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  • 1
    Publication Date: 2024-02-07
    Description: Submarine hydrothermal systems along active volcanic ridges and arcs are highly dynamic, responding to both oceanographic (e.g., currents, tides) and deep-seated geological forcing (e.g., magma eruption, seismicity, hydrothermalism, and crustal deformation, etc.). In particular, volcanic and hydrothermal activity may also pose profoundly negative societal impacts (tsunamis, the release of climate-relevant gases and toxic metal(loid)s). These risks are particularly significant in shallow (〈1000m) coastal environments, as demonstrated by the January 2022 submarine paroxysmal eruption by the Hunga Tonga-Hunga Ha’apai Volcano that destroyed part of the island, and the October 2011 submarine eruption of El Hierro (Canary Islands) that caused vigorous upwelling, floating lava bombs, and natural seawater acidification. Volcanic hazards may be posed by the Kolumbo submarine volcano, which is part of the subduction-related Hellenic Volcanic Arc at the intersection between the Eurasian and African tectonic plates. There, the Kolumbo submarine volcano, 7 km NE of Santorini and part of Santorini’s volcanic complex, hosts an active hydrothermal vent field (HVF) on its crater floor (~500m b.s.l.), which degasses boiling CO 2 –dominated fluids at high temperatures (~265°C) with a clear mantle signature. Kolumbo’s HVF hosts actively forming seafloor massive sulfide deposits with high contents of potentially toxic, volatile metal(loid)s (As, Sb, Pb, Ag, Hg, and Tl). The proximity to highly populated/tourist areas at Santorini poses significant risks. However, we have limited knowledge of the potential impacts of this type of magmatic and hydrothermal activity, including those from magmatic gases and seismicity. To better evaluate such risks the activity of the submarine system must be continuously monitored with multidisciplinary and high resolution instrumentation as part of an in-situ observatory supported by discrete sampling and measurements. This paper is a design study that describes a new long-term seafloor observatory that will be installed within the Kolumbo volcano, including cutting-edge and innovative marine-technology that integrates hyperspectral imaging, temperature sensors, a radiation spectrometer, fluid/gas samplers, and pressure gauges. These instruments will be integrated into a hazard monitoring platform aimed at identifying the precursors of potentially disastrous explosive volcanic eruptions, earthquakes, landslides of the hydrothermally weakened volcanic edifice and the release of potentially toxic elements into the water column.
    Type: Article , PeerReviewed
    Format: text
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  • 2
    Publication Date: 2020-12-10
    Description: The most recent eruptive activity of Turrialba volcano began on the 5th of January 2010, after more than a century of dormancy. The fragmentation process and aerodynamic behavior of the ash from Turrialba’s vulcanian eruptions were investigated by combining grain-size, petrography, mineralogy, Scanning Electron Microscopy (SEM) and Energy Dispersive System (EDS) analyses. The ash components include variable percentages of accessory fresh (no necessary juvenile) to hydrothermally altered lithics (15 - 50 % vol.) with hydrothermal minerals (≤ 12 % vol.: anhydrite, gypsum, bassanite, alunite, hexahydrite, pyrite, heulandite, native sulfur), clay minerals (8 - 17 % vol.: montmorillonite, halloysite, allophane), and a smaller quantity of fresh glassy ashes (5 - 49 % vol.) as fragments and shards (3 - 20 % vol. tackylite and 2 - 26 % vol. sideromelane), as well as primary and eroded/recycled phenocrysts (3 - 13 % vol.: 1 - 5% vol. plagioclase, 1 - 7 % vol. pyroxene, 0 - 1 % vol. olivine, 0 - 6 % vol. opaques, cristobalite and tridimite), and xenocrysts (≤ 1 % vol.: riebeckite and biotite). The secondary minerals were sourced from the deeper to surficial hydrothermal system. Textural features identified in ash particles (90 - 350 μm) suggest that they were formed by brittle fragmentation of vesicle-poor magma/water interaction; molten structures seems to be related to the ductile behavior of some fragments, probably due to the high temperature (〉 600 °C) of the fumarolic/magmatic system. The percentage of juvenile components was low (1 - 2 % vol.) at the first opening eruptive phase in January 2010, and it increased steadily until the end of 2016 (ca. 12 - 25 % vol.) . The ash eruptions in the Western Crater from 2014 to 2016 were related to one and later two or three simultaneously active vents fed by distinct conduit branches. The alternation of volcanic explosions (VEI: 0 - 2), from closed conduit and the formation of new craters, to open system with phreatomagmatic events, and the repose intervals (inter-eruptive exhalative degassing), were controlled by the rate at which magma ascended and remained in the volcanic edifice. The recent tephra sequence consists of a complex succession of layers generated by contrasting fragmentation and transportation dynamics. They resulted from fully diluted, low temperature (〈 300 °C), pyroclastic density currents (wet surge deposits), originated by short-lived, singlepulse, column collapse of phreatomagmatic columns, which traveled short distances (〈 1000 m) from the vent area and surmounted topographic obstacles, and simultaneous fallout and ballistic ejecta. The fine material, in continuous suspension within the uppermost part of the convective plume, was dispersed into the atmosphere and finally settled down on the Valle Central. The quiescent phases could be related to a temporal cooling of the magmatic dike system or to a waning of magmatic activity at depth. Sequential fragmentation/transport theory (SFT) was used to decompose grain-size distributions into five different sub-populations. A new way of using the resultant fragmentation coefficient to assign sub-populations to different fragmentation mechanisms, even in cases when modes overlapped, is presented. For the first time the corresponding results are consistent with the phreatomagmatic eruptions, as well as with those derived from ab initio fractal model.
    Description: Published
    Description: 7-60
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: N/A or not JCR
    Keywords: Volcanic ash, vulcanian eruptions, pheatomagmatism, eruptive column collapse, pyroclastic surges, hydrothermal alteration, granulometry, SFT, Turrialba volcano, Costa Rica. ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2021-03-01
    Description: A new period of eruptive activity started at Turrialba volcano, Costa Rica, in 2010 after almost 150 years of quiescence. This activity has been characterized by sporadic explosions whose frequency clearly increased since October 2014. This study aimed to identify the mechanisms that triggered the resumption of this eruptive activity and characterize the evolution of the phenomena over the past 2 years. We integrate 3He/4He data available on fumarole gases collected in the summit area of Turrialba between 1999 and 2011 with new measurements made on samples collected between September 2014 and February 2016. The results of a petrological investigation of the products that erupted between October 2014 and May 2015 are also presented. We infer that the resumption of eruptive activity in 2010 was triggered by a replenishment of the plumbing system of Turrialba by a new batch of magma. This is supported by the increase in 3He/4He values observed since 2005 at the crater fumaroles and by comparable high values in September 2014, just before the onset of the new eruptive phase. The presence of a number of fresh and juvenile glassy shards in the erupted products increased between October 2014 and May 2015, suggesting the involvement of new magma with a composition similar to that erupted in 1864–1866. We conclude that the increase in 3He/4He at the summit fumaroles since October 2015 represents strong evidence of a new phase of magma replenishment, which implies that the level of activity remains high at the volcano.
    Description: Published
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Turrialba volcano ; eruptive activity ; 3He/4He ; fumarole gases ; glassy shards ; juvenile component ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2021-02-10
    Description: San Cristóbal volcano in northwest Nicaragua is one of the most active basaltic–andesitic stratovolcanoes of the Central American Volcanic Arc (CAVA). Here we provide novel constraints on the volcano's magmatic plumbing system, by presenting the first direct measurements of major volatile contents in mafic-to-intermediate glass inclusions from Holocene and historic-present volcanic activity. Olivine-hosted (forsterite [Fo] b80; Fob80) glass inclusions from Holocene tephra layers contain moderate amounts of H2O (0.1–3.3 wt%) and S and Cl up to 2500 μg/g, and define the mafic (basaltic) endmember component. Historic-present scoriae and tephra layers exhibit more-evolved olivines (Fo69–72) that contain distinctly lower volatile contents (0.1–2.2 wt% H2O, 760–1675 μg/g S, and 1021–1970 μg/g Cl), and represent a more-evolved basaltic–andesitic magma. All glass inclusions are relatively poor in CO2, with contents reaching 527 μg/g (as measured by nanoscale secondary ion mass spectrometry), suggesting pre- to postentrapment CO2 loss to a magmatic vapor. We use results of Raman spectroscopy obtained in a population of small (b50 μm) inclusions with CO2-bearing shrinkage bubbles (3–12 μm) to correct for postentrapment CO2 loss to bubbles, and to estimate the original minimumCO2 content in San Cristóbal parental melts at ~1889 μg/g, which is consistent with the less-CO2-degassed melt inclusions (MI) (N1500 μg/g) found in Nicaragua at Cerro Negro, Nejapa, and Granada. Models of H2O and CO2 solubilities constrain the degassing pathway of magmas up to 425 MPa (~16 km depth), which includes a deep CO2 degassing step (only partially preserved in the MI record), followed by coupled degassing of H2O and S plus crystal fractionation at magma volatile saturation pressures from ∼195 to b10 MPa. The variation in volatile contents from San Cristóbal MI is interpreted to reflect (1) Holocene eruptive cycles characterized by the rapid emplacement of basaltic magma batches, saturated in volatiles, at depths of 3.8–7.4 km, and (2) the ascent of more-differentiated and cogenetic volatile-poor basaltic andesites during historic-present eruptions, having longer residence times in the shallowest (b3.4 km) and hence coolest regions of the magmatic plumbing system. We also report the first measurements of the compositions of noble-gas isotopes (He, Ne, and Ar) in fluid inclusions in olivine and pyroxene crystals. While the measured 40Ar/36Ar ratios (300–304) and 4He/20Ne ratios (9–373) indicate some degree of air contamination, the 3He/4He ratios (7.01–7.20 Ra) support a common mantle source for Holocene basalts and historic-present basaltic andesites. The magmatic source is interpreted as generated by a primitive MORB-like mantle, that is influenced to variable extents by distinct slab fluid components for basalts (Ba/La ~ 76 and U/Th ~ 0.8) and basaltic andesites (Ba/La ~ 86 and U/Th ~ 1.0) in addition to effects of magma differentiation. These values for the geochemical markers are particularly high, and their correlation with strong plume CO2/S ratios from San Cristóbal is highly consistent with volatile recycling at the CAVA subduction zone, where sediment involvement in mantle fluids influences the typical relatively C-rich signature of volcanic gases in Nicaragua.
    Description: Published
    Description: 131-148
    Description: 1V. Storia eruttiva
    Description: JCR Journal
    Keywords: San Cristóbal, Volatiles, Melt inclusions, NanoSIMS, Multi-GAS, Noble gases ; Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2021-05-11
    Description: We use the chemical and isotopic composition of volcanic gases and steam condensate, in situ measurements of plume composition and remote measurements of SO2 flux to constrain volatile sources and characterize subvolcanic conditions at three persistently degassing and seismically active volcanoes within the Katmai Volcanic Cluster (KVC), Alaska:Mount Martin,Mount Mageik and Trident. In situ plume measurements of gas composition were collected at all three volcanoes usingMultiGAS instruments to calculate gas ratios (e.g. CO2/H2S, SO2/H2S and H2O/H2S), and remote measurements of SO2 column density were collected from Mount Martin and Mount Mageik by ultraviolet spectrometer systems to calculate SO2 fluxes. Fumaroles were directly sampled for chemical and isotopic composition from Mount Mageik and Trident. Mid Ocean Ridge Basalt (MORB)-like 3He/4He ratios (~7.2–7.6 Rc/RA) within Mount Mageik and Trident's fumarole emissions and a moderate SO2 flux (~75 t/d) from Mount Martin, combined with gas compositions dominated by H2O, CO2 and H2S from all three volcanoes, indicate magma degassing and active hydrothermal systems in the subsurface of these volcanoes. Mount Martin's gas emissions have the lowest CO2/H2S ratio (~2–4) and highest SO2 flux compared to the other KVC volcanoes, indicative of shallow magma degassing. Geothermometry techniques applied to Mount Mageik and Trident's fumarolic gas compositions suggest that their hydrothermal reservoirs are located at depths of ~0.2 and 4 km below the surface, respectively. Observations of an unusually reducing gas composition at Trident and organic material in the near-surface soils suggest that thermal decomposition of sediments may be influencing gas composition. When the measured gas compositions from Mount Mageik and Trident are compared with previous samples collected in the late 1990's, relatively stable magmatic-hydrothermal conditions are inferred forMountMageik,while gradual degassing of residual magma and contamination by shallow crustal fluids is inferred for Trident. The isotopic composition of volcanic gases emitted from Mount Mageik and Trident reflect mixing of subducted slab, mantle and crustal volatile sources, with organic sediment and carbonate being the predominant sources. Considering the close proximity of the target volcanoes in comparison with the depth to the subducted slab we speculate that Aleutian Arc volatiles are fed by a relatively homogeneous subducted fluid and that much of the apparent variability in volatile provenance can be explained by shallow crustal volatile sources and/or processes.
    Description: Published
    Description: 64-81
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: Katmai ; volcanic gases ; Mount Martin ; Mount Mageik ; Trident ; hydrothermal system ; arc volcano ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2021-07-19
    Description: The Comoros archipelago is an active geodynamic region of intra-plate volcanism within which the youngest and oldest islands (Grande Comore and Mayotte respectively) are characterized by recent volcanic activity. The frequent eruptions of the large shield volcano Karthala on Grande Comore (last eruption 2007), and the recent birth of a large submarine volcano since 2018 at the submarine base of Mayotte are associated with permanent fumarolic emissions, bubbling gas seeps, and soil gas emissions, which are studied in detail here for the first time. CO2 fluxes and chemical and isotopic gas compositions acquired during two surveys in 2017 and 2020 are integrated with older datasets collected between 2005 and 2016, permitting the identification of a possible influence of the recent volcanic and magmatic activity at Mayotte. At Karthala, high gas fluxes with high temperature, and a marked magmatic signature are concentrated close to the summit crater area, while only weaker emissions with a stronger biogenic signature are found on the volcano flanks. At Mayotte, lower temperature and higher CH4 content are recorded in two main seep areas of CO2-rich fluid bubbling, while soil emissions on land record a higher proportion of magmatic fluids compared to Karthala. Our preliminary results reveal two quite separate gas emission patterns for each island that are distinct in composition and isotopic signatures, and well-correlated with the present state of volcanic activity. This work may potentially provide support for local observation infrastructures and contribute to the improvement in volcanic and environmental monitoring.
    Description: INGV (GECO project Fondi Ricerca libera 2019 INGV) and REVOSIMA Initiative (IPGP, CNRS, BRGM, IFREMER)
    Description: Submitted
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Keywords: •Geochemical characterisation of fumarolic and hydrothermal gases in terms of both primary component species and isotopic characteristics ; 04.08. Volcanology ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 7
    Publication Date: 2020-11-09
    Description: The Pico do Fogo volcano, in the Cape Verde Archipelago off the western coasts of Africa, has been the most active volcano in the Macaronesia region in the Central Atlantic, with at least 27 eruptions during the last 500 years. Between eruptions fumarolic activity has been persisting in its summit crater, but limited information exists for the chemistry and output of these gas emissions. Here, we use the results acquired during a field survey in February 2019 to quantify the quiescent summit fumaroles’ volatile output for the first time. By combining measurements of the fumarole compositions (using both a portable Multi-GAS and direct sampling of the hottest fumarole) and of the SO2 flux (using near-vent UV Camera recording), we quantify a daily output of 1060±340 tons CO2, 780±320 tons H2O, 6.2±2.4 tons H2S, 1.4±0.4 tons SO2 and 0.05±0.022 tons H2. We show that the fumarolic CO2 output from Pico do Fogo exceeds (i) the time-averaged CO2 release during 2015-type recurrent eruptions and (ii) is larger than current diffuse soil degassing of CO2 on Fogo Island. When compared to worldwide volcanoes in quiescent hydrothermal-stage, Pico do Fogo is found to rank among the strongest CO2 emitters. Its substantial CO2 discharge implies a continuous deep supply of magmatic gas from the volcano’s plumbing system (verified by the low but measurable SO2 flux), that becomes partially affected by water condensation and sulphur scrubbing in fumarolic conduits prior to gas exit. Variable removal of magmatic H2O and S accounts for both spatial chemical heterogeneities in the fumarolic field and its CO2-enriched mean composition, that we infer at 64.1±9.2 mol. % H2O, 35.6±9.1 mol. % CO2, 0.26±0.14 mol. % total Sulfur (St), and 0.04±0.02 mol. % H2.
    Description: Published
    Description: 325-340
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Pico do Fogo volcano ; Cape Verde ; Volcanic gases ; CO2 output ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2020-12-15
    Description: Pacaya volcano in Guatemala is one of the most active volcanoes of the Central American Volcanic Arc (CAVA). However, its magmatic gas signature and volatile output have received little attention to date. Here, we present novel volcanic gas information from in-situ (Multi-GAS) and remote (UV camera) plume observations in January 2016. We find in-plume H2O/SO2 and CO2/SO2 ratios of 2-20 and 0.6-10.5, and an end-member magmatic gas signature of 80.5 mol. % H2O, 10.4 mol. % CO2, and 9.0 mol. % SO2. The SO2 flux is evaluated at 8856550 tons/d. This, combined with co-acquired volcanic plume composition, leads to H2O and CO2 fluxes of 2,23061,390 and 7006440, and a total volatile flux of 3,800 tons/d. We use these results in tandem with previous SO2 flux budgets for Fuego and Santiaguito to estimate the total volcanic CO2 flux from Guatemala at 1,1606600 tons/day. This calculation is based upon CO2/total S (St) ratios for Fuego (1.560.75) and Santiaguito (1.460.75) inferred from a gas (CO2/St ratio) versus traceelement (Ba/La ratio) CAVA relationship. The H2O-poor and low CO2/St ratio ( 1.0-1.5) signature of Pacaya gas suggests dominant mantle-wedge derivation of the emitted volatiles. This is consistent with 3He/4He ratios in olivine hosted fluid inclusions (FIs), which range between 8.4 and 9.0 Ra (being Ra the atmospheric 3He/4He ratio) at the upper limit of MORB range (861 Ra). These values are the highest ever measured in CAVA and among the highest ever recorded in arc volcanoes worldwide, indicating negligible 4He contributions from the crust/slab.
    Description: Published
    Description: 667-692
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2021-05-17
    Description: Recent geophysical evidence for large-scale regional crustal inflation and localized crustal magma intrusion has made Lastarria volcano (northern Chile) the target of numerous geological, geophysical, and geochemical studies. The chemical composition of volcanic gases sampled during discrete campaigns from Lastarria volcano indicated a well-developed hydrothermal system from direct fumarole samples in A.D. 2006, 2008, and 2009, and shallow magma degassing using measurements from in situ plume sampling techniques in 2012. It is unclear if the differences in measured gas compositions and resulting interpretations were due to artifacts of the different sampling methods employed, short-term excursions from baseline due to localized changes in stress, or a systematic change in Lastarria’s magmatic-hydrothermal system between 2009 and 2012. Integrated results from a two-day volcanic gas sampling and measurement campaign during the 2014 International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) Commission on the Chemistry of Volcanic Gases (CCVG) 12th Gas Workshop are used here to compare and evaluate current gas sampling and measurement techniques, refine the existing subsurface models for Lastarria volcano, and provide new constraints on its magmatic-hydrothermal system and total degassing budget. While compositional differences among sampling methods are present, distinct compositional changes are observed, which if representative of longterm trends, indicate a change in Lastarria’s overall magmatic-hydrothermal system. The composition of volcanic gases measured in 2014 contained high proportions of relatively magma- and water-soluble gases consistent with degassing of shallow magma, and in agreement with the 2012 gas composition. When compared with gas compositions measured in 2006–2009, higher relative H2O/CO2 ratios combined with lower relative CO2/St and H2O/St and stable HCl/St ratios (where St is total S [SO2 + H2S]) are observed in 2012 and 2014. These compositional changes suggest variations in the magmatic-hydrothermal system between 2009 and 2012, with possible scenarios to explain these trends including: (1) decompression-induced degassing due to magma ascent within the shallow crust; (2) crystallization-induced degassing of a stalled magma body; (3) depletion of the hydrothermal system due to heating, changes in local stress, and/or minimal precipitation; and/or (4) acidification of the hydrothermal system. These scenarios are evaluated and compared against the geophysical observations of continuous shallow inflation at ~8 km depth between 1997 and 2016, and near-surface (〈1 km) inflation between 2000 and 2008, to further refine the existing subsurface models. Higher relative H2O/CO2 observed in 2012 and 2014 is not consistent with the depletion or acidification of a hydrothermal system, while all other observations are consistent with the four proposed models. Based on these observations, we find that scenarios 1 or 2 are the most likely to explain the geochemical and geophysical observations, and propose that targeted shallow interferometric synthetic-aperture radar (InSAR) studies could help discriminate between these two scenarios. Lastly, we use an average SO2 flux of 604 ± 296 t/d measured on 22 November 2014, along with the average gas composition and diffuse soil CO2 flux measurements, to estimate a total volatile flux from Lastarria volcano in 2014 of ~12,400 t/d, which is similar to previous estimates from 2012.
    Description: Published
    Description: 983–1007
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 2IT. Laboratori sperimentali e analitici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2021-06-24
    Description: The possibility of constraining the composition and evolution of specific portions of the Sub-Continental Lithospheric Mantle (SCLM) by means of an integrated study of petrography, mineral chemistry, and concentrations of volatiles in fluid inclusions (FI) is a novel approach that can provide clues on the recycling of volatiles within the lithosphere. This approach is even more important in active or dormant volcanic areas, where the signature of the gaseous emissions at the surface can be that of the underlying lithospheric mantle domains. In this respect, the ultramafic xenoliths brought to the surface in West Eifel (~0.5–0.01 Ma) and Siebengebirge (~30–6 Ma) volcanic fields (Germany) are ideal targets, as they provide direct information on one of the most intriguing portions of SCLM beneath the Central European Volcanic Province (CEVP). Five distinct populations from these localities were investigated using petrographic observations, mineral phase analyses and determination of He, Ne, Ar and CO2 contents in olivine-, orthopyroxene-, and clinopyroxene-hosted FI. The most refractory Siebengebirge rocks have highly forsteritic olivine, high-Mg#, low-Al pyroxene, and spinel with high Cr#, reflecting high extents (up to 30%) of melt extraction. In contrast, xenoliths from West Eifel are modally and compositionally heterogeneous, as indicated by the large forsterite range of olivine (Fo83–92), the Cr# range of spinel (0.1–0.6), and the variable Al and Ti contents of pyroxene. Equilibration temperatures vary from 870 ◦C to 1070 ◦C in Siebengebirge, and from ⁓900 ◦C to ⁓1190 ◦C in West Eifel xenoliths, at oxygen fugacity values generally between 􀀀 0.5 and + 1.3 ΔlogƒO2 [FMQ]. In both areas, the FI composition was dominated by CO2, with clinopyroxene, and most of the orthopyroxene had the highest concentrations of volatiles, while olivine was gas-poor. The noble gas and CO2 distributions suggest that olivine is representative of a residual mantle that experienced one or more melt extraction episodes. The 3He/4He ratio corrected for air contamination (Rc/Ra values) varied from 6.8 Ra in harzburgitic lithotypes to 5.5 Ra in lherzolites and cumulate rocks, indicating that the original MORB-like mantle signature was progressively modified by interaction with crustal-related components and melts having 3He/4He and 4He/40Ar* values consistent with those published for magmatic gaseous emissions. The Ne and Ar isotope systematics indicated that most of the data were consistent with mixing between a recycled atmospheric component and a MORB-like mantle, which does not necessarily require the involvement of a lower mantle plume beneath this portion of the CEVP. The major element distribution in mineral phases from West Eifel and Siebengebirge, together with the systematic variations in FI composition, the positive correlation between Al enrichment in pyroxene and equilibration temperatures, and the concomitant Rc/Ra decrease with increasing temperature, suggest that the SCLM beneath Siebengebirge represented the Variscan lithosphere in CEVP prior to the massive infiltration of melts/fluids belonging to the Quaternary Eifel volcanism. In contrast, West Eifel xenoliths reflect multiple heterogeneous metasomatism/refertilisation events that took place in the regional SCLM between ~6 and ~ 0.5 Ma.
    Description: Published
    Description: 120400
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Eifel ; Siebengebirge ; Noble gas and CO2 measurements ; Fluid inclusions ; Mantle xenoliths ; European SCLM ; Partial melting ; Metasomatism ; Refertilisation ; 04.01. Earth Interior ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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