In:
Chemical Communications, Royal Society of Chemistry (RSC), Vol. 58, No. 93 ( 2022), p. 12963-12966
Kurzfassung:
We report a rare redox-active Mn 0 metalloradical [Mn(CO) 3 (Ph 2 B( t Bu NHC) 2 )] − (NHC = N-heterocyclic carbene) with countercations [K(2.2.2)crypt] + , [Na(2.2.2)crypt] + , or [Li(DME)(12-crown-4)] + (DME = 1,2-dimethoxyethane), all characterized via single crystal X-ray diffraction. Cyclic voltammograms reveal solvation-dependent Mn I/0 redox potentials that are modeled using the Born equation.
Materialart:
Online-Ressource
ISSN:
1359-7345
,
1364-548X
Sprache:
Englisch
Verlag:
Royal Society of Chemistry (RSC)
Publikationsdatum:
2022
ZDB Id:
1472881-3
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