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  • 1
    Electronic Resource
    Electronic Resource
    Isotope Dilution MC-ICP-MS Rare Earth Element Analysis of Geochemical Reference Materials NIST SRM 610, NIST SRM 612, NIST SRM 614, BHVO-2G, BHVO-2, BCR-2G, JB-2, WS-E, W-2, AGV-1 and AGV-2 (2004)
    Oxford, UK : Blackwell Publishing Ltd
    Geostandards and geoanalytical research 28 (2004), S. 0 
    Details
    ISSN: 1751-908X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: We present data for the concentrations of eleven rare earth elements (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er, Yb, Lu) in eleven international geochemical reference materials obtained by isotope dilution multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We have analysed both rock powders and synthetic silicate glasses, and the latter provide precise data to support the use of these as reference materials for in situ trace element determination techniques. Our data also provide precise measurements of the abundance of mono-isotopic Pr in both glasses and powders, which allows more accurate constraints on the anomalous redox-related behaviour of Ce during geochemical processes. All materials were analysed in replicate providing data that typically reproduce to better than one percent. Sm/Nd ratios in all these materials also reproduce to better than 0.2% and are accurate to 〈 0.2% and can thus be used as calibrants for Sm-Nd geochronology. Our analyses agree well with existing data on these reference materials. In particular, for NIST SRM 610, USGS BHVO-2, AGV-1 and AGV-2, our measured REE abundances are typically within 〈 2% (and mostly 1%) of REE concentrations previously determined by isotope dilution analysis and thermal ionisation mass spectrometry, consistent with the higher degree of precision and accuracy obtained from isotope dilution techniques. Close agreement of results between basaltic glass reference materials USGS BHVO-2G and BCR-2G and the BHVO-2 and BCR-2 powders from which they were created suggests that little fractionation, concentration or dilution of REE contents occurred during glass manufacture.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1751-908X.2004.tb00760.x
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  • 2
    Electronic Resource
    Electronic Resource
    The Hohonu Batholith of North Westland, New Zealand: granitoid compositions controlled by source H2O contents and generated during tectonic transition (1998)
    Springer
    Contributions to mineralogy and petrology 130 (1998), S. 225-239 
    Details
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Geochemical studies on the Hohonu Batholith, of the West Coast, South Island, New Zealand, have recognised two distinct but chemically related suites of mid-Cretaceous granitoids. The suites are characterised by restricted radiogenic isotopic compositions (Sr(i) = 0.7062 to 0.7085; ɛNd(i) = −4.4 to −6.1), and represent melting of a mafic lithosphere source followed by interaction with Ordovician metasediments. The two suites (Te Kinga Suite and Deutgam Suite) are distinguished by contrasting contents of Al2O3, Na2O, Sr, Ba, Eu and HREE, attributable to different residual asssemblages controlled by differing H2O contents during melting of a metabasaltic source. The relatively mafic, metaluminous, I-type Deutgam Suite represents magmas derived by dehydration melting in equilibrium with an amphibolitic (plagioclase + amphibole) residue. In contrast, the peraluminous, high silica compositions of the Te Kinga Suite were produced by melting at higher H2O contents, reducing the stability of plagioclase and resulting in a melt in equilibrium with a plagioclase-free eclogitic (garnet + amphibole) residue. Residual plagioclase during generation of the Deutgam Suite resulted in lower Al2O3, Na2O, Sr, Ba and Eu contents, whereas residual garnet during generation of the Te Kinga suite resulted in depleted HREE contents. The mid-Cretaceous granitoids of the Hohonu Batholith were generated during a period of rapid tectonic transition from crustal thickening during collision to crustal thinning and core complex formation during extension.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s004100050362
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  • 3
    Electronic Resource
    Electronic Resource
    Fingerprinting feldspar phenocrysts using crystal isotopic composition stratigraphy: implications for crystal transfer and magma mingling in S-type granites (2000)
    Springer
    Contributions to mineralogy and petrology 139 (2000), S. 227-239 
    Details
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Microsampling of cm-scale feldspar crystals within an S-type granite from the Lachlan Fold Belt of southeastern Australia has revealed complex internal Sr and Nd isotopic variations. The observed isotopic zonations are in part interpreted as recording feldspar crystallisation in a dynamically mixing magma system, the isotopic composition of which was varying in response to the influx of more mafic and isotopically more mantle-like magmas, the latter stages of which are now represented in modified form by microgranular enclaves. Similar core to rim isotopic variations in feldspar megacrysts from a microgranular enclave and the adjacent host granite strongly suggest megacrysts in the enclave were transferred from the granitic magma during crystallisation. Feldspar rims have higher 87Sr/86Sri and lower ɛNd(i) than adjacent whole rock analyses, but match those of mineral separates from the surrounding enclave matrix. This suggests that the final stages of megacryst growth occurred in the presence of a component that had previously interacted with a high 87Sr/86Sr, low ɛNd(i) component such as metasedimentary wall rocks. Isotopic heterogeneities are also presererved within different mineral phases in the enclave matrix, suggesting that differing phases grew at differing stages of equilibration between the enclave magma and its host granitic magma. Our results reveal major isotopic heterogeneities on a single crystal and also inter-mineral scale in a pluton which shows well constrained evidence for magma mingling. These results indicate the suitability of feldspars as recorders of isotopic change in magmatic systems, even those which have cooled slowly in the plutonic environment and suggest that much heterogeneity in plutonic systems may be overlooked on a whole rock scale.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s004100000128
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  • 4
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    Origin and transformation of organic carbon from the Hiawatha meteorite crater, North-West Greenland: a preliminary study (2018)
    In:  EPIC3Energy Procedia, 146, pp. 17-22, ISSN: 18766102
    Details
    Publication Date: 2018-07-30
    Description: Glaciofluvial sand draining the newly discovered Hiawatha impact crater under the Greenland Ice Sheet in North-West Greenland contains shocked quartz, glasses derived from direct mineral melts, carbon-bearing glasses, particles of charcoal and transformed ('glassy') charcoal, as well as low-reflectance carbonaceous grains with tiny carbon spherules and mineral fragments. Some of these grains are interpreted as ejecta and perhaps plume material containing sublimated and re-deposited carbon. The only plausible carbon source of this carbon is subfossil Arctic vegetation including small conifer and angiosperm trees older than 50 ka and likely around 2.3 Ma in age, supporting a very young age of the crater.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 5
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    A large impact crater beneath Hiawatha Glacier in northwest Greenland (2018)
    In:  EPIC3Science Advances, 4(11), pp. eaar8173, ISSN: 2375-2548
    Details
    Publication Date: 2018-11-19
    Description: We report the discovery of a large impact crater beneath Hiawatha Glacier in northwest Greenland. From airborne radar surveys, we identify a 31-kilometer-wide, circular bedrock depression beneath up to a kilometer of ice. This depression has an elevated rim that cross-cuts tributary subglacial channels and a subdued central uplift that appears to be actively eroding. From ground investigations of the deglaciated foreland, we identify overprinted structures within Precambrian bedrock along the ice margin that strike tangent to the subglacial rim. Glaciofluvial sediment from the largest river draining the crater contains shocked quartz and other impact-related grains. Geochemical analysis of this sediment indicates that the impactor was a fractionated iron asteroid, which must have been more than a kilometer wide to produce the identified crater. Radiostratigraphy of the ice in the crater shows that the Holocene ice is continuous and conformable, but all deeper and older ice appears to be debris rich or heavily disturbed. The age of this impact crater is presently unknown, but from our geological and geophysical evidence, we conclude that it is unlikely to predate the Pleistocene inception of the Greenland Ice Sheet.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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