Description: Gas hydrates were recovered during coring by Ocean Drilling Program (ODP) Leg 112 at Sites 685 and 688 on the Peruvian outer continental margin at latitudes of 9° and 11.5°S, where water depths are 5070 and 3820 m, respectively. In addition, nearby Sites 682 and 683 yielded compelling evidence that gas hydrates are present, but gas hydrates were not directly observed there. Anomalous acoustic reflectors, known as bottom-simulating reflectors (BSRs), on marine seismic profiles from the region also provided inferential evidence that gas hydrates are present. Geothermal gradients of about 43 and 49°C/km were calculated on the basis of relations between depths to BSRs, bottom-water temperatures, and the pressure-temperature stability field of gas hydrates. Geochemical studies revealed that methane concentrations increase rapidly with depth after pore-water sulfate concentrations have been depleted. The relationship between methane and sulfate suggests that microbial processes account for the generation of methane, and the relationship between the carbon isotopic composition of methane and dissolved carbon dioxide supports this suggestion. We believe that decreasing chlorinity in pore water from squeezed sediment at the four sites results mainly from the decomposition of gas hydrates and is a dilution artifact observed as a result of the squeezing procedure. Maximum chlorinity values at or near the surface result from excess salt that comes from the formation of gas hydrates composed of freshwater. Record alkalinity attests to the intensity of diagenetic processes and has significant effects on salinity profiles at these sites. Gas hydrates were recovered at 99 and 166 meters below the seafloor (mbsf) at Site 685, and at 141 mbsf at Site 688 in Pleistocene diatomaceous mud. Methane constitutes more than 99% of the hydrocarbon gas mixture in the gas hydrates. The volumetric ratio of methane to water in the sample from Site 685 is 100, indicating that the sampled gas hydrate is either undersaturated with respect to methane or had partially decomposed during core recovery or both. The discovery of gas hydrates in lower slope deposits of the Peruvian outer continental margin extends our knowledge of gas-hydrate formation and occurrence in the Circum-Pacific region.

Description: The d13C values of total inorganic carbon (Sum CO2 ) were measured for interstitial waters extracted from the turbidite and hemipelagic sediments of the Nankai Trough accretionary prism during ODP Leg 131. At 3.0 mbsf in the bacterial sulfate reduction zone, a significant low d13C of -29.8 per mil (PDB) was found, suggesting oxidation of upward-migrated methane from the zone below. At 6.0 mbsf, below the sulfate reduction zone, the d13C value increases abruptly to a maximum value of +12.0 per mil, reflecting an enrichment of 13C in residual Sum CO2 from the bacterial reduction of some Sum CO2 to 12C-enriched CH4. Below 80 mbsf, the 13C values decrease almost linearly with depth to ~ -20 per mil at 1000 mbsf, indicating that the fraction of Sum CO2 derived from thermal degradation of organic material increases gradually with increasing in-situ temperature.