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  • 2020-2024  (35)
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  • 1
    Keywords: Forschungsbericht ; Ostsee ; Versauerung ; Eutrophierung
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource (33 Seiten, 6,52 MB) , Diagramme, Karten
    Language: German
    Note: Förderkennzeichen BMBF 03F0773A , Verbundnummer 01178467 , Unterschiede zwischen dem gedruckten Dokument und der elektronischen Ressource können nicht ausgeschlossen werden
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  • 2
    Publication Date: 2023-02-08
    Description: In the current era of rapid climate change, accurate characterization of climate-relevant gas dynamics-namely production, consumption, and net emissions-is required for all biomes, especially those ecosystems most susceptible to the impact of change. Marine environments include regions that act as net sources or sinks for numerous climateactive trace gases including methane (CH4) and nitrous oxide (N2O). The temporal and spatial distributions of CH4 and N2O are controlled by the interaction of complex biogeochemical and physical processes. To evaluate and quantify how these mechanisms affect marine CH4 and N2O cycling requires a combination of traditional scientific disciplines including oceanography, microbiology, and numerical modeling. Fundamental to these efforts is ensuring that the datasets produced by independent scientists are comparable and interoperable. Equally critical is transparent communication within the research community about the technical improvements required to increase our collective understanding of marine CH4 and N2O. A workshop sponsored by Ocean Carbon and Biogeochemistry (OCB) was organized to enhance dialogue and collaborations pertaining to marine CH4 and N2O. Here, we summarize the outcomes from the workshop to describe the challenges and opportunities for near-future CH4 and N2O research in the marine environment.
    Type: Article , PeerReviewed
    Format: text
    Format: video
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  • 3
    Publication Date: 2024-02-07
    Description: The ocean and inland waters are two separate regimes, with concentrations in greenhouse gases differing on orders of magnitude between them. Together, they create the land–ocean aquatic continuum (LOAC), which comprises itself largely of areas with little to no data with regards to understanding the global carbon system. Reasons for this include remote and inaccessible sample locations, often tedious methods that require collection of water samples and subsequent analysis in the lab, and the complex interplay of biological, physical and chemical processes. This has led to large inconsistencies, increasing errors and has inevitably lead to potentially false upscaling. A set-up of multiple pre-existing oceanographic sensors allowing for highly detailed and accurate measurements was successfully deployed in oceanic to remote inland regions over extreme concentration ranges. The set-up consists of four sensors simultaneously measuring pCO2, pCH4 (both flow-through, membrane-based non-dispersive infrared (NDIR) or tunable diode laser absorption spectroscopy (TDLAS) sensors), O2 and a thermosalinograph at high resolution from the same water source. The flexibility of the system allowed for deployment from freshwater to open ocean conditions on varying vessel sizes, where we managed to capture day–night cycles, repeat transects and also delineate small-scale variability. Our work demonstrates the need for increased spatiotemporal monitoring and shows a way of homogenizing methods and data streams in the ocean and limnic realms.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 4
    Publication Date: 2024-02-07
    Description: The Baltic Sea has a salinity gradient decreasing from fully marine (〉 25) in the west to below 7 in the central Baltic Proper. Habitat-forming and ecologically dominant mytilid mussels exhibit decreasing growth when salinity 〈 11; however, the mechanisms underlying reduced calcification rates in dilute seawater are not fully understood. Both [HCO−3] and [Ca2+] also decrease with salinity, challenging calcifying organisms through CaCO3 undersaturation (Ω≤1) and unfavourable ratios of calcification substrates ([Ca2+] and [HCO−3]) to the inhibitor (H+), expressed as the extended substrate–inhibitor ratio (ESIR). This study combined in situ monitoring of three southwest Baltic mussel reefs with two laboratory experiments to assess how various environmental conditions and isolated abiotic factors (salinity, [Ca2+], [HCO−3] and pH) impact calcification in mytilid mussels along the Baltic salinity gradient. Laboratory experiments rearing juvenile Baltic Mytilus at a range of salinities (6, 11 and 16), HCO−3 concentrations (300–2100 µmol kg−1) and Ca2+ concentrations (0.5–4 mmol kg−1) reveal that as individual factors, low [HCO−3], pH and salinity cannot explain low calcification rates in the Baltic Sea. Calcification rates are impeded when Ωaragonite ≤ 1 or ESIR ≤ 0.7 primarily due to [Ca2+] limitation which becomes relevant at a salinity of ca. 11 in the Baltic Sea. Field monitoring of carbonate chemistry and calcification rates suggest increased food availability may be able to mask the negative impacts of periodic sub-optimal carbonate chemistry, but not when seawater conditions are permanently adverse, as observed in two Baltic reefs at salinities 〈 11. Regional climate models predict a rapid desalination of the southwest and central Baltic over the next century and potentially a reduction in [Ca2+] which may shift the distribution of marine calcifiers westward. It is therefore vital to understand the mechanisms by which the ionic composition of seawater impacts bivalve calcification for better predicting the future of benthic Baltic ecosystems.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 5
    Publication Date: 2024-02-07
    Description: High alkalinity values observed in coastal seas promote the uptake of CO2 from the atmosphere. However, the alkalinity budget of coastal areas and marginal seas is poorly understood, even though some of the recently observed alkalinity enhancement can be ascribed to riverine fluxes and anaerobic processes in shelf sediments. Here, we investigate the alkalinity budget of the Baltic Sea to identify previously unrecognized alkalinity sources. We quantify the generation of alkalinity and dissolved calcium (Ca) in this marginal sea applying simple mass balance calculations. Using this approach, we identify alkalinity and Ca sources of approximately 324 Gmol yr-1 and 122 Gmol yr-1, respectively, that cannot be ascribed to the riverine input. The magnitude of the Ca source suggests that a major fraction of the excess alkalinity (244 Gmol yr-1) is induced by the dissolution of calcium carbonate (CaCO3). A review of available field data shows that carbonate-bearing rocks at the coast and the seabed of the Baltic Sea are rapidly eroded and may provide sufficient CaCO3 to close the Ca budget. Hence, dissolution of eroded CaCO3 is the most likely source for the Ca enrichment observed in Baltic Sea water. This hypothesis is supported by mass accumulation rates of sediments derived from radioisotope data that are evaluated to derive a basin-wide rate of mud to muddy sand accumulation at the bottom of the Baltic Sea. The resulting value (139 Tg yr-1) exceeds current estimates of riverine particle fluxes into the Baltic Sea by more than one order of magnitude and confirms that rates of till erosion are sufficiently high to account for the Ca and most of the alkalinity excess in Baltic Sea water. Finally, we show that deliberate addition of CaCO3 to sediments deposited in the Baltic Sea could neutralize significant amounts of CO2 and help to achieve net-zero greenhouse gas emissions in the Baltic region.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 6
    Publication Date: 2024-03-14
    Description: Wie soll der Mensch den Klimawandel wirkungsvoll begrenzen? Oberste Priorität haben sicherlich Maßnahmen zur Vermeidung von Treibhausgas-Emissionen. Fakt ist mittlerweile aber auch, dass wir der Atmosphäre in den kommenden Jahrzehnten viel Kohlendioxid entnehmen und sicher einlagern müssen. Kann oder sogar muss uns der Ozean bei dieser Aufgabe helfen? Der neue „World Ocean Review“ (WOR Nr. 8) erläutert diese Frage anhand der Rolle des Ozeans im Kohlenstoffkreislauf der Erde und stellt Vorteile, Risiken und Wissenslücken zu den wichtigsten meeresbasierten Verfahren zur Kohlendioxid-Entnahme vor.
    Type: Book , NonPeerReviewed
    Format: text
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  • 7
    Publication Date: 2024-03-19
    Description: What action should we take for the effective mitigation of climate change? Measures to avoid greenhouse gas emissions are surely the main priority – but the truth is that in the coming decades, we will also have to remove large quantities of carbon dioxide from the atmosphere and store it securely. Can – indeed, should – the ocean aid us in this task? The new World Ocean Review (WOR 8) explores this issue with reference to the oceans' role in the Earth's carbon cycle and looks at the benefits, risks and knowledge gaps around the main marine carbon dioxide removal techniques.
    Type: Book , NonPeerReviewed
    Format: text
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  • 8
    Publication Date: 2024-03-25
    Description: Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere in a changing climate is critical to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe and synthesize data sets and methodology to quantify the five major components of the global carbon budget and their uncertainties. Fossil CO2 emissions (E-FOS) are based on energy statistics and cement production data, while emissions from land-use change (E-LUC), mainly deforestation, are based on land-use and land-use change data and bookkeeping models. Atmospheric CO2 concentration is measured directly, and its growth rate (G(ATM)) is computed from the annual changes in concentration. The ocean CO2 sink (S-OCEAN) is estimated with global ocean biogeochemistry models and observation-based fCO(2) products. The terrestrial CO2 sink (S-LAND) is estimated with dynamic global vegetation models. Additional lines of evidence on land and ocean sinks are provided by atmospheric inversions, atmospheric oxygen measurements, and Earth system models. The resulting carbon budget imbalance (B-IM), the difference between the estimated total emissions and the estimated changes in the atmosphere, ocean, and terrestrial biosphere, is a measure of imperfect data and incomplete understanding of the contemporary carbon cycle. All uncertainties are reported as +/- 1 sigma. For the year 2022, E-FOS increased by 0.9% relative to 2021, with fossil emissions at 9.9 +/- 0.5 GtC yr(-1) (10.2 +/- 0.5 GtC yr(-1) when the cement carbonation sink is not included), and E-LUC was 1.2 +/- 0.7 GtC yr(-1), for a total anthropogenic CO2 emission (including the cement carbonation sink) of 11.1 +/- 0.8 GtC yr(-1) (40.7 +/- 3.2 GtCO(2) yr(-1)). Also, for 2022, G(ATM) was 4.6 +/- 0.2 GtC yr(-1) (2.18 +/- 0.1 ppm yr(-1); ppm denotes parts per million), S-OCEAN was 2.8 +/- 0.4 GtC yr(-1), and S-LAND was 3.8 +/- 0.8 GtC yr(-1), with a B-IM of 0.1 GtC yr(-1) (i.e. total estimated sources marginally too low or sinks marginally too high). The global atmospheric CO2 concentration averaged over 2022 reached 417.1 +/- 0.1 ppm. Preliminary data for 2023 suggest an increase in E-FOS relative to 2022 of +/- 1:1% (0.0% to 2.1 %) globally and atmospheric CO2 concentration reaching 419.3 ppm, 51% above the pre-industrial level (around 278 ppm in 1750). Overall, the mean of and trend in the components of the global carbon budget are consistently estimated over the period 1959-2022, with a near-zero overall budget imbalance, although discrepancies of up to around 1 Gt Cyr(-1) persist for the representation of annual to semi-decadal variability in CO2 fluxes. Comparison of estimates from multiple approaches and observations shows the following: (1) a persistent large uncertainty in the estimate of land-use changes emissions, (2) a low agreement between the different methods on the magnitude of the land CO2 flux in the northern extra-tropics, and (3) a discrepancy between the different methods on the strength of the ocean sink over the last decade. This living-data update documents changes in methods and data sets applied to this most recent global carbon budget as well as evolving community understanding of the global carbon cycle.
    Type: Article , PeerReviewed
    Format: text
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  • 9
    Publication Date: 2023-12-19
    Description: 〈jats:p〉Abstract. Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere in a changing climate is critical to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe and synthesize data sets and methodology to quantify the five major components of the global carbon budget and their uncertainties. Fossil CO2 emissions (EFOS) are based on energy statistics and cement production data, while emissions from land-use change (ELUC), mainly deforestation, are based on land-use and land-use change data and bookkeeping models. Atmospheric CO2 concentration is measured directly, and its growth rate (GATM) is computed from the annual changes in concentration. The ocean CO2 sink (SOCEAN) is estimated with global ocean biogeochemistry models and observation-based fCO2 products. The terrestrial CO2 sink (SLAND) is estimated with dynamic global vegetation models. Additional lines of evidence on land and ocean sinks are provided by atmospheric inversions, atmospheric oxygen measurements, and Earth system models. The resulting carbon budget imbalance (BIM), the difference between the estimated total emissions and the estimated changes in the atmosphere, ocean, and terrestrial biosphere, is a measure of imperfect data and incomplete understanding of the contemporary carbon cycle. All uncertainties are reported as ±1σ. For the year 2022, EFOS increased by 0.9 % relative to 2021, with fossil emissions at 9.9±0.5 Gt C yr−1 (10.2±0.5 Gt C yr−1 when the cement carbonation sink is not included), and ELUC was 1.2±0.7 Gt C yr−1, for a total anthropogenic CO2 emission (including the cement carbonation sink) of 11.1±0.8 Gt C yr−1 (40.7±3.2 Gt CO2 yr−1). Also, for 2022, GATM was 4.6±0.2 Gt C yr−1 (2.18±0.1 ppm yr−1; ppm denotes parts per million), SOCEAN was 2.8±0.4 Gt C yr−1, and SLAND was 3.8±0.8 Gt C yr−1, with a BIM of −0.1 Gt C yr−1 (i.e. total estimated sources marginally too low or sinks marginally too high). The global atmospheric CO2 concentration averaged over 2022 reached 417.1±0.1 ppm. Preliminary data for 2023 suggest an increase in EFOS relative to 2022 of +1.1 % (0.0 % to 2.1 %) globally and atmospheric CO2 concentration reaching 419.3 ppm, 51 % above the pre-industrial level (around 278 ppm in 1750). Overall, the mean of and trend in the components of the global carbon budget are consistently estimated over the period 1959–2022, with a near-zero overall budget imbalance, although discrepancies of up to around 1 Gt C yr−1 persist for the representation of annual to semi-decadal variability in CO2 fluxes. Comparison of estimates from multiple approaches and observations shows the following: (1) a persistent large uncertainty in the estimate of land-use changes emissions, (2) a low agreement between the different methods on the magnitude of the land CO2 flux in the northern extra-tropics, and (3) a discrepancy between the different methods on the strength of the ocean sink over the last decade. This living-data update documents changes in methods and data sets applied to this most recent global carbon budget as well as evolving community understanding of the global carbon cycle. The data presented in this work are available at https://doi.org/10.18160/GCP-2023 (Friedlingstein et al., 2023). 〈/jats:p〉
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 10
    Publication Date: 2023-07-11
    Description: The high surface productivity triggered by nutrient-rich Benguela upwelled waters results in significant enrichment of organic carbon in the sub-surface waters due to enhanced mineralization in the water column and benthic fluxes. Hence, microbial oxygen-consuming processes are promoted, driving oxygen depletion that favours trace gases i.e. methane (CH4) and nitrous oxide (N2O) production at relatively shallow depths. Also, gas-rich subsurface waters are transported towards the surface waters during upwelling, enhancing trace gas sea-air fluxes. Within the EVAR project, we investigate the variability of these fluxes on seasonal and shorter timescales to understand the intensity of the Benguela upwelling system as the source of these greenhouse gases relative to the atmosphere. The data might serve as a base for projections under a changing climate. The fieldwork took place during the cruise SO283 (March 19th – May 25th, 2021) onboard the R/V SONNE from and to Emden (Germany). The main area of the sampling was the Namibian shelf between 18°S and 25°S which is suggested to represent some regional hotspots of trace gas emissions to the atmosphere, in particular in the vicinity of the upwelling cells. Over 260 discrete water samples were collected from the Niskin bottles at different stations for the determination of the concentrations of CH4, N2O, and dissolved inorganic carbon (DIC). 200ml seawater samples were fixed with 200 µL of saturated HgCl2 solution straight after sampling and trace gas was quantified in return. Dissolved CH4 and N2O were measured by an in-house designed purge and trap system with a dynamic headspace method back on land. In brief, a subsample is purged with an inert ultrapure carrier gas of Helium, and the gases are focused on a cryo-trap operated at about -120°C. The volatile compounds are desorbed by rapid heating and analyzed by a gas chromatograph (GC; Agilent 7890B), equipped with capillary columns and a Deans Switch, which directed the components to the flamenionization detector for CH4 detection and electron capture detector ECD for N2O detection. To explore the carbonate system Dissolved Inorganic Carbon (DIC) was measured in the institute. About 5.00 ml of each fixed discrete sample was acidified by 10 % phosphoric acid, resulting in release of inorganic carbon content of the sample. An automated infra-red inorganic carbon analyzer (AIRICA, Marianda, Tulpenweg 28, D-24145 Kiel) equipped with an infrared detector LICOR 7000 (LI-COR Environmental – GmbH, Homburg, Germany) was used to quantify DIC. A 3-fold measurement of the pH was also carried out in 120 ml of discrete samples directly after sampling using the HydroFIA pH system (4H Jena Engineering, 24148 Kiel, Germany). We calculated the average pH value of the corresponding sample after Müller and Rehder (2018) and corresponding total alkalinity and pCO2 after Dickson et al. (2007).
    Keywords: Benguela Upwelling System; Biogeochemical cycle of Trace Gas; Carbon dioxide; CTD/Rosette; CTD-RO; DEPTH, water; EVAR; Event label; LATITUDE; LONGITUDE; Methane; Namibia; Nitrous oxide; oxygen deficient zones; SO283; SO283_28-1; SO283_29-1; SO283_30-1; SO283_31-1; SO283_32-1; SO283_36-1; SO283_37-1; SO283_38-1; SO283_39-1; SO283_43-1; SO283_47-2; SO283_49-1; SO283_50-1; SO283_51-1; SO283_52-1; SO283_53-1; SO283_57-2; SO283_58-2; SO283_59-1; SO283_60-1; SO283_62-1; SO283_64-1; SO283_66-1; SO283_68-1; SO283_69-1; SO283_73-1; SO283_75-1; SO283_77-1; Sonne_2; South Atlantic Ocean; The Benguela Upwelling System under climate change – Effects of VARiability in physical forcing on carbon and oxygen budgets
    Type: Dataset
    Format: text/tab-separated-values, 778 data points
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