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  • 1
    Book
    Book
    Boca Raton : CRC Press
    Keywords: Seawater Analysis ; Seawater Analysis ; Aufsatzsammlung ; Meerwasser ; Chemische Eigenschaft ; Meerwasser ; Chemische Eigenschaft
    Type of Medium: Book
    Pages: xii, 401 Seiten , Illustrationen, Diagramme
    ISBN: 1420073060 , 9781420073065 , 9780367385576
    Series Statement: Environmental science and technology
    DDC: 551.46/6
    RVK:
    Language: English
    Note: Literaturangaben. - Index
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  • 2
    Online Resource
    Online Resource
    Boca Raton, FL : CRC Press
    Keywords: Seawater ; Analysis ; Oceanography ; Electronic books
    Type of Medium: Online Resource
    Pages: axii, 401, [2] p. , ill.
    ISBN: 9781420073072
    DDC: 551.46/6
    Language: English
    Note: Includes bibliographical references and index
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  • 3
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A monitor is described which provides the on-line determination of mercury in river water at concentrations from 20 to 1000 ng/L. The measurement includes an on-line digestion with Br–/BrO3 – and UV-radiation. Each determination is controlled by an on-line addition of 50 and 100 ng/L mercury carried out by pre-dilution of a 500 and 1000 ng/L stock solution using sequential injection analysis (SIA). One cycle of analysis takes 20 min and results in nine signals. A five days stand-alone operation has been performed successfully. Details are also published at web page: “http/www.rzbd.fh-hamburg.de/¶∼prmercol”
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2021-02-08
    Description: Wind, chemical enhancement, phytoplankton activity, and surfactants are potential factors driving the air-sea gas exchange of carbon dioxide (CO2). We investigated their effects on the gas transfer velocity of CO2 in a large annular wind-wave tank filled with natural seawater from the North Atlantic Ocean. Experiments were run under 11 different wind speed conditions (ranging from 1.5 ms−1 to 22.8 ms−1), and we increased the water pCO2 concentration twice by more than 950 μatm for two of the seven experimental days. We develop a conceptual box model that incorporated the thermodynamics of the marine CO2 system. Surfactant concentrations in the sea surface microlayer (SML) ranged from 301 to 1015 μgL−1 (as Triton X-100 equivalents) with enrichments ranged from 1.0 to 5.7 in comparison to the samples from the underlying bulk water. With wind speeds up to 8.5 ms−1, surfactants in the SML can reduce the gas transfer velocity by 54%. Wind-wave tank experiments in combination with modeling are useful tools for obtaining a better understanding of the gas transfer velocities of CO2 across the air-sea boundary. The tank allowed for measuring the gas exchange velocity under extreme low and high wind speeds; in contrast, most previous parametrizations have fallen short because measurements of gas exchange velocities in the field are challenging, especially at low wind conditions. High variability in the CO2 transfer velocities suggests that gas exchange is a complex process not solely controlled by wind forces, especially in low wind conditions.
    Type: Article , PeerReviewed
    Format: text
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  • 5
    Publication Date: 2019-09-23
    Description: The sea surface microlayer (SML) covers more than 70% of the Earth’s surface and is the boundary layer interface between the ocean and the atmosphere. This important biogeochemical and ecological system is critical to a diverse range of Earth system processes, including the synthesis, transformation and cycling of organic material, and the air–sea exchange of gases, particles and aerosols. In this review we discuss the SML paradigm, taking into account physicochemical and biological characteristics that define SML structure and function. These include enrichments in biogenic molecules such as carbohydrates, lipids and proteinaceous material that contribute to organic carbon cycling, distinct microbial assemblages that participate in air–sea gas exchange, the generation of climate-active aerosols and the accumulation of anthropogenic pollutants with potentially serious implications for the health of the ocean. Characteristically large physical, chemical and biological gradients thus separate the SML from the underlying water and the available evidence implies that the SML retains its integrity over wide ranging environmental conditions. In support of this we present previously unpublished time series data on bacterioneuston composition and SML surfactant activity immediately following physical SML disruption; these imply timescales of the order of minutes for the reestablishment of the SML following disruption. A progressive approach to understanding the SML and hence its role in global biogeochemistry can only be achieved by considering as an integrated whole, all the key components of this complex environment. Highlights ► The sea surface microlayer is a biogenic film layer at the air-ocean interface. ► Distinct microbial assemblages have defining roles in microlayer functions. ► The sea surface microlayer is fundamentally involved in air-ocean transfer. ► The sea surface microlayer is linked to aerosol production. ► The sea surface microlayer is reservoir of pollutants.
    Type: Article , PeerReviewed
    Format: text
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  • 6
    Publication Date: 2020-11-13
    Description: Biofilm-like properties can form on sea surfaces, but an understanding of the underlying processes leading to the development of these biofilms is not available. We used approaches to study the development of biofilm-like properties at the sea surface, i.e. the number, abundance and diversity of bacterial communities and phytoplankton, the accumulation of gel-like particles and dissolved tracers. During the expedition POS537 we used newly developed and free drifting mesocosms and performed incubation experiments. With these approaches we aim to investigate the role of light and UV radiation as well as the microbes themselves, which lead to the formation of biofilms. With unique microbial interactions and photochemical reactions, sea surface biofilms could be biochemical reactors with significant implications for ocean and climate research, e.g. with respect to the marine carbon cycle, diversity of organisms and oceanatmosphere interactions.
    Type: Report , NonPeerReviewed
    Format: text
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  • 7
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    Carl-von-Ossietzky University Oldenburg, Institute of Chemistry and Biology of the Marine Environment
    In:  Carl-von-Ossietzky University Oldenburg, Institute of Chemistry and Biology of the Marine Environment, Wilhelmshaven, 3 pp.
    Publication Date: 2019-10-07
    Type: Report , NonPeerReviewed
    Format: text
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  • 8
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    Carl-von-Ossietzky University Oldenburg, Institute of Chemistry and Biology of the Marine Environment
    In:  Carl-von-Ossietzky University Oldenburg, Institute of Chemistry and Biology of the Marine Environment, Wilhelmshaven, 4 pp.
    Publication Date: 2019-09-23
    Type: Report , NonPeerReviewed
    Format: text
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  • 9
    Publication Date: 2023-02-08
    Description: MILAN was a multidisciplinary, international study examining how the diel variability of sea-surface microlayer biogeochemical properties potentially impacts ocean-atmosphere interaction, in order to improve our understanding of this globally important process. The sea-surface microlayer (SML) at the air-sea interface is 〈 1 mm deep but it is physically, chemically and biologically distinct from the underlying water and the atmosphere above. Wind-driven turbulence and solar radiation are important drivers of SML physical and biogeochemical properties. Given that the SML is involved in all ocean-atmosphere exchanges of mass and energy, its response to solar radiation, especially in relation to how it regulates the air-sea exchange of climate-relevant gases and aerosols, is surprisingly poorly characterised. MILAN (sea-surface MIcroLAyer at Night) was an international, multidisciplinary campaign designed to specifically address this issue. In spring 2017, we deployed diverse sampling platforms (research vessels, radio-controlled catamaran, free-drifting buoy) to study full diel cycles in the coastal North Sea SML and in underlying water, and installed a land-based aerosol sampler. We also carried out concurrent ex situ experiments using several microsensors, a laboratory gas exchange tank, a solar simulator, and a sea spray simulation chamber. In this paper we outline the diversity of approaches employed and some initial results obtained during MILAN. Our observations of diel SML variability, e.g. the influence of changing solar radiation on the quantity and quality of organic material, and diel changes in wind intensity primarily forcing air-sea CO2 exchange, underline the value and the need of multidisciplinary campaigns for integrating SML complexity into the context of air-sea interaction.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 10
    Publication Date: 2024-02-07
    Description: Transparent exopolymer particles (TEPs) exhibit the properties of gels and are ubiquitously found in the world oceans. TEPs may enter the atmosphere as part of sea-spray aerosol. Here, we report number concentrations of TEPs with a diameter 〉 4.5 µm, hence covering a part of the supermicron particle range, in ambient aerosol and cloud water samples from the tropical Atlantic Ocean as well as in generated aerosol particles using a plunging waterfall tank that was filled with the ambient seawater. The ambient TEP concentrations ranged between 7×102 and 3×104 #TEP m−3 in the aerosol particles and correlations with sodium (Na+) and calcium (Ca2+) (R2=0.5) suggested some contribution via bubble bursting. Cloud water TEP concentrations were between 4×106 and 9×106 #TEP L−1 and, according to the measured cloud liquid water content, corresponding to equivalent air concentrations of 2–4×103 #TEP m−3. Based on Na+ concentrations in seawater and in the atmosphere, the enrichment factors for TEPs in the atmosphere were calculated. The tank-generated TEPs were enriched by a factor of 50 compared with seawater and, therefore, in-line with published enrichment factors for supermicron organic matter in general and TEPs specifically. TEP enrichment in the ambient atmosphere was on average 1×103 in cloud water and 9×103 in ambient aerosol particles and therefore about two orders of magnitude higher than the corresponding enrichment from the tank study. Such high enrichment of supermicron particulate organic constituents in the atmosphere is uncommon and we propose that atmospheric TEP concentrations resulted from a combination of enrichment during bubble bursting transfer from the ocean and a secondary TEP in-situ formation in atmospheric phases. Abiotic in-situ formation might have occurred from aqueous reactions of dissolved organic precursors that were present in particle and cloud water samples, whereas biotic formation involves bacteria, which were abundant in the cloud water samples. The ambient TEP number concentrations were two orders of magnitude higher than recently reported ice nucleating particle (INP) concentrations measured at the same location. As TEPs likely possess good properties to act as INPs, in future experiments it is worth studying if a certain part of TEPs contributes a fraction of the biogenic INP population.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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