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  • 1
    Online Resource
    Online Resource
    Sulfites, Selenites and Tellurites. (1986)
    San Diego :Elsevier Science & Technology,
    Details
    Keywords: Solubility. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (476 pages)
    Edition: 1st ed.
    ISBN: 9781483286433
    Series Statement: IUPAC Solubility Data Series ; v.Volume 26
    URL: https://ebookcentral.proquest.com/lib/geomar/detail.action?docID=1838397
    DDC: 546/.72
    Language: English
    Note: Front Cover -- Sulfites, Selenites and Tellurites -- Copyright Page -- Table of Contents -- Foreword -- Preface -- Introduction: The Solubility of Solids in Liquids -- Chapter 1. Sodium Sulfite -- 1.1 Evaluation -- 1.2 Binary system -- 1.3 Ternary systems -- 1.4 More complex systems -- Chapter 2. Sodium pyrosulfite (sodium disulfite) -- 2.1 Evaluation -- 2.2 Binary system -- 2.3 Ternary systems -- 2.4 More complex systems -- Chapter 3. Potassium sulfite -- 3.1 Evaluation -- 3.2 Binary system -- 3.3 Ternary systems -- 3.4 More complex systems -- Chapter 4. Potassium pyrosulfite (potassium disulfite) -- 4.1 Evaluation -- 4.2 Binary system -- Chapter 5. Ammonium sulfite -- 5.1 Evaluation -- 5.2 Binary system -- 5.3 Ternary systems -- 5.4 More complex systems -- Chapter 6. Ammonium pyrosulfite (ammonium disulfite) -- 6.1 Evaluation -- 6.2 Binary system -- 6.3 Ternary systems -- Chapter 7. Beryllium sulfite -- Chapter 8. Magnesium sulfite -- 8.1 Evaluation -- 8.2 Binary system -- 8.3 Ternary systems -- 8.4 More complex systems -- Chapter 9. Calcium sulfite -- 9.1 Evaluation -- 9.2 Binary system -- 9.3 Ternary systems -- 9.4 More complex systems -- Chapter 10. Strontium sulfite -- Chapter 11. Barium sulfite -- Chapter 12. Manganese(II) sulfite -- Chapter 13. Iron(II) sulfite -- Chapter 14. Cobalt(II) sulfite -- Chapter 15. Nickel(II) sulfite -- Chapter 16. Copper(I) sulfite -- Chapter 17. Copper(I,II) sulfite -- Chapter 18. Silver sulfite -- Chapter 19. Zinc sulfite -- Chapter 20. Cadmium sulfite -- Chapter 21. Mercury(I) sulfite -- Chapter 22. Lead(II) sulfite -- Chapter 23. Sodium selenite -- Chapter 24. Potassium selenite -- Chapter 25. Alkali-metal selenites -- 25.1 Evaluation -- 25.2 Lithium selenite -- 25.3 Sodium pyroselenite (sodium diselenite) -- 25.4 Sodium trihydrogen diselenite -- 25.5 Potassium pyroselenite (diselenite). , 25.6 Potassium trihydrogen diselenite -- 25.7 Ammonium selenite -- 25.8 Ammonium pyroselenite (diselenite) -- 25.9 Ammonium trihydrogen diselenite -- Chapter 26. Sparingly soluble selenites -- 26.1 Evaluation -- 26.2 Beryllium selenite -- 26.3 Magnesium selenite -- 26.4 Calcium selenite -- 26.5 Strontium selenite -- 26.6 Barium selenite -- 26.7 Manganese(II) selenite -- 26.8 Iron(III) selenite -- 26.9 Cobalt(II) selenite -- 26.10 Nickel(II) selenite -- 26.11 Copper(II) selenite -- 26.12 Silver selenite -- 26.13 Zinc selenite -- 26.14 Cadmium selenite -- 26.15 Mercury(I) selenite -- 26.16 Mercury(II) selenite -- 26.17 Lead(II) selenite -- Chapter 27. Tellurites (salts of the tellurate(IV) ion) -- 27.1 Evaluation -- 27.2 Lithium tellurite -- 27.3 Sodium tellurite -- 27.4 Cesium tellurite -- 27.5 Barium tellurite -- 27.6 Cobalt(II) tellurite -- 27.7 Nickl (II) tellurite -- 27.8 Copper(II) tellurite -- 27.9 Silver tellurite -- 27.10 Lead(II) tellurite -- System Index -- Registry Number Index -- Author Index.
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  • 2
    Electronic Resource
    Electronic Resource
    Lattice vibration spectra. LXVIII. Single-crystal Raman spectra of marcasite-type iron chalcogenides and pnictides, FeX2 (X=S, Se, Te; P, As, Sb) (1991)
    Springer
    Physics and chemistry of minerals 18 (1991), S. 265-268 
    Details
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract Single-crystal Raman spectra of marcasite-type FeS2, FeSe2, and FeTe2 and loellingite-type FeP2, FeAs2, and FeSb2 are presented and discussed with reference to the energies of the two X-X stretching modes v x-x (A g, B 1g) and the four X2 librations Rx2 (A g, B 1g, B 2g, B 3g). The main results obtained are that (i) the intraionic X-X bonds of FeS2 marcasite and FeS2 pyrite are nearly equal in strengths (mean values of the S-S stretching modes 418 and 420 cm-1, respectively) and (ii) the interactions of the metal ions and the dumbbell-like X2 units increase on going from the chalcogenides to the respective pnictides and from FeS2 marcasite to pyrite (as shown from the frequencies of the X2 librations).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00202579
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  • 3
    Electronic Resource
    Electronic Resource
    Hydrogen bonding in basic copper salts: a spectroscopic study of malachite, Cu2(OH)2CO3, and brochantite, Cu4(OH)6SO4 (1993)
    Springer
    Physics and chemistry of minerals 20 (1993), S. 27-32 
    Details
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract Infrared and Raman spectra of the basic copper salts malachite, Cu2(OH)2CO3, and brochantite, Cu4(OH)6SO4, as well as of deuterated and 13C substituted samples are presented and discussed in terms of group theory and the hydrogen bonds present. The main results are that (i) the hydrogen donor strengths of the OH− ions are strongly increased due to the very great synergetic effect of the copper ions, (ii) the acceptor strengths of the H-bond acceptor groups (SO4 2-, CO3 2-, and OH− ions) are significantly modified by the linkage and coordination of the acceptor atoms — this complicates true assignment of the OH bands observed to the two and six different OH− ions present in malachite and brochantite, respectively -, and (iii) the Cu — O stretching modes at 430–590 cm−1 and 420–520 cm−1 for malachite and brochantite, respectively, exhibit strong, partially covalent Cu — O bonding.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00202247
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  • 4
    Electronic Resource
    Electronic Resource
    Semiempirical band structure calculations on skutterudite-type compounds (1999)
    Springer
    Physics and chemistry of minerals 27 (1999), S. 41-46 
    Details
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract Semiempirical band structure calculations were performed on several skutterudite-type compounds by using the extended Hückel method. Starting with the molecular orbital calculations on isolated P4 and As4 rings, the reason for the band dispersions of the skutterudites was found to be the interactions between the nonmetal atoms. Both the intermolecular and the intramolecular interactions between the phosphorus atoms are stronger than those between the arsenic atoms. Hence, the dispersion of the bands in CoP3 is larger than that in CoAs3. The COOP (crystal orbital overlap population) integrals of the intramolecular P-P bonds reveal the relation between the valence electron count and the observed bond lengths. The P-P bonds in the skutterudite-type compounds like TP3 (T = Co, Rh, Ir) become stronger by reduction as in NiP3 and weaker by oxidation as in RT4X12 (X = P, As, Sb; R = alkaline earth or rare earth metals) because the bands near the Fermi level are bonding. The electronic reason for the geometric distortion of the Ge2Y2 (Y = S, Se) units of mixed skutterudites TGe1.5Y1.5 is caused by an electron pair gap on germanium, which corresponds to low electron density perpendicular to the ring plane on the germanium atoms.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s002690050238
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  • 5
    Electronic Resource
    Electronic Resource
    Chalcides and pnictides of group VIII transition metals: Far-infrared spectroscopic studies on compounds MX 2, MXY, and MY 2 with pyrite, marcasite, and arsenopyrite structure (1983)
    Springer
    Physics and chemistry of minerals 9 (1983), S. 109-114 
    Details
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract The far-infrared (FIR) spectra of pyrites, marcasites and loellingites, and arsenopyrites of the type MX 2, MY 2, and MXY with M=Fe, Co, Ru, Rh, Os, Ir X=S, Se, Te, and Y=P, As, and Sb have been studied, including group theoretical treatment of the phonon modes. The internal Y - Y and X - Y stretching modes, infrared (IR) allowed only in the case of the arsenopyrites, have been found to be in the range 440–490, 470–510, 450–490, 430–450 and 400–420 cm−1 for MP 2, MPS, MPSe, MAsS, and MSbS type compounds, respectively. From the obtained spectra intensity weighted mean phonon frequencies, i.e. central frequencies as defined by Plendl (1961), and mass weighted ones have been calculated and interpreted in terms of the strength of the MX and MY bonds, especially comparing 3d, 4d, and 5d transition metal compounds. Method of preparation and X-ray data of the chalcides and pnictides studied are also given.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00308366
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  • 6
    Electronic Resource
    Electronic Resource
    Darstellung von Schwermetallchalkogenid-Einkristallen durch chemischen Transport mit Aluminiumchlorid (1970)
    Springer
    Monatshefte für Chemie 101 (1970), S. 519-524 
    Details
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Single crystals of the following compounds have been grown by chemical transport with anhydrous aluminium chloride as transporting agent: Cr2S3, Cr3S4, Cr5S6, Cr7S8, CrS, Cr2Se3, Cr7Se8, CoS2, CoS, (Co), NiS2, NiS, ZnCr2S4, CdCr2S4, MnCr2S4, ZnCr2Se4, CdCr2Se4, HgCr2Se4, CuCr2Se4, NiCr2S4, Ni0,95Cr0,05S, Ni0,83Cr0,17S, Ni0,75Cr0,25S. The growing of larger crystals and the mechanism of the transport with AlCl3 are discussed.
    Notes: Zusammenfassung Durch chemischen Transport mit wasseerfr. AlCl3 als Transportmittel konnten folgende Schwermetallsulfide und-selenide in Form von Einkristallen erhalten werden: Cr2S3, Cr3S4, Cr5S6, Cr7S8, CrS, Cr2Se3, Cr7Se8, CoS2, CoS, (Co), NiS2, NiS, ZnCr2S4, CdCr2S4, MnCr2S4, ZnCr2Se4, CdCr2Se4, HgCr2Se4, CuCr2Se4, NiCr2S4, Ni0,95Cr0,05S, Ni0,83Cr0,17S, Ni0,75Cr0,25S. Der Mechanismus des Transports mit AlCl3 und die Darstellung größerer Einkristalle werden diskutiert.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00910239
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  • 7
    Electronic Resource
    Electronic Resource
    Aluminiumchlorid als Transportmittel zum chemischen Transport von Übergangsmetallchalkogeniden (1974)
    Springer
    Monatshefte für Chemie 105 (1974), S. 849-852 
    Details
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The closed-tube vapour transport of chalcogenides using anhydrous aluminium chloride as transporting agent has been studied. The conditions for the transport of binary and ternary chromium, manganese, iron, cobalt and nickel sulfides and selenides are communicated.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00912984
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  • 8
    Electronic Resource
    Electronic Resource
    The First Beryllium Periodate: Be(H4IO6)2.4H2O (1996)
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 52 (1996), S. 2660-2662 
    Details
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S0108270196006762
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  • 9
    Electronic Resource
    Electronic Resource
    Caesium Nickel(II) Trichloride, CsNiCl3, and Tricaesium Nickel(II) Pentachloride, Cs3NiCl5 (1998)
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 54 (1998), S. 704-706 
    Details
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S0108270197019598
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  • 10
    Electronic Resource
    Electronic Resource
    Neutron Powder Diffraction Study on Highly Deuterated Ca(IO3)2.D2O (1998)
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 54 (1998), S. 1064-1066 
    Details
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S010827019800167X
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