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  • 2010-2014  (7)
Publikationsart
Schlagwörter
Verlag/Herausgeber
Erscheinungszeitraum
Jahr
  • 1
    Publikationsdatum: 2017-07-31
    Beschreibung: Gas hydrate samples from various locations in the Gulf of Mexico (GOM) differ considerably in their microstructure. Distinct microstructure characteristics coincide with discrete crystallographic structures, gas compositions and calculated thermodynamic stabilities. The crystallographic structures were established by X-ray diffraction, using both conventional X-ray sources and high-energy synchrotron radiation. The microstructures were examined by cryo-stage Field-Emission Scanning Electron Microscopy (FE-SEM). Good sample preservation was warranted by the low ice fractions shown from quantitative phase analyses. Gas hydrate structure II samples from the Green Canyon in the northern GOM had methane concentrations of 70–80% and up to 30% of C2–C5 of measured hydrocarbons. Hydrocarbons in the crystallographic structure I hydrate from the Chapopote asphalt volcano in the southern GOM was comprised of more than 98% methane. Fairly different microstructures were identified for those different hydrates: Pores measuring 200–400 nm in diameter were present in structure I gas hydrate samples; no such pores but dense crystal surfaces instead were discovered in structure II gas hydrate. The stability of the hydrate samples is discussed regarding gas composition, crystallographic structure and microstructure. Electron microscopic observations showed evidence of gas hydrate and liquid oil co-occurrence on a micrometer scale. That demonstrates that oil has direct contact to gas hydrates when it diffuses through a hydrate matrix.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Publikationsdatum: 2023-03-03
    Schlagwort(e): 140; 157-1; 169; Area/locality; Bush Hill; Campeche Knoll; Center for Marine Environmental Sciences; Chapopote; Comment; Elevation of event; Event label; GC; GeoB10618; Gravity corer; Hydrate; Latitude of event; Longitude of event; M67/2b; MARUM; Meteor (1986); OTEGA II; Sample code/label; SO174/1; SO174/1_47-1; SO174/1_96; SO174/2; SO174/2_140; SO174/2_157-1; SO174/2_169; Sonne; Television-Grab; TVG; X-ray diffraction (XRD)
    Materialart: Dataset
    Format: text/tab-separated-values, 93 data points
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Publikationsdatum: 2023-03-03
    Schlagwort(e): 140; 157-1; 169; Area/locality; Bush Hill; C1 hydrocarbons; C2 hydrocarbons; C3 hydrocarbons; C5-isomers hydrocarbons; Campeche Knoll; Center for Marine Environmental Sciences; Chapopote; Comment; Elevation of event; Event label; Gas chromatography - Flame Ionization Detection (GC-FID); GC; GeoB10618; Gravity corer; iso-C4 hydrocarbons; Latitude of event; Longitude of event; M67/2b; MARUM; Meteor (1986); n-C4 hydrocarbons; Number; OTEGA II; Sample code/label; SO174/1; SO174/1_47-1; SO174/1_96; SO174/2; SO174/2_140; SO174/2_157-1; SO174/2_169; Sonne; Television-Grab; TVG
    Materialart: Dataset
    Format: text/tab-separated-values, 123 data points
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    facet.materialart.
    Unbekannt
    PANGAEA
    In:  Supplement to: Klapp, Stephan A; Bohrmann, Gerhard; Kuhs, Werner F; Murshed, Mangir M; Pape, Thomas; Klein, Helmut; Techmer, Kirsten S; Heeschen, Katja U; Abegg, Friedrich (2010): Microstructures of structure I and II gas hydrates from the Gulf of Mexico. Marine and Petroleum Geology, 27(1), 116-125, https://doi.org/10.1016/j.marpetgeo.2009.03.004
    Publikationsdatum: 2023-03-03
    Beschreibung: Gas hydrate samples from various locations in the Gulf of Mexico (GOM) differ considerably in their microstructure. Distinct microstructure characteristics coincide with discrete crystallographic structures, gas compositions and calculated thermodynamic stabilities. The crystallographic structures were established by X-ray diffraction, using both conventional X-ray sources and high-energy synchrotron radiation. The microstructures were examined by cryo-stage Field-Emission Scanning Electron Microscopy (FE-SEM). Good sample preservation was warranted by the low ice fractions shown from quantitative phase analyses. Gas hydrate structure II samples from the Green Canyon in the northern GOM had methane concentrations of 70-80% and up to 30% of C2-C5 of measured hydrocarbons. Hydrocarbons in the crystallographic structure I hydrate from the Chapopote asphalt volcano in the southern GOM was comprised of more than 98% methane. Fairly different microstructures were identified for those different hydrates: Pores measuring 200-400 nm in diameter were present in structure I gas hydrate samples; no such pores but dense crystal surfaces instead were discovered in structure II gas hydrate. The stability of the hydrate samples is discussed regarding gas composition, crystallographic structure and microstructure. Electron microscopic observations showed evidence of gas hydrate and liquid oil co-occurrence on a micrometer scale. That demonstrates that oil has direct contact to gas hydrates when it diffuses through a hydrate matrix.
    Schlagwort(e): 140; 157-1; 169; Bush Hill; Campeche Knoll; Center for Marine Environmental Sciences; Chapopote; GC; GeoB10618; Gravity corer; M67/2b; MARUM; Meteor (1986); OTEGA II; SO174/1; SO174/1_47-1; SO174/1_96; SO174/2; SO174/2_140; SO174/2_157-1; SO174/2_169; Sonne; Television-Grab; TVG
    Materialart: Dataset
    Format: application/zip, 2 datasets
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    facet.materialart.
    Unbekannt
    PANGAEA
    In:  Supplement to: Spaeth, Gerhard; Hotten, Rüdiger; Peters, Matthias; Techmer, Kirsten S (1995): Mafic Dykes in the Shackleton Range, Antarctica. Polarforschung, 63(2/3), 101-121, hdl:10013/epic.29717.d001
    Publikationsdatum: 2023-01-13
    Beschreibung: In addition to some mafic dykes which are already known and which were resampled, a number of mafic dykes were discovered in the Shackleton Range during the 1987/88 GEISHA expedition and sampled for the first time. Field data for 29 dykes, as well as analytical results of petrographic, geochemical, and isotope-geochemistry studies on the basalts of 26 of these dykes, are presented and discussed. The mafic dykes can be subdivided into five groups on the basis of their petrography and degree of alteration. According to the geochemical analyses, the dyke rocks are continental tholeiites. Geochemical characterization on the basis of trace-elements, especially rare earths, permits subdivision according to magma type. This subdivision shows reasonable agreement with the subdivision according to petrographic criteria. On the basis of radiometric dating and field relationships, the following ages can be assigned to the five groups of dykes: Group I, Early Jurassic; Groups II and III, early Palaeozoic (Middle Devonian to Late Ordovician?); Group IV, probably Late Proterozoic and Group V, probably Middle Proterozoic. These groups of mafic dykes, which can be regarded as indicating extension phases, are discussed with respect to the geotectonic history of the Shackleton Range, and comparisons with neighbouring regions are made.
    Schlagwort(e): Dyke-1; Dyke-11; Dyke-13; Dyke-15; Dyke-16a; Dyke-16b; Dyke-17; Dyke-18; Dyke-19; Dyke-2; Dyke-21; Dyke-23; Dyke-24; Dyke-25; Dyke-26; Dyke-27; Dyke-28; Dyke-5; Dyke-6; Dyke-7; Dyke-8; Dyke-9; GEISHA; Geological sample; GEOS; Haskard Highlands, Shackleton Range, Antarctica; Herbert Mountains, Shackleton Range, Antarctica; Lagrange Nunataks, Shackleton Range, Antarctica; Read Mountains, Shackleton Range, Antarctica
    Materialart: Dataset
    Format: application/zip, 2 datasets
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 6
    Publikationsdatum: 2023-07-11
    Schlagwort(e): Age, dated; Age, error; Argon-40; Argon-40 at standard pressure; Description; Dyke-15; Dyke-16a; Dyke-16b; Dyke-24; Dyke-25; Dyke-27; Dyke-5; Event label; GEISHA; Geological sample; GEOS; Haskard Highlands, Shackleton Range, Antarctica; Herbert Mountains, Shackleton Range, Antarctica; Lagrange Nunataks, Shackleton Range, Antarctica; Potassium oxide; Read Mountains, Shackleton Range, Antarctica; Sample code/label; Sample code/label 2; Size fraction
    Materialart: Dataset
    Format: text/tab-separated-values, 118 data points
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 7
    Publikationsdatum: 2023-07-10
    Schlagwort(e): -; Aluminium oxide; Area/locality; Barium; Caesium; Calcium oxide; Carbon dioxide; Cerium; Chromium; Cobalt; Dyke-1; Dyke-11; Dyke-13; Dyke-15; Dyke-16a; Dyke-16b; Dyke-17; Dyke-18; Dyke-19; Dyke-2; Dyke-21; Dyke-23; Dyke-24; Dyke-25; Dyke-26; Dyke-27; Dyke-28; Dyke-5; Dyke-6; Dyke-7; Dyke-8; Dyke-9; Europium; Event label; GEISHA; Geological sample; GEOS; Hafnium; Haskard Highlands, Shackleton Range, Antarctica; Herbert Mountains, Shackleton Range, Antarctica; Iron oxide, Fe2O3; Iron oxide, FeO; Lagrange Nunataks, Shackleton Range, Antarctica; Lanthanum; Lanthanum/Niobium ratio; Lithium; Lutetium; Magnesium oxide; Manganese oxide; Nickel; Niobium; Phosphorus pentoxide; Potassium oxide; Read Mountains, Shackleton Range, Antarctica; Rubidium; Samarium; Sample code/label; Scandium; Silicon dioxide; Sodium oxide; Strontium; Sulfur, total; Sum; Tantalum; Terbium; Thorium; Titanium dioxide; Water in rock; Ytterbium; Yttrium; Zirconium
    Materialart: Dataset
    Format: text/tab-separated-values, 1048 data points
    Standort Signatur Einschränkungen Verfügbarkeit
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