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  • 1
    Publication Date: 2016-03-07
    Description: Biogas is becoming an increasingly important resource of energy production from biomass, and a number of alternative technologies are proposed for its production and upgrading. However, in spite of the increasing number of accidents recorded, scarce attention was dedicated to date to the control and mitigation of biogas hazards. In the present study, inherent safety of biogas technologies was addressed. A method for the selection of inherently safer alternatives during early design stages was further developed and combined to a Monte Carlo sensitivity analysis, accounting for uncertainty of input parameters and addressing the robustness of the ranking provided. The method was applied to the assessment of several alternative reference process schemes for biogas production and upgrading. The results allowed the identification of critical safety issues and the ranking of inherently safer solutions. This article is protected by copyright. All rights reserved.
    Print ISSN: 0001-1541
    Electronic ISSN: 1547-5905
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 2
    Publication Date: 2012-01-01
    Description: The role of antagonistic organismal interactions in the production of long-term macroevolutionary trends has been debated for decades. Some evidence seems to suggest that temporal trends in predation frequency share a common causative mechanism with genus-level diversity, whereas studies on the role of parasites in “shaping” the evolutionary process are rare indeed. Digenean trematodes (Phylum Platyhelminthes) infest molluscs in at least one stage of their complex life cycle. Trematodes leave characteristic oval-shaped pits with raised rims on the interior of their bivalve hosts, and these pits are preserved in the fossil record. Here we survey 11,785 valves from the Pleistocene–Holocene deposits of the Po Plain and from nearby modern coastal environments on the northeast Adriatic coast of Italy. Of these, 205 valves exhibited trematode-induced pits. Trematodes were selective parasites in terms of host taxonomy and host body size. Infestation was restricted to lower shoreface/transition-to-platform paleoenvironments. During the Holocene, individuals from the transgressive systems tract were significantly more likely to be infested than those from highstand systems tracts. Temporal trends in infestation frequency cannot be explained as an ecological/evolutionary phenomenon (e.g., the hypothesis of escalation); instead the trend seems controlled by environmental variation induced by glacio-eustatic sea-level changes and inadequate sampling. Because this interaction appears to be ephemeral, both temporally and spatially, it is not likely that any selective pressure would be continuous over geologic time in this region. Furthermore, these results support the hypothesis that antagonistic interactions are lower in the northern Adriatic Sea in comparison to other midlatitude shallow marine settings.
    Print ISSN: 0094-8373
    Electronic ISSN: 0094-8373
    Topics: Geosciences
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  • 3
    Publication Date: 2021-03-08
    Description: The Valle di Manche (VdM) section (Calabria, Southern Italy), a candidate to host the Middle Pleistocene Global Stratotype Section and Point, offers the opportunity to investigate the ostracod turnover along a continuous, tens m-thick (ca. 45 m) shelf succession of Early-Middle Pleistocene age (MISs 22- 18), and compare it against other palaeoenvironmental (i.e., molluscs) and palaeoclimate (Uvigerina peregrina δ 18O values) proxies. High-resolution (ca. 1 sample/meter) ostracod fauna quantitative data, coupled with gradient analyses (Dentrended Correspondence Analysis-DCA and nonmetric MultiDimensional Scaling-nMDS), document a strong relationship between changes in faunal composition and lithofacies vertical stacking patterns The comparison between the mollusk- and ostracod-derived ordination data demonstrates that the meio- and macro-faunal turnover are guided by a common complex gradient: bathymetry. The integrated ostracod-mollusc gradient analysis also provides trend in water depths along the section, highlighting to what extent such multivariate approach can improve the palaeoenvironmental and sequence stratigraphic interpretation of ancient shallow marine successions. When plotted stratigraphically, ordination major axis sample scores reveal two increasing-decreasing patterns in palaeowater depth that fit well with the T-R cycles previously identified. Palaeobathymetric estimates combined with the vertical distribution of key ostracod groups (i.e., epiphytic taxa on sandy substrates vs. deep-sea mud lover taxa) allow refining depositional trends, stratal stacking patters and position of previously not well resolved sequence stratigraphic surfaces within each T-R cycle (e.g., Transgressive Surface-TS). Indeed, two rapid increases in water depth values mark the TSs that separate progradational (LST) from retrogradational (TST) stratal stacking patterns of shelf deposits. The TSs, which underline fine-grained successions dominated by deep-sea mud lover taxa, are invariably constrained to the inception of interglacials MIS 21 and MIS 19, identified within the VdM section by δ 18O values. Within both the VdM T-R cycles, the deepest conditions (ca. 140 m of water depth) are invariably identified within the Neopycnodonte unit, slightly above of the lightest δ18O intervals. The overlying decreasing bathymetric trend, coupled with shifts in ostracod ecological groups, allows to identify in the bryozoans lithofacies the highstand+falling stage system tracts, also tracked by a progressively heavier δ18O record. More stable palaeobathymetric conditions (around 40-45 m of water depth) characterize the overlying silt-sand deposits (lithofacies C3-D) dominated by epiphytic species and showing the heaviest δ18O values.
    Description: Published
    Description: 127-138
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-05-12
    Description: The on-land marine Valle di Manche section (Crotone Basin, Calabria, Southern Italy), one of the candidates to host the GSSP of the Middle Pleistocene (“Ionian”) Stage, preserves a manifold record of independent chronological, paleoclimatic and stratigraphic proxies that permit a straightforward correlation with marine and terrestrial reference records at the global scale. In particular, the section holds an excellent record of the Matuyama-Brunhes magnetic reversal, which occurs in the midst of Marine Isotope Stage (MIS) 19. We report on a complete revision of the section that improves dramatically the available dataset, especially in the stratigraphic interval straddling the Lower-Middle Pleistocene boundary. Our benthic δ18O record provides evidence that the Matuyama-Brunhes transition, the stratigraphic position of which is marked by a prominent tephra (the “Pitagora ash”), occurred during full MIS 19, in agreement with many records worldwide. We obtained an age of 786.9 ± 5 ka for the Matuyama-Brunhes magnetic reversal and pinpointed the paleomagnetic transition of to a 3 cm-thick interval, indicating that the event was very fast. Since the section fulfills all the requirements to host the GSSP of the Ionian Stage, we propose that the boundary should be placed at the base of the “Pitagora ash”, ca. 12.5 cm below the midpoint of the Matuyama-Brunhes reversal.
    Description: Published
    Description: 31-48
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: 5A. Paleoclima e ricerche polari
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2017-08-25
    Description: Understanding past seasonal temperature variability in the ocean is essential to evaluate the effects of future climate change on marine ecosystems. Here, we estimate seasonal amplitudes and average water temperature from stable oxygen isotope (δ18Oshell) values assuming δ18Owater values of 0.9±0.1permill (V-SMOV). Fossil valves of the bivalve Arctica islandica were collected from three Pleistocene successions (middle-late Calabrian) in Italy. Biostratigraphic analyses from Tacconi Quarry deposits (Rome) indicate an age between 1.6 and 1.2 Ma, while Augusta and Cutrofiano (Lecce) successions are slightly more recent (1.1 and 0.62 Ma, respectively). Prior to carbonate geochemical analysis, we checked the shells for potential diagenetic alterations (e.g., from aragonite to calcite). Stable oxygen isotope (δ18Oshell) profiles of eleven fossil A. islandica valves all depict a relatively low seasonality scenario. δ18Oshell amplitudes vary between 0.4permill and 1.1permill implying a reconstructed seasonal water temperature amplitude of 1.7 ̊C to 4.8 ̊C. The reconstructed average water temperature for the Sicilian population (i.e., 9 valves) is 9.5±0.47 ̊C for δ18Owater 0.9±0.1permill and coincides well with temperature requirements for modern A. islandica. The low seasonality scenario (ca. 3 ̊C) represented by the shells and the low reconstructed water temperatures, colder than modern water temperatures let to the conclusion that the shells lived during a maximum glacial phase when relatively constant water temperatures prevailed throughout the year.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
    Format: application/pdf
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  • 6
    Publication Date: 2020-02-25
    Description: The 10Be/9Be ratio is commonly employed as a tool for establishing the stratigraphic position of paleomagnetic excursions and reversals whenever the traditional paleomagnetic approach fails to provide conclusive results. In particular, it is held that 10Be production rates in the atmosphere depend on the strength of the Earth’s magnetic field, and the fallout and deposition of cosmogenic beryllium at the surface happen on a very short time scale. However, investigations performed on terrestrial and marine successions demonstrate that the 10Be record and the paleomagnetic signal are often asynchronous. Mechanisms that control the conveyance and deposition of cosmogenic 10Be to the seafloor are still ambiguous and poorly documented. Here, we discuss the dynamics of 10Be in a central Mediterranean marginal marine depositional scenario characterized by a pervasive terrigenous influx. Our data show that a very close correlation exists between 10Be concentrations and the local proxy of rainfall rates and regimes (pollen), indicating that a considerable 10Be transport from the mainland may occur in response to the remobilization of terrestrial reservoirs during periods of increased runoff. Superimposed is a dynamic oceanographic setting that further controls the preservation potential of 10Be at the bottom, in terms of changing water chemistry and/or composition of the sedimentary flux to the seafloor. Results of our investigation suggest that, in particular environmental and depositional settings, the interplay between climate, terrigenous yield and oceanography may jeopardize the sedimentary depiction of the meteoric 10Be contribution, thus challenging the use of 10Be for tracking the stratigraphic position of geomagnetic reversals.
    Description: Published
    Description: 106039
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Keywords: 10Be record, Matuyama-Brunhes, MIS 19, paleoclimatic proxies ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2019-03-06
    Description: Ostracod faunal turnover and oxygen isotope data (foraminifera) along the Valle di Manche (VdM) section are herein compiled. Specifically, the material reported in this work includes quantitative palaeoecological data and patterns of ostracod fauna framed within a high-resolution oxygen isotope stratigraphy (δ18O) from Uvigerina peregrina. In addition, the multivariate ostracod faunal stratigraphic trend (nMDS axis-1 sample score) is calibrated using bathymetric distributions of extant molluscs sampled from the same stratigraphic intervals along the VdM section. Data and analyses support the research article "Dynamics of benthic marine communities across the Early-Middle Pleistocene boundary in the Mediterranean region (Valle di Manche, Southern Italy): biotic and stratigraphic implications" Rossi et al. [1].
    Description: Published
    Description: 1099-1107
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2018-10-01
    Description: High-resolution palaeomagnetic and rock magnetic investigations on the Valle di Manche section (Crotone Basin, Calabria, Southern Italy) provide a detailed record of the Matuyama-Brunhes (M-B) reversal that, to our best knowledge, is the only available record of the last geomagnetic reversal for the Mediterranean on-land marine stratigraphy. The M-B transition can be pinpointed precisely, as it develops within a 3-cm-thick interval located just above a prominent tephra layer (the “Pitagora ash”) where the sedimentation rates are about 27 cm/kyr. Demagnetization analyses indicate a stable palaeomagnetic behaviour throughout the section for both normal and reversed polarity directions, with demagnetization vectors aligned toward the origin of Zijderveld diagrams after the removal of a small viscous low-coercivity remanence component. In the lower part of the studied interval, some samples acquired a spurious gyromagnetic remanent magnetization (GRM) during AF demagnetization in high fields. Rock magnetic analyses confirm that magnetite is the main magnetic carrier for all measured specimens, which also have an abundant paramagnetic fraction. Only the lower part of the record, well below the M-B boundary, is characterized by a downward-increasing presence of iron sulphides (greigite). According to our chronology, which is based on a robust, cross-validated age model, the final reverse-to-normal directional change of the M-B transition occurred at ca. 786.9 ± 5 ka (error includes uncertainty in orbital tuning) and was very rapid, of the order of 100 years or less.
    Description: Published
    Description: 1-15
    Description: 1A. Geomagnetismo e Paleomagnetismo
    Description: JCR Journal
    Keywords: Magnetostratigraphy ; Matuyama-Brunhes transition ; Southern Italy ; Middle Pleistocene ; MIS 19 ; Paleomagnetism
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2021-01-26
    Description: Understanding past seasonal temperature variability in the ocean is essential to evaluate the effects of future climate change on marine ecosystems. Here, we estimate seasonal water temperature amplitudes from stable oxygen isotope (δ18Oshell) values of fossil shells of Arctica islandica (assuming δ18Owater = + 0.9 ± 0.1‰ V-SMOW). Specimens were collected from three Pleistocene successions (Emilian and Sicilian substages of the Calabrian) in Central and Southern Italy (i.e., Rome, Lecce and Sicily). Biostratigraphic analyses from Rome Quarry deposits indicate an age between 1.6 and 1.2 Ma, whereas Sicily and Lecce successions are slightly more recent (between 1.1 and 0.62 Ma). Prior to carbonate geochemical analysis, we checked the shells for potential diagenetic alterations (e.g., from aragonite to calcite) using confocal Raman microscopy. δ18Oshell transects indicate an annual temperature amplitude of about 3 °C during the Early Pleistocene. This is in sharp contrast to reconstructions based on faunal assemblages, according to which the simultaneous occurrence of boreal and warm-water species in the Calabrian Mediterranean Sea suggests a much higher seasonality (ca. 10 °C). The low seasonality and the relatively cold water (9–10 °C) indicate the outcrops represent colder climatic conditions compared to modern times, and suggest the occurrence of a maximum glacial phase.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 10
    Publication Date: 2016-06-14
    Description: Understanding the climate of the past, in particular seasonal temperature amplitudes, is essential to evaluate the effects of future climate change on marine ecosystems. The Mediterranean is of particular importance, because of its crucial role in modern ocean atmosphere phenomena such as the North Atlantic Oscillation (NAO). We analyzed fossil shells of the bivalve Arctica islandica collected from Pleistocene successions in Central and Southern Italy (i.e., Rome, Lecce and Sicily). According to preliminary biostratigraphic data the studied deposits belong to the middle Calabrian, between 1.2-0.9 Ma for the Sicily outcrop and 1.4-1.2 Ma for the Rome and Lecce outcrops. Prior to isotope geochemical analysis confocal Raman microscopy measurements were conducted to detect potential diagenetic alterations (e.g., from aragonite to calcite). The seasonal water temperature amplitude was reconstructed using stable oxygen isotope (δ18O) values, which were derived by micro-milling and Isotope Ratio Mass Spectrometry. Analysis of the growth patterns (on-going research) revealed ontogenetic ages of up to 210 years. These time series are used for the identification of multi-year (i.e., decadal) patterns, such as the NAO. First results of our study indicate that seasonality was remarkably low during the studied geological epoch. This is in sharp contrast to previous assumptions according to which the simultaneous occurrence of boreal (A. islandica) and warm-water species in the Mediterranean Sea during the Pleistocene can be explained by high seasonality. Different links and scenarios on a regional as well as a bigger scale will be discussed.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
    Format: application/pdf
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