpact and is designed to assess the environmental impacts of deep-sea mining of polymetallic nodules in the Clarion-Clipperton Fracture Zone (CCZ). In particular, the cruise aimed at conducting an independent scientific monitoring of the first industrial test of a pre-protoype nodule collector by the Belgian company DEME-GSR. The work includes collecting the required baseline data in the designated trial and reference sites in the Belgian and German contract areas, a quantification of the spatial and temporal spread of the produced sediment plume during the trials as well as a first assessment of the generated environmental impacts. However, during SO268 Leg 1 DEME-GSR informed us that the collector trials would not take place as scheduled due to unresolvable technical problems. Thus, we adjusted our work plan accordingly by implementing our backup plan. This involved conducting a small-scale sediment plume experiment with a small chain dredge to quantify the spatial and temporal dispersal of the suspended sediment particles, their concentration in the plume as well as the spatial footprint and thickness of the deposited sediment blanket on the seabed. Leg 1 and 2 acquired detailed environmental baseline data in the designated collector trial and reference sites as well as the site of the small-scale sediment plume experiment. The plume experiment was monitored by an array of acoustic and optical sensors and the impacted area was investigated in order to develop standards and protocols for impact assessments and recommendations for marine policy and international legislation. A more technical aim of the cruise was to test tools, technologies, and a concept for the environmental monitoring of future deep-sea mining operations. This comprised oceanographic, biological, microbiological, biogeochemical, and geologic investigations which required the deployment of a multitude of seagoing equipment, such as ROV Kiel 6000 for sampling of sediments, nodules, and benthic fauna as well as carrying out in situ measurements and experiments, and the deployment of the plume sensor array. AUV ABYSS and ROV Kiel 6000 were used for high-resolution acoustic mapping of the seafloor using mounted multibeam systems and video/photo surveys of the manganese nodule habitat. This work was accompanied by video observations with the OFOS system. Several benthic landers and moorings with acoustic and optical sensors were deployed and recovered for the measurements of physical and chemical oceanographic variables. Coring devices (i.e., box corer, gravity corer, TV-guided multiple corer, ROV-operaten push cores) were used to collect sediment samples for biological, geochemical, and microbiological analyses, and a CTD rosette water sampler, in situ pumps, and a bottom water sampler sampled the water column. In addition, recolonization experiments for nodule-associated fauna were started by deploying artificial hard substrates on the seabed of the working areas.