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  • 1
    In: Earth & planetary science letters, Amsterdam [u.a.] : Elsevier, 1966, 244(2006), Seite 1-15, 0012-821X
    In: volume:244
    In: year:2006
    In: pages:1-15
    Type of Medium: Article
    ISSN: 0012-821X
    Language: English
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  • 2
    Keywords: Forschungsbericht
    Type of Medium: Online Resource
    Pages: Online-Resource (117 MB, 190 S.)
    Series Statement: IFM-GEOMAR-Report 9
    Language: English
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  • 3
    In: Environmental modelling & software, Amsterdam [u.a.] : Elsevier Science, 1997, 24(2009), 8, Seite 1012-1013, 1873-6726
    In: volume:24
    In: year:2009
    In: number:8
    In: pages:1012-1013
    Description / Table of Contents: The presented software application allows GUI-based access to the bubble dissolution model presented by McGinnis et al. [McGinnis, D.F., Greinert, J., Artemov, Y., Beaubien, S.E., Wüest, A., 2006. The fate of rising methane bubbles in stratified waters: what fraction reaches the atmosphere? Journal of Geophysical Research 111, C09007. doi:10.1029/2005JC003183]. It quantifies the dissolution of gas bubbles (containing any combination of CH4, CO2, O2, N2, and Ar) in marine or lacustrine environments based on the initial bubble size, free gas composition and environmental parameters (temperature, salinity, and dissolved gas concentrations). The software enables scientists and engineers to evaluate bubble dynamics in a simple way on Windows® PCs.
    Type of Medium: Online Resource
    ISSN: 1873-6726
    Language: English
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  • 4
    Keywords: Forschungsbericht
    Type of Medium: Book
    Pages: 151 S. , Ill., graph. Darst., Kt.
    Series Statement: IFM-GEOMAR-Report 9
    Language: English
    Note: Auch als elektronisches Dokument vorh
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  • 5
    Publication Date: 2019-12-03
    Description: The relation between acoustic sea-floor backscatter and seep distribution is examined by integrating multibeam backscatter data and seep locations detected by single-beam echosounder. This study is further supported by side-scan sonar recordings, high-resolution 5 kHz seismic data, pore-water analysis, grain-size analysis and visual sea-floor observations. The datasets were acquired during the 2003 and 2004 expeditions of the EC-funded CRIMEA project in the Dnepr paleo-delta area, northwestern Black Sea. More than 600 active methane seeps were hydroacoustically detected within a small (3.96 km by 3.72 km) area on the continental shelf of the Dnepr paleo-delta in water depths ranging from − 72 m to − 156 m. Multibeam and side-scan sonar recordings show backscatter patterns that are clearly associated with seepage or with a present dune area. Seeps generally occur within medium- to high-backscatter areas which often coincide with pockmarks. High-resolution seismic data reveals the presence of an undulating gas front, i.e. the top of the free gas in the subsurface, which domes up towards and intersects the sea floor at locations where gas seeps and medium- to high-backscatter values are detected. Pore-water analysis of 4 multi-cores, taken at different backscatter intensity sites, shows a clear correlation between backscatter intensity and dissolved methane fluxes. All analyzed chemical species indicate increasing anaerobic oxidation of methane (AOM) from medium- to high-backscatter locations. This is confirmed by visual sea-floor observations, showing bacterial mats and authigenic carbonates formed by AOM. Grain-size analysis of the 4 multi-cores only reveals negligible variations between the different backscatter sites. Integration of all datasets leads to the conclusion that the observed backscatter patterns are the result of ongoing methane seepage and the precipitation of methane-derived authigenic carbonates (MDACs) caused by AOM. The carbonate formation also appears to lead to a gradual (self)-sealing of the seeps by cementing fluid pathways/horizons followed by a relocation of the bubble-releasing locations.
    Type: Article , PeerReviewed
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  • 6
    Publication Date: 2013-07-03
    Description: An ancient hydrocarbon seep province of 14 isolated, authigenic carbonate deposits has been identified in fine-grained, deep-marine siliciclastic strata of the Miocene East Coast Basin, North Island, New Zealand. These forearc sediments have been uplifted and complexly deformed into accretionary ridges, adjacent to the still-active Hikurangi convergent margin. Older active and passive margin strata (mid-Cretaceous to Oligocene in age) underlie the Neogene sequence, and contain oil- and gas-prone source rocks. Older Mesozoic meta-sedimentary rocks constitute the backstop against which the current phase of subduction-related sedimentation has accumulated (~ 24 Ma–present). The seep-carbonates (up to 10 m thick, 200 m across) archive methane signatures in their depleted carbon isotopes (to δ13C –51.7‰ PDB), and contain chemosynthesis-based paleocommunities (e.g. worm tubes, bathymodioline mussels, and vesicomyid, lucinid and thyasirid bivalves) typical of other Cenozoic and modern seeps. Northern and southern sites are geographically separated, and exhibit distinct lithological and faunal differences. Structural settings are variable. Seep-associated lithologies also are varied, and suggest carbonate development in sub-seafloor, seafloor and physically reworked (diapiric expansion, gas explosion, gravity slide or debris flow) settings, similar to Italian Apennine seep deposits of overlapping ages. Peculiar attributes of the New Zealand Miocene seep deposits are several, including digitate thrombolites of clotted microbial micrite encased in thick, isopachous horizons and botryoids of aragonite. Seep plumbing features are also well-exposed at some sites, displaying probable gas-explosion breccias filled with aragonite, tubular concretions (fluid conduits), and carbonate-cemented, thin sandstone beds and burrows within otherwise impermeable mudstones. A few seeps were large enough to develop talus-debris piles on their flanks, which were populated by lucinid bivalves and terebratulid brachiopods. Firmgrounds and hardgrounds were common, as evidenced by trace fossil associations or caryophyllid coral thickets atop some seep-carbonate deposits. Thus, the New Zealand examples show strong evidence of formation in sediments at or just beneath the seafloor, but some were clearly exhumed by erosion to sustain later non-seep, epifaunal and boring paleocommunities.
    Type: Article , PeerReviewed
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  • 7
    Publication Date: 2013-06-28
    Description: Extensive ROV-based sampling and exploration of the seafloor was conducted along an eroded transform-parallel fault scarp on the northeastern side of the Guaymas Basin in the Gulf of California to observe the nature of fluids venting from the seafloor, measure the record left by methane-venting on the carbonates from this area, and determine the association with gas hydrate. One gas vent vigorous enough to generate a water-column gas plume traceable for over 800 m above the seafloor was found to emanate from a ∼10-cm-wide orifice on the eroded scarp face. Sediment temperature measurements and topography on a sub-bottom reflector recorded in a transform-parallel seismic reflection profile identified a subsurface thermal anomaly beneath the gas vent. Active chemosynthetic biological communities (CBCs) and extensive authigenic carbonates that coalesce into distinct chemoherm structures were encountered elsewhere along the eroded transform-parallel scarp. The carbon isotopic composition of methane bubbles flowing vigorously from the gas vent (−53.6±0.8‰ PDB) is comparable to methane found in sediment cores taken within the CBCs distributed along the scarp (−51.9±8.1‰ PDB). However, the δ13C value of the CO2 in the vent gas (+12.4±1.1‰ PDB) is very distinct from those for dissolved inorganic carbon (DIC) (−35.8‰ to −2.9‰ PDB) found elsewhere along the scarp, including underneath CBCs. The δ13C values of the carbonate-rich sediments and rocks exposed on the seafloor today also span an unusually large range (−40.9‰ to +12.9‰ PDB) and suggest two distinct populations of authigenic carbonate materials were sampled. Unconsolidated sediments and some carbonate rocks, which have lithologic evidence for near-seafloor formation, have negative δ13C values, while carbonate rocks that clearly formed in the subsurface have positive δ13C values (up to +23.0‰) close to that measured for CO2 in the vent gas. There appears to be two carbon sources for the authigenic carbonates: (1) deeply-sourced, isotopically heavy CO2 (∼+12‰); and (2) isotopically light DIC derived from local anaerobic oxidation of methane at the sulfate–methane interface in the shallow subsurface. Addition of isotopically light methane-derived carbon at the seafloor may completely mask the isotopically heavy CO2 signature (+12.4‰) in the underlying sediments. Thus, the authigenic carbonates may have formed from the same methane- and carbon dioxide-bearing fluid, but under different migration and alteration conditions, depending on how it migrated through the sediment column.
    Type: Article , PeerReviewed
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  • 8
    Publication Date: 2017-12-07
    Description: Analyses of the chemical and isotopic composition of carbonates rocks recovered from methane seepage areas of the Kodiak Trench, Hydrate Ridge, Monterey Bay Clam Flats, and the Eel River Basin, coupled with the studies of the chemistry of the pore fluids, have shown that these carbonates have grown within the sediment column. Geochemical profiles of pore fluids show that, in deep water seeps (Kodiak Trench—4450 m; Monterey Bay—1000 m; Hydrate Ridge—650 m), δ13C (DIC) values are low (isotopically light), whereas in the Eel River area (∼ 350–500 m), δ13C (DIC) values are much higher (isotopically heavier). In all cases, the δ13C values indicate that processes of methane oxidation, associated with sulfate reduction, are dominant in the shallow sediments. Data on the isotopic composition of authigenic carbonates found at sites in Kodiak Trench, Eel River Basin South, and Eel River Basin North indicate a variable composition and origin in different geochemical environments. Some of the authigenic carbonates from the study sites show a trend in their δ13C values similar to those of the pore fluids obtained in their vicinity, suggesting formation at relatively shallow depths, but others indicate formation at greater sediment depths. The latter usually consist of high magnesium calcite or dolomite, which, from their high values of δ13C (up to 23‰;) and δ18O (up to 7.5‰), suggest formation in the deeper horizons of the sediments, in the zone of methanogenesis. These observations are in agreement with observations by other workers at Hydrate Ridge, in Monterey Bay, and in the Eel River Basin.
    Type: Article , PeerReviewed
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  • 9
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    AGU
    In:  Journal of Geophysical Research: Oceans, 113 (C7). C07048.
    Publication Date: 2020-07-23
    Description: A lander-based hydroacoustic swath system, GasQuant, was deployed in an intensely bubbling seep area at the shelf west of the Crimea Peninsula, Black Sea. With its horizontally oriented swath (21 beams, 63° swath angle, 180 kHz) GasQuant operates in a sonar-like mode and monitors bubbles remotely, exploiting their strong backscattering when crossing the swath. All active seep spots were monitored simultaneously within the covered area (2075 m2). Even applying simple processing and visualization techniques (moving average for filtering, FFT for spectrum analyses; swath and trace plots) identified 17 seeps of different activity patterns that have been grouped as follows: (1) sporadically active with one to a few long bursts (up to 18 min) or randomly occurring short bursts (〈200 bursts and active for 〈5% of the observation time); (2) regularly active seeps showing mainly short bursts of less than one minute but also longer burst of a few minutes (200–350 bursts and 5 to 20% active); (3) frequently active spots with sometimes very periodic bubble release (〉350 bursts or 〉20% active). Studying the bubble release variability of single seeps and of the entire area allows speculation about the external and internal processes that modulate the bubble release. In the study area none of the 17 seeps was found to be permanently active. Only one was active for 75% and another one for 45% of the time monitored. The rest only released bubbles during less than 20% of the time with an overall average of only 12%. This would have strong implications for flux extrapolations if these were based on very accurate but few short-term measurements. Both strong overestimates and underestimates are possible. High-resolution monitoring over at least one tidal cycle as with the GasQuant system might help to get an idea of the temporal variability. Thus flux extrapolations can be corrected to better reflect the real seep activity.
    Type: Article , PeerReviewed
    Format: text
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  • 10
    Publication Date: 2016-05-24
    Description: Shallow gas occurs between 0 and 1000 m below the sea floor. It consists mainly of microbial-formed or thermogenic methane or a combination of both, sometimes with a limited admixture of higher hydrocarbons (propane, butane, etc.).
    Type: Article , PeerReviewed
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