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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 235-236 (1992), S. 611-622 
    ISSN: 1573-5117
    Keywords: cadmium ; cobalt ; sediment ; sulphide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A sediment sample with high organic matter and trace metal content was suspended in synthetic river water for four weeks under an inert gas atmosphere. Subsequently, the anaerobic suspension was reoxidized by bubbling air through it. The concentrations of dissolved oxygen, sulfide, ferrous iron, manganese, cadmium, cobalt and the pH-value were measured at close time intervals during the anaerobic incubation. The anaerobic suspension was a post-oxic or sub-oxic environment with oxygen and total sulfide concentrations less than 1 µmole 1−1. Concentrations of dissolved ferrous iron and manganese were 50–150 µmole 1−1 and 5–30 µmole 1−1, respectively. The total sulfide concentration was measured using a sensitive voltammetric technique, with a detection limit of 1 nmole 1−1. A sequential extraction procedure was applied to two sediment samples taken at the end of the anaerobic incubation and after one week of reoxidation. The extractions indicated that cadmium was bound in sulfide minerals under post-oxic conditions. Thermodynamic equilibrium calculations revealed that the concentrations of dissolved cobalt in the post-oxic suspension were limited by the precipitation of cobalt sulfide minerals.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2017-05-23
    Description: Seafloormethane emission from the Quepos Slide on the submarine segment of the Costa Rica fore-arc margin was estimated by extrapolating flux measurements from individual seeps to the total area covered by bacterial mats. This approach is based on the combination of detailed mapping to determine the abundance of seeps and the application of a numerical model to estimate the amount of benthic methane fluxes. Model results suggest that the majority of the studied seeps transport rather limited amount of methane (on average: *177 lmol cm-2 a-1) into the water column due to moderate upward advection, allowing for intense anaerobic oxidation of methane (AOM; on average: 53 % of the methane flux is consumed). Depth-integrated AOM rates (56–1,538 lmol CH4 cm-2 a-1) are comparable with values reported from other active seep sites. The overall amount of dissolved methane released into the water column from the entire area covered by bacterial mats on the Quepos Slide is estimated to be about 0.28 9 106 mol a-1. This conservative estimate which relies on rather accurate determinations of seafloor methane fluxes emphasizes the potential importance of submarine slides as sites of natural methane seepage; however, at present the global extent of methane seepage from submarine slides is largely unknown.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2017-02-01
    Description: In 2000, the Carbon Dioxide in the Ocean working group of the North Pacific Marine Science Organization (PICES) performed an international experiment on the intercalibration of the measurements of the total alkalinity in seawater using certified reference materials (CRM). Taking part in this experiment, Russian specialists presented the method by Bruevich. The results of the intercalibration showed that the alkalinity values obtained by Bruevich's method using modern burettes, an Na2CO3 reactant of high purity as a standard to ascertain the acid titre, and corrections for the acid density and for the weights of the acid and seawater samples in vacuum are in agreement with the standard within +/- 1 mu M/kg.
    Type: Article , PeerReviewed
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  • 4
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    ECO2 Project Office
    In:  ECO2 Deliverable, D11.3 . ECO2 Project Office, Kiel, Germany, 15 pp.
    Publication Date: 2019-03-11
    Description: ECO2 conducted a comprehensive offshore field programme at the Norwegian storage sites Sleipner and Snøhvit and at several natural CO2 seepage sites in order to identify potential pathways for CO2 leakage through the overburden, monitor seep sites at the seabed, track and trace the spread of CO2 in ambient bottom waters, and study the response of benthic biota to CO2. Based on its extensive field programme ECO2 developed guidelines for the monitoring of sub-seabed storage sites. ECO2 recommends that overburden, seabed, and water column should be surveyed applying the following techniques: i) 3-D seismic imaging of seals and overburden, ii) high-resolution bathymetry/backscatter mapping of the seabed, iii) hydro-acoustic imaging of shallow gas accumulations in the seabed and gas bubbles ascending into the water column, iv) video/photo imaging of biota at the seabed, v) chemical detection of dissolved CO2 and related parameters in ambient bottom waters. Additional targeted studies have to be conducted if active formation water seeps, gas seeps, and pockmarks with deep roots reaching into the storage formation occur at the seabed. These sites have to be revisited on a regular basis to determine emission rates of gases and fluids and exclude that seepage is invigorated and pockmarks are re-activated by the storage operation. Baseline studies serve to determine the natural variability against which the response of the storage complex to the storage operation has to be evaluated. All measurements being part of the monitoring program, thus, need to be performed during the baseline study prior to the onset of the storage operation to assess the spatial and temporal variability of leakage-related structures, parameters, and processes.
    Type: Report , NonPeerReviewed , info:eu-repo/semantics/book
    Format: text
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  • 5
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    Unknown
    ECO2 Project Office
    In:  ECO2 Deliverable, D12.2 . ECO2 Project Office, 6 pp.
    Publication Date: 2019-03-11
    Description: In order to proceed with speculative modelling of the impacts of potential leakage of geologically stored carbon, it is necessary to develop plausible scenarios. Here a range of such scenarios are developed based on a consensus of the possible geological mechanisms of leakage, namely abandoned wells, geological faults and operational blowouts. Whilst the resulting scenarios remain highly speculative, they do enable short term progress in modelling and provide a basis for further debate and refinement.
    Type: Report , NonPeerReviewed , info:eu-repo/semantics/book
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  • 6
    Publication Date: 2019-03-11
    Type: Report , NonPeerReviewed , info:eu-repo/semantics/book
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  • 7
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    Unknown
    ECO2 Project Office
    In:  ECO2 Deliverable, D7.4 . ECO2 Project Office, Kiel, Germany, 4 pp.
    Publication Date: 2019-03-11
    Type: Report , NonPeerReviewed , info:eu-repo/semantics/book
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  • 8
    Publication Date: 2017-06-29
    Description: Hydrothermal activity in the Central Bransfield Basin revealed an active low-temperature vent field on top of a submarine volcanic structure. A temperature anomaly was detected and the sea floor showed various patches of white silica (opal-A) precipitate exposures and some yellow–brown Fe-oxyhydroxide crusts. Enriched dissolved methane concentrations were encountered. Sediment was near 24°C just after the grab came on deck. No dense population of chemosynthetically based macrofauna known from other hydrothermal venting areas was present, except for pogonophora. The observations suggest that the sedimented hydrothermal field at Hook Ridge is a low-temperature end-member branch from a deeper hydrothermal source.
    Type: Article , PeerReviewed
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  • 9
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    Unknown
    Springer
    In:  International Journal of Earth Sciences, 93 . pp. 596-611.
    Publication Date: 2019-09-23
    Description: Carbonate precipitates on mounds and along tectonic scarps off the Costa Rica margin are manifestations of subduction-induced dewatering. The long-term dewatering history is recorded in mineralogical, petrological and isotope signals of carbonates recovered from these sites. The carbonates are strongly depleted in δ13C (−11 to −53‰ PDB) and enriched in δ18O (+4 to +8‰ PDB). Thermogenic methane and biogenic methane were identified as sources of the carbon. Chemoherm carbonates and seepage-associated carbonates formed in a focused flow regime have lighter δ13C values, while others formed in a more diffusive flow regime have slightly enriched C isotope values. Three fluid components were inferred based on the calculation of equilibrium δ18O: clay dehydration water, gas hydrate water and seawater. Calculated equilibrium δ18O values of carbonates from different down-core depths as well as from different precipitation stages show that the δ18O of the precipitating fluid is progressively depleted with time. Dolostones showing a methane-C source and a well constrained O-isotope signature are thought to have formed at depth in the sediment and subsequently became exhumed. Glauconitic sandstones cemented by methane-derived carbonate provide evidence that fluid and solid material have been expelled by the mud volcano.
    Type: Article , PeerReviewed
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  • 10
    Publication Date: 2017-05-22
    Description: Geochemical properties of gas hydrate accumulation associated with an active gas vent on the continental slope offshore northeast Sakhalin Island in the Sea of Okhotsk have been investigated. The pore water chemistry data suggest that the gas hydrates (GHs) were formed in an environment of upward-migrating fluid combined with a mechanism of pore water segregation. The upward infiltration of water enriched mainly by Cl− and K+ species appears to occur on the background of earlier diagenesis processes within the gas vent sediments. The GHs were formed from water with chlorinity ranging from 530 to 570 mM. The δ18O and δD of GH water varied from −1.4 to −1.8‰ and from −13 to −18‰, respectively, representing a mix of seawater and infiltrating fluid water. A complex interaction of pore water, water of ascending fluid and segregated pore water during hydrate formation is also supported by water content measurements and observed gas hydrate structure. The direction of segregated water is opposite to upward fluid migration. Decreasing activity of the gas vent is inferred by comparing the present top of the recovered hydrate layer with previous observations.
    Type: Article , PeerReviewed
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