Online Resource
San Diego :Elsevier Science & Technology,
Keywords:
Isocyanides.
;
Electronic books.
Type of Medium:
Online Resource
Pages:
1 online resource (293 pages)
Edition:
1st ed.
ISBN:
9780323157339
URL:
https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1174093
DDC:
547.044
Language:
English
Note:
Front Cover -- Isonitrile Chemistry -- Copyright Page -- Table of Contents -- List of Contributors -- Preface -- Chapter 1. The Structure of Isonitriles -- I. The History of the Structure of Isonitriles -- II. Some Physicochemical Consequences of the Structure of the Isocyano Group -- References -- Chapter 2. Isonitrile Syntheses -- I. Introduction -- II. The Dehydration of N-Monosubstituted Formamides and Related α-Eliminations -- III. The Classical Isonitrile Syntheses and Related Reactions -- IV. Miscellaneous Reactions by Which Isonitriles are Formed -- References -- Chapter 3. Kinetics of the Isonitrile-Nitrile Rearrangement -- I. Introduction -- II. Thermal Rearrangement -- III. External Excitation -- References -- Chapter 4. Simple α-Additions -- I. Introduction -- II. α-Addition Reactions of Isonitriles with Reactive Hydrogen Compounds -- III. α-Addition Reactions of Isonitriles with Reactive Halogen Compounds -- IV. Oxidation of Isonitriles -- V. Reduction of Isonitriles -- VI. Reactions with Carbenes and Nitrenes -- VII. Reaction with Organometallic Compounds -- VIII. Radical Reactions of Isonitriles -- IX. Reactions Related to α-Additions -- References -- Chapter 5. Cyclization Reactions -- I. Introduction -- II. Four-Membered Rings -- III. Five-Membered Rings -- IV. Six-Membered Rings -- V. Seven-Membered Rings -- References -- Chapter 6. The Reaction of Isonitriles with Boranes -- I. Isonitrile-Organoborane Reactions -- II. Isonitrile-Organoaluminum and Cyanide-Organoaluminum Reactions -- III. Cyanide-Organoborane Reactions -- IV. Related Reactions: The Reaction of Carbon Monoxide and Other Lewis Bases with Organoboranes -- References -- Chapter 7. The Passerini Reaction and Related Reactions -- I. Introduction -- II. α-Acyloxycarbonamides -- III. The Mechanism of the Passerini Reaction -- IV. Tetrazoles -- V. α-Hydroxyamides.
,
VI. α,γ-Diketoamides -- References -- Chapter 8. Four-Component Condensations and Related Reactions -- I. Introduction and General Remarks -- II. Hydantoin-4-imides and 2-Thiohydantoin-4-imides -- III. Acylated α-Amino- and α-Hydrazinocarbonamides -- IV. Stereoselective Syntheses and the Reaction Mechanism of 4 C C -- V. β-Lactams and Penicillanic Acid Derivatives -- VI. Urethanes -- VII. The Bucherer-Bergs Reaction -- VIII. N-Alkyl-3-acyl-4-hydroquinoline-4-carbonamides -- IX. Diacylimides, Amides, Thioamides, Selenoamides, and Amidines of α-Amino Acids -- X. Tetrazoles -- References -- Chapter 9. Peptide Syntheses -- I. The General Concept -- II. The Present Status of Classical Methods -- III. Potential Advantages of the 4 C C Concept -- IV. Isonitrile and Amine Components-Model Reactions -- V. Tactics of the 4 C C Peptide Synthesis -- References -- Chapter 10. Coordinated Isonitriles -- I. Introduction -- II. Structure and Bonding in Isonitrile Complexes -- III. Reactions of Coordinated Isonitriles -- IV. The Synthesis of Metal Isonitrile Complexes -- References -- Addendum Recent Developments in Isonitrile Chemistry -- Author Index -- Subject Index.
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