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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' journal of analytical chemistry 363 (1999), S. 651-654 
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Resonance Rayleigh scattering (RRS) of cationic surfactants–Eosin Y systems and their analytical application have been studied. In aqueous solution at pH 2∼3, Eosin Y reacts with a monomer of cationic surfactants (CS), such as Zephiramine (Zeph), tetradecylpyridinium bromide (TPB), cetylpyridinium bromide (CPB), cetylpyridinium chloride (CPC) and cetyltrimethylammonium bromide (CTMAB), to form an ion associate and a new RRS spectrum appears. The spectral characteristics of the five ion associates are similar and their maximum scattering wavelengths (λmax) are all at 313 nm. The intensity of RRS at λmax of the ion associate is directly proportional to the concentration of CS in the range of 0∼3.0 μg/25 mL. The technique has high sensitivity for the determination of CS; their detection limit is between 5.57 ng/mL and 7.60 ng/mL depending on the CS. In this case, most metal and non-metal ions, NH4 + and some anionic surfactants do not interfere, so that the method has a good selectivity. It can be applied to the determination of trace amounts of cationic surfactants in water samples.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2024-04-20
    Description: LGM simulations are lively topics in paleoclimate research. Here we used IsoGSM model, an isotope-enabled atmospheric general circulation model, to simulate precipitation isotopes (18O and 2H) and its factors (temperature, precipitation, etc) during the LGM and PI periods. IsoGSM is run at a T62 resolution, with a timestep of 6 hours. Each experiment was conducted for 360 months model time and the first 120 months are considered as spin-up before model equilibrium. We also provide datasets of monthly-averaged data and seasonal data. Additionally, 4 idealized experiments are conducted for testing impact of boundary conditions on LGM climate changes. We used orbital parameters, greenhouse gases and vegetation, ice sheets, SST of LGM forcings respectively for sensitivity tests in idealized experiments.
    Keywords: East Asian monsoon; LGM; modeling; Paleoclimate; precipitation isotopes
    Type: Dataset
    Format: application/zip, 455.7 MBytes
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  • 3
    Publication Date: 2022-11-14
    Description: The Indo-Pacific Warm Pool (IPWP) exerts a dominant role in global climate by releasing huge amounts of water vapour and latent heat to the atmosphere and modulating upper ocean heat content (OHC), which has been implicated in modern climate change1. The long-term variations of IPWP OHC and their effect on monsoonal hydroclimate are, however, not fully explored. Here, by combining geochemical proxies and transient climate simulations, we show that changes of IPWP upper (0–200 m) OHC over the past 360,000 years exhibit dominant precession and weaker obliquity cycles and follow changes in meridional insolation gradients, and that only 30%–40% of the deglacial increases are related to changes in ice volume. On the precessional band, higher upper OHC correlates with oxygen isotope enrichments in IPWP surface water and concomitant depletion in East Asian precipitation as recorded in Chinese speleothems. Using an isotope-enabled air–sea coupled model, we suggest that on precessional timescales, variations in IPWP upper OHC, more than surface temperature, act to amplify the ocean–continent hydrological cycle via the convergence of moisture and latent heat. From an energetic viewpoint, the coupling of upper OHC and monsoon variations, both coordinated by insolation changes on orbital timescales, is critical for regulating the global hydroclimate.
    Type: Article , PeerReviewed
    Format: text
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