Keywords:
Seawater -- Carbon dioxide content.
;
Electronic books.
Type of Medium:
Online Resource
Pages:
1 online resource (361 pages)
Edition:
1st ed.
ISBN:
9780080529226
Series Statement:
Issn Series ; v.Volume 65
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=313598
Language:
English
Note:
Cover -- Contents -- Chapter 1. Equilibrium -- 1.1 The carbonate system -- 1.2 Alkalinity -- 1.3 pH scales -- 1.4 Partial pressure and fugacity -- 1.5 The Revelle factor -- 1.6 Worked out problems -- Chapter 2. Kinetics -- 2.1 Basic concepts of kinetics -- 2.2 Temperature dependence of rate constants -- 2.3 Reactions and rate constants of the carbonate system -- 2.4 Approaching equilibrium: the carbonate system -- 2.5 Approaching isotopic equilibrium: 12C, 13C, and 14C -- 2.6 Diffusion and Reaction -- 2.7 Summary -- Chapter 3. Stable Isotope Fractionation -- 3.1 Notation, abundances, standards -- 3.2 Carbon -- 3.3 Oxygen -- 3.4 Boron -- 3.5 Thermodynamic properties of isotopic substances -- Appendix A: Equilibrium constants -- A.1 CO2: Acidity constants K1* and K2* -- A.2 Acidity constant of true carbonic acid -- A.3 CO2 solubility in water (Henry's law) -- A.4 Ion product of water: KW* -- A.5 Bisulfate ion -- A.6 Hydrogen fluoride -- A.7 Boric acid -- A.8 Phosphoric acid -- A.9 Silicic acid -- A.10 Solubility product of calcite and aragonite -- A.11 Effect of pressure on equilibrium constants -- A.12 Chemical composition of seawater -- A.13 The equation of state of seawater -- Appendix B: From two to six -- Appendix C: Details and Calculations -- C.1 Total alkalinity and charge balance -- C.2 Saturation vapor pressure of water -- C.3 The fugacity of a pure gas -- C.4 Equilibrium at air-sea interface and chemical potential -- C.5 Change CO2 concentration while keeping pH constant -- C.6 The rate constant for the hydroxylation of CO2, k+4 -- C.7 A formula for the equilibration time of CO2 -- C.8 Kinetic rate laws of the carbonate system -- C.9 Derivation of oxygen isotope partitioning -- C.10 Mathematical derivation of the partition function ratio -- Appendix D: Answers to Exercises -- Appendix E: Notation and Symbols -- References -- Index.
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