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  • 1
    In: Economic Geology, Society of Economic Geologists, Inc., Vol. 116, No. 2 ( 2021-03-01), p. 407-425
    Kurzfassung: The Miocene low-sulfidation epithermal deposits of the Omu camp in northeastern Hokkaido, Japan, are small past-producers of precious metals and represent significant exploration targets for high-grade Au and Ag ores. The quartz textures of ore samples and the distribution of ore minerals within quartz veins were studied to identify the processes that resulted in the bonanza-grade precious metal enrichment in these deposits. In the high-grade vein samples, which are crustiform or brecciated in hand specimen, ore minerals exclusively occur within colloform quartz bands. High-magnification microscopy reveals that ore-bearing colloform bands consist of fine-grained quartz exhibiting relic microsphere textures and quartz having a mosaic texture that formed through recrystallization of the microspheres. The presence of relic microspheres is evidence that the microcrystalline quartz hosting the ore minerals formed through recrystallization of a noncrystalline silica precursor phase. The ore-hosting colloform bands composed of agglomerated microspheres alternate with barren colloform quartz bands that are composed of fibrous chalcedonic quartz and mosaic quartz formed through recrystallization of the chalcedony. The findings of this study are consistent with previous models linking bonanza-grade precious metal enrichment and the formation of bands of noncrystalline silica in low-sulfidation epithermal veins to episodic vigorous boiling or flashing of the hydrothermal system in the near-surface environment.
    Materialart: Online-Ressource
    ISSN: 1554-0774 , 0361-0128
    Sprache: Englisch
    Verlag: Society of Economic Geologists, Inc.
    Publikationsdatum: 2021
    ZDB Id: 217703-1
    ZDB Id: 2091221-3
    SSG: 13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    In: Scientific Reports, Springer Science and Business Media LLC, Vol. 12, No. 1 ( 2022-10-17)
    Kurzfassung: Orogenic gold deposits are comprised of complex quartz vein arrays that form as a result of fluid flow along transcrustal fault zones in active orogenic belts. Mineral precipitation in these deposits occurs under variable pressure conditions, but a mechanism explaining how the pressure regimes evolve through time has not previously been proposed. Here we show that extensional quartz veins at the Garrcon deposit in the Abitibi greenstone belt of Canada preserve petrographic characteristics suggesting that the three recognized paragenetic stages formed within different pressure regimes. The first stage involved the growth of interlocking quartz grains competing for space in fractures held open by hydrothermal fluids at supralithostatic pressures. Subsequent fluid flow at fluctuating pressure conditions caused recrystallization of the vein quartz and the precipitation of sulfide minerals through wall-rock sulfidation, with some of the sulfide minerals containing microscopic gold. These pressure fluctuations between supralithostatic to near-hydrostatic conditions resulted in the post-entrapment modification of the fluid inclusion inventory of the quartz. Late fluid flow occurred at near-hydrostatic conditions and resulted in the formation of fluid inclusions that have not been affected by post-entrapment modification as pressure conditions never returned to supralithostatic conditions. This late fluid flow is interpreted to have formed the texturally late, coarse native gold that occurs along quartz grain boundaries and in open spaces. The systematic evolution of the pressure regimes in orogenic gold deposits such as Garrcon can be explained by relative movement of fault-fracture meshes across the base of the upper crustal brittle-ductile transition zone. We conclude that early vein quartz in orogenic deposits is precipitated at near-lithostatic conditions whereas the paragenetically late gold is introduced at distinctly lower pressure.
    Materialart: Online-Ressource
    ISSN: 2045-2322
    Sprache: Englisch
    Verlag: Springer Science and Business Media LLC
    Publikationsdatum: 2022
    ZDB Id: 2615211-3
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Online-Ressource
    Online-Ressource
    Geological Society of America ; 2023
    In:  Geology Vol. 51, No. 2 ( 2023-02-01), p. 189-192
    In: Geology, Geological Society of America, Vol. 51, No. 2 ( 2023-02-01), p. 189-192
    Kurzfassung: High-grade ores in low-sulfidation epithermal precious metal deposits include banded quartz veins that contain gold dendrites. The processes by which dendrite growth takes place have been subject to debate for decades, especially given that these deposits are known to form from dilute thermal liquids that contain only trace amounts of gold. It is shown here that growth of gold dendrites in epithermal veins at the McLaughlin deposit in California (western USA) originally took place within bands of gel-like noncrystalline silica. The gel provided a framework for the delicate dendrites to form. The high permeability of the gel allowed the diffusion and advection of gold from the thermal liquids flowing across the top of the silica layers to the sites of crystal growth within the gel. Over time, the gel hardened to form opal-AG. This silica phase is thermodynamically unstable and recrystallized to quartz that has a distinct mosaic texture.
    Materialart: Online-Ressource
    ISSN: 0091-7613 , 1943-2682
    Sprache: Englisch
    Verlag: Geological Society of America
    Publikationsdatum: 2023
    ZDB Id: 184929-3
    ZDB Id: 2041152-2
    SSG: 13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    In: Mineralium Deposita, Springer Science and Business Media LLC
    Materialart: Online-Ressource
    ISSN: 0026-4598 , 1432-1866
    RVK:
    Sprache: Englisch
    Verlag: Springer Science and Business Media LLC
    Publikationsdatum: 2023
    ZDB Id: 1462046-7
    ZDB Id: 1679-2
    SSG: 13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    In: Mineralium Deposita, Springer Science and Business Media LLC
    Materialart: Online-Ressource
    ISSN: 0026-4598 , 1432-1866
    RVK:
    Sprache: Englisch
    Verlag: Springer Science and Business Media LLC
    Publikationsdatum: 2023
    ZDB Id: 1462046-7
    ZDB Id: 1679-2
    SSG: 13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 6
    In: Mineralium Deposita, Springer Science and Business Media LLC, Vol. 56, No. 5 ( 2021-06), p. 823-842
    Materialart: Online-Ressource
    ISSN: 0026-4598 , 1432-1866
    RVK:
    Sprache: Englisch
    Verlag: Springer Science and Business Media LLC
    Publikationsdatum: 2021
    ZDB Id: 1462046-7
    ZDB Id: 1679-2
    SSG: 13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 7
    Online-Ressource
    Online-Ressource
    Society of Economic Geologists, Inc. ; 2021
    In:  Economic Geology Vol. 116, No. 2 ( 2021-03-01), p. 323-356
    In: Economic Geology, Society of Economic Geologists, Inc., Vol. 116, No. 2 ( 2021-03-01), p. 323-356
    Kurzfassung: The Grass Valley orogenic gold district in the Sierra Nevada foothills province, central California, is the largest historical gold producer of the North American Cordillera. Gold mineralization is associated with shallowly dipping north-south veins hosted by the 160 Ma Grass Valley granodiorite to the southwest of the Grass Valley fault and steeply dipping east-west veins in accreted oceanic rocks to the northeast of this major fault. Quartz veins from both vein types show well-preserved primary textural relationships. Using a combination of petrographic and microanalytical techniques, the paragenetic sequence of minerals within the veins and the compositions of ore minerals were determined to constrain the mechanisms of quartz vein formation and gold deposition. The veins are composed of early quartz that formed through cooling of hydrothermal fluids derived from a geopressured reservoir at depth. The early quartz shows growth zoning in optical cathodoluminescence and contains abundant growth bands of primary inclusions. The primary inclusion assemblages and myriads of crosscutting secondary fluid inclusions have been affected by postentrapment modification, suggesting that early quartz formation was postdated by pronounced pressure fluctuations. These pressure fluctuations, presumably involving changes from lithostatic to hydrostatic conditions, may be related to fault failure of the host structure as predicted by the fault-valve model. Fluid flow associated with pressure cycling took place along microfractures and grain boundaries resulting in extensive recrystallization of the early quartz. Deposition of pyrite, arsenopyrite, and first-generation gold from these hydrothermal fluids causing recrystallization of the early quartz occurred as a result of wall-rock sulfidation. The gold forms invisible gold in the compositionally zoned pyrite or micron-sized inclusions within pyrite growth zones. The latest growth zones in euhedral quartz crystals that formed in association with this stage of the paragenesis contain very rare primary fluid inclusions that have not been affected by postentrapment modification. The hydrothermal system transitioned entirely to hydrostatic conditions immediately after formation of the latest quartz, explaining the preservation of the primary fluid inclusions. The formation of minor quartz in open spaces was followed by the deposition of second-generation native gold and telluride minerals that are commonly associated with base metal sulfides. Ore formation at this stage of the paragenesis is attributed to the rapid decompression of hydrothermal fluids escaping from the geopressured part of the crust into the overlying hydrostatic realm. There is no fluid inclusion evidence that this pressure drop resulted in fluid immiscibility of the hydrothermal fluids. Fluid inclusion evidence suggests that the north-south veins formed at a paleodepth of ~8 km, whereas the east-west veins appear to have formed at ~10 to 11 km below surface, confirming previous inferences that the NE-dipping Grass Valley reverse fault accommodated a large displacement. The findings of the study at Grass Valley have significant implications for the model for orogenic gold deposits, as the reconstruction of the paragenetic relationships provides evidence for the occurrence of two discrete events of gold introduction that occurred at different conditions during the evolution of the hydrothermal system.
    Materialart: Online-Ressource
    ISSN: 1554-0774 , 0361-0128
    Sprache: Englisch
    Verlag: Society of Economic Geologists, Inc.
    Publikationsdatum: 2021
    ZDB Id: 217703-1
    ZDB Id: 2091221-3
    SSG: 13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 8
    In: Economic Geology, Society of Economic Geologists, Inc., Vol. 112, No. 7 ( 2017-11-1), p. 1747-1771
    Kurzfassung: The world-class Veladero high-sulfidation epithermal Au-Ag deposit is located in the Andean cordillera of Argentina near the northern end of the El Indio-Pascua metallogenic belt. The deposit comprises two nearly coalescing subhorizontal orebodies that are centered on an extensive zone of intense hydrothermal alteration. Intensely altered volcanic rocks are composed of fine-grained groundmass quartz that formed as a result of extreme acid leaching. These quartz grains contain ubiquitous rutile inclusions as well as healed microfractures of vapor-filled inclusions that record magmatic vapor streaming through the Miocene volcanic host succession. Condensation of the magmatic vapor into ambient groundwater generated the highly acidic waters responsible for the alteration. Alunite is present in the fine-grained groundmass quartz and fills vugs in the altered rocks. Stable isotope data indicate that the alunite formed through the disproportionation of SO2 in the condensed magmatic vapor. The fine-grained groundmass quartz is crosscut by later fracture-controlled euhedral quartz that is texturally associated with ore minerals. The euhedral quartz crystals show oscillatory growth zoning and contain rare primary fluid inclusions suggesting that quartz formation occurred at ~200°C from a moderately saline ( 〈 5 wt % NaCl equiv) liquid-phase hydrothermal fluid. High-fineness native Au grains are hosted in euhedral quartzlined void spaces and along fractures. In addition to native Au, vugs and fractures in the silicified volcanic rocks host Fe oxide/hydroxide and jarosite that are interpreted to represent the oxidation products of hypogene sulfide minerals that formed during and after the late stages of quartz formation. Results of previous jarosite dating suggest that pervasive oxidation of the orebody commenced during the waning stages of the hydrothermal activity or immediately thereafter. Oxidation of the orebody continued in the supergene environment for at least 3 m.y. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) showed that jarosite, which formed as a result of the oxidation of the orebody, is the principal host for Ag in Veladero ore, explaining the low (ca. 10%) Ag recovery from the oxide ore. The Veladero high-sulfidation epithermal deposit is interpreted to have formed in the shallow part of a magmatic-hydrothermal system. Early alteration related to magmatic vapor discharge was followed by later mineralization from liquid-phase hydrothermal fluids under reduced and slightly acidic to near-neutral conditions. This change from early vapor-dominated to later liquid-dominated magmatic-hydrothermal fluid flow was key in formation of the deposit.
    Materialart: Online-Ressource
    ISSN: 1554-0774 , 0361-0128
    Sprache: Englisch
    Verlag: Society of Economic Geologists, Inc.
    Publikationsdatum: 2017
    ZDB Id: 217703-1
    ZDB Id: 2091221-3
    SSG: 13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 9
    Online-Ressource
    Online-Ressource
    Society of Economic Geologists, Inc. ; 2021
    In:  Economic Geology Vol. 116, No. 6 ( 2021-09-01), p. 1267-1284
    In: Economic Geology, Society of Economic Geologists, Inc., Vol. 116, No. 6 ( 2021-09-01), p. 1267-1284
    Kurzfassung: The Santa Rita porphyry Cu deposit in New Mexico, USA, is characterized by a stockwork of three vein types that differ in morphology, mineralogy, and associated alteration assemblages. Early quartz veins associated with potassic alteration are composed of recrystallized granular quartz grains that host ubiquitous hypersaline liquid and vapor-rich fluid inclusions. The early quartz likely formed at high (≳500°C) temperatures and lithostatic pressures. Hypogene Cu mineralization at Santa Rita is in sulfide veins that reopened or crosscut the early quartz veins. The sulfide veins are surrounded by alteration halos containing chlorite and K-feldspar. Rare quartz crystals are present in some of these chalcopyrite and pyrite veins. The cores of the quartz crystals contain hypersaline liquid and vapor-rich fluid inclusions, whereas the rims mostly contain hypersaline liquid inclusions. The quartz crystals are interpreted to have formed close to the ductile-brittle transition as a result of the pressure drop from lithostatic to hydrostatic conditions. Formation of the quartz crystals was postdated by the deposition of Cu sulfides. Grain boundaries between the quartz and the sulfide minerals are irregular in shape, with sulfide crosscutting growth zones in the quartz. The Cu sulfides are interpreted to have formed from intermediate-density fluids that form secondary fluid inclusion assemblages in all earlier-formed quartz types. Microthermometric investigations showed that these fluid inclusion assemblages homogenize at ~385° to 435°C by critical or near-critical behavior and have salinities of & lt;10 wt % NaCl equiv. The precipitation of Cu sulfides occurred as a result of cooling of these fluids following their escape from the lithostatic into the hydrostatic realm. Retrograde quartz solubility caused the corrosion of earlier-formed quartz during Cu sulfide deposition. The youngest veins at Santa Rita are composed of quartz and pyrite. These veins are associated with intense sericite alteration that overprinted all earlier alteration assemblages. The late quartz hosts primary and secondary liquid-rich fluid inclusions, but no intermediate-density fluid inclusions were identified. This quartz vein type formed at temperatures & lt;360°C and hydrostatic pressures. The paragenetic relationships show that hypogene Cu mineralization at Santa Rita postdated potassic alteration of the host rocks. The Cu mineralization was formed by cooling intermediate-density fluids with critical or near-critical densities as they escaped from lithostatic to hydrostatic conditions.
    Materialart: Online-Ressource
    ISSN: 1554-0774 , 0361-0128
    Sprache: Englisch
    Verlag: Society of Economic Geologists, Inc.
    Publikationsdatum: 2021
    ZDB Id: 217703-1
    ZDB Id: 2091221-3
    SSG: 13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 10
    Online-Ressource
    Online-Ressource
    Society of Economic Geologists, Inc. ; 1998
    In:  Economic Geology Vol. 93, No. 4 ( 1998-07-01), p. 373-404
    In: Economic Geology, Society of Economic Geologists, Inc., Vol. 93, No. 4 ( 1998-07-01), p. 373-404
    Materialart: Online-Ressource
    ISSN: 1554-0774 , 0361-0128
    Sprache: Englisch
    Verlag: Society of Economic Geologists, Inc.
    Publikationsdatum: 1998
    ZDB Id: 217703-1
    ZDB Id: 2091221-3
    SSG: 13
    Standort Signatur Einschränkungen Verfügbarkeit
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