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  • 1
    Publication Date: 2023-09-13
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The sampling of fluvial sediment is subject to many sources of uncertainty, for example, time and location, and the number of samples collected. It is nevertheless commonly assumed that a sample taken at one time and location provides a somewhat averaged compositional signal. Any spatial or temporal variability of this signal is often neglected. This study investigates how the composition of bed load sand changes over an observation period of 1 year in four river basins with differing bedrock geology in southwestern Germany. Up to 12 bulk sediment samples were taken at the same locations using the same approach and analyzed for their granulometry and geochemistry. The results indicate that (a) different grain sizes yield different compositions due to source rock composition and hydraulic sorting effects, (b) bulk sediment composition changes temporally due to changing grain‐size distribution, and (c) compared to the bulk sample, the composition of narrow grain sizes is temporally more stable but nevertheless has an average variability of 15%. Because heavy mineral‐bound elements such as Zr have the highest variability, we relate a major component of compositional variability to temporally varying heavy mineral concentrations in response to hydrodynamic processes. Mixing modeling demonstrates that the fluvial sand faithfully reflects its catchment geology and that the sediment sources do not change substantially during the observation period, even during a flooding event. We conclude (a) that the causes for compositional variability may be disentangled using chemical and granulometric time series data and (b) that narrow grain sizes yield representative source rock contributions.〈/p〉
    Description: Plain Language Summary: Sediment transported by rivers is generated by the erosion of the rocks present within the river catchment area. The composition of this sediment is controlled by various processes in the catchment, for example, climate, rock type, weathering, and flow strength. Geoscientists can use modern river sediment to understand how these processes impact sediment composition, and then apply this information to the geologic time. Sampling the river sediment is often the first step in such studies, but few studies consider the sources of uncertainty during sampling, for example, time and location of sampling, and number of collected samples. For this study, we returned to the same river location during the course of 1 year to take bulk sediment samples and analyzed how variable the size of sediment grains and the sediment chemistry are. We discovered that different grain sizes yield different chemical compositions, and this is caused by differences in rock type and hydraulic processes. Because the proportion of different grain sizes in the bulk sediment changes over the year due to water flow conditions, the chemistry of the bulk sediment sample changes over the year. We provide some quantitative estimates for this variability that should be considered in similar studies.〈/p〉
    Description: Key Points: Bed load sand from 4 rivers was sampled monthly over the course of 1 year to analyze the temporal compositional variability. Composition is grain‐size‐dependent, and narrow grain‐size fractions show less variability than bulk sediment samples. Composition changes during the year, and this is related to changing grain‐size distributions rather than changing sediment sources.
    Description: https://doi.pangaea.de/10.1594/PANGAEA.959006
    Keywords: ddc:551.9 ; geochemistry ; provenance ; grain‐size ; variability ; bed load ; fluvial sediment
    Language: English
    Type: doc-type:article
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of metamorphic geology 20 (2002), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: A metamorphic field gradient has been investigated in the Moldanubian zone of the central European Variscides encompassing, from base to the top, a staurolite–kyanite zone, a muscovite–sillimanite zone, a K-feldspar–sillimanite zone, and a K-feldspar–cordierite zone, respectively. The observed reaction textures in the anatectic metapsammopelites of the higher grade zones are fully compatible with experimental data and petrogenetic grids that are based on fluid-absent melting reactions. From structural and microstructural observations it can be concluded that the boundary between the kyanite–staurolite zone and the muscovite- and K-feldspar–sillimanite zones coincides with an important switch in deformation mechanism(s). Besides minor syn-anatectic shearing (melt-enhanced deformation), microstructural criteria point (a) to a switch in deformation mechanism from rotation recrystallization (climb-accommodated dislocation creep) to prism slip and high-temperature (fast) grain boundary migration in quartz (b) to the activity of diffusion creep in quartz–feldspar layers, and (c) to accommodation of strain by intense shearing in fibrolite–biotite layers. It is suggested that any combination of these deformation mechanisms will profoundly affect the rheological characteristics of high-grade metamorphic rocks and significantly lower rock strength. Hence, the boundary between these zones marks a major rheological barrier in the investigated cross section and probably also in other low- to medium-pressure/high-temperature areas. At still higher metamorphic grades (K-feldspar-cordierite zone), where the rheologically critical melt percentage is reached, rock rheology is mainly governed by the melt and other deformation mechanisms are of minor importance. In the study area, the switch in deformation mechanism(s) is responsible for large-scale strain partitioning and concentration of deformation within the higher-temperature hanging wall during top-to-the-S thrusting, thus preserving a more complete petrostructural record within the rocks of the footwall including indications for a ?Devonian high- to medium-pressure/medium-temperature metamorphic event. Thrusting is accompanied by diapiric ascent of diatexites of the K-feldspar-cordierite zone and infolding of the footwall, suggesting local crustal overturn in this part of the Moldanubian zone.
    Type of Medium: Electronic Resource
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  • 3
    facet.materialart.
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    In:  Berichte der Deutschen Mineralogischen Gesellschaft : Beihefte zum European Journal of Mineralogy ; Vol. 15, 1
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/conferenceObject
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  • 4
    Publication Date: 2022-12-05
    Description: Hydrothermal alteration is a common process in active geothermal systems and can significantly change the physiochemical properties of rocks. To improve reservoir assessment and modeling of high-temperature geothermal resources linked to active volcanic settings, a detailed understanding of the reservoir is needed. The Los Humeros Volcanic Complex, hosting the third largest exploited geothermal field in Mexico, represents a natural laboratory to investigate the impact of hydrothermal processes on the rock properties through andesitic reservoir cores and outcropping analogs. Complementary petrographic and chemical analyses were used to characterize the intensities and facies of hydrothermal alteration. The alteration varies from argillic and propylitic facies characterized by no significant changes of the REE budget indicating an inert behavior to silicic facies and skarn instead showing highly variable REE contents. Unaltered outcrop samples predominantly feature low matrix permeabilities (〈 10–17 m2) as well as low to intermediate matrix porosities (〈 5–15%), thermal conductivities (0.89–1.49 W m−1 K−1), thermal diffusivities (~ 0.83 10–6 m2 s−1), and sonic wave velocities (VP: ~ 2800–4100 m s−1, VS: ~ 1600–2400 m s−1). Average magnetic susceptibility and specific heat capacity range between 2.4–7.0 10–3 SI and 752–772 J kg−1 K−1, respectively. In contrast, the hydrothermally altered reservoir samples show enhanced porosities (~ 7–23%), permeabilities (10–17–10–14 m2), and thermal properties (〉 1.67 W m−1 K−1; 〉 0.91 10–6 m2 s−1), but a significant loss of magnetic susceptibility (10–3–10–6 SI). In particular, this latter characteristic appears to be a suitable indicator during geophysical survey for the identification of hydrothermalized domains and possible pathways for fluids. The lack of clear trends between alteration facies, alteration intensity, and chemical indices in the studied samples is interpreted as the response to multiple and/or repeated hydrothermal events. Finally, the proposed integrated field-based approach shows the capability to unravel the complexity of geothermal reservoir rocks in active volcanic settings.
    Type: info:eu-repo/semantics/article
    Format: application/pdf
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  • 5
    Publication Date: 2023-08-25
    Description: Hydrothermal alteration is a common process in active geothermal systems and can significantly change the physiochemical properties of rocks. To improve reservoir assessment and modeling of high-temperature geothermal resources linked to active volcanic settings, a detailed understanding of the reservoir is needed. The Los Humeros Volcanic Complex, hosting the third largest exploited geothermal field in Mexico, represents a natural laboratory to investigate the impact of hydrothermal processes on the rock properties through andesitic reservoir cores and outcropping analogs. Complementary petrographic and chemical analyses were used to characterize the intensities and facies of hydrothermal alteration. The alteration varies from argillic and propylitic facies characterized by no significant changes of the REE budget indicating an inert behavior to silicic facies and skarn instead showing highly variable REE contents. Unaltered outcrop samples predominantly feature low matrix permeabilities (〈 10–17 m2) as well as low to intermediate matrix porosities (〈 5–15%), thermal conductivities (0.89–1.49 W m−1 K−1), thermal diffusivities (~ 0.83 10–6 m2 s−1), and sonic wave velocities (VP: ~ 2800–4100 m s−1, VS: ~ 1600–2400 m s−1). Average magnetic susceptibility and specific heat capacity range between 2.4–7.0 10–3 SI and 752–772 J kg−1 K−1, respectively. In contrast, the hydrothermally altered reservoir samples show enhanced porosities (~ 7–23%), permeabilities (10–17–10–14 m2), and thermal properties (〉 1.67 W m−1 K−1; 〉 0.91 10–6 m2 s−1), but a significant loss of magnetic susceptibility (10–3–10–6 SI). In particular, this latter characteristic appears to be a suitable indicator during geophysical survey for the identification of hydrothermalized domains and possible pathways for fluids. The lack of clear trends between alteration facies, alteration intensity, and chemical indices in the studied samples is interpreted as the response to multiple and/or repeated hydrothermal events. Finally, the proposed integrated field-based approach shows the capability to unravel the complexity of geothermal reservoir rocks in active volcanic settings.
    Type: info:eu-repo/semantics/article
    Format: application/pdf
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