GLORIA

GEOMAR Library Ocean Research Information Access

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Keywords: Hochschulschrift ; Golf von Guinea ; Holozän ; Klima
    Type of Medium: Online Resource
    Pages: Online-Ressource
    DDC: 910
    Language: English
    Note: Kiel, Univ., Diss., 2013
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 2
    Publication Date: 2017-06-19
    Description: The radiogenic neodymium (Nd) isotope composition of foraminiferal shells provides a powerful archive to investigate past changes in sources and mixing of water masses. However, seawater Nd isotope ratios extracted from foraminiferal shells can be biased by contaminant phases such as organic matter, silicates, or ferromanganese coatings, the removal of which requires rigorous multiple step cleaning of the samples. Here we investigate the efficiency of Flow Through and batch cleaning methods to extract seawater Nd isotope compositions from planktonic foraminifera in a shelf setting in the Gulf of Guinea that is strongly influenced by riverine sediment inputs. Nd isotope analyses of reductively and oxidatively cleaned mono-specific planktonic foraminiferal samples and reductively cleaned mixed benthic foraminifera were complemented by analyses of non-reductively cleaned mono-specific planktonic foraminiferal samples, Fe–Mn coatings of de-carbonated bulk sediment leachates, and the residual detrital fraction of the same sediment. Al/Ca and Mn/Ca ratios of fully cleaned foraminiferal samples reveal indistinguishable levels of cleaning efficiency between the batch and the Flow Through methods and the Nd isotope compositions obtained from application of both methods are identical within error. Furthermore, non-reductively cleaned foraminiferal samples have the same Nd isotope composition as reductively cleaned foraminifera at our study sites. Close to the Niger River mouth the Nd isotope composition of the foraminifera agree with the seawater Nd isotope composition of nearby stations. Based on the combined extracted Nd isotope signatures and element to calcium ratios, as well as rare earth element distribution patterns, we infer that the planktonic foraminiferal Nd isotope signatures reflect bottom water/pore water signatures. The isotopic composition of the bulk de-carbonated sediment leachates (Fe–Mn coatings) differs significantly from the foraminiferal data at this site and probably reflects particles that acquired their ferromanganese/pre-formed pre-formed/ferromanganese coatings in nearby rivers. Therefore, in such river influenced shelf settings foraminiferal shells should be used to obtain unbiased bottom seawater signatures.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2017-05-31
    Description: We present trace element compositions, rare earth elements (REEs) and radiogenic Nd–Sr isotope analyses of Cretaceous to recent sediments of the Tarfaya basin, SW Morocco, in order to identify tectonic setting, source rocks composition and sediments provenance. The results suggest that the sediments originate from heterogeneous source areas of the Reguibat Shield and the Mauritanides (West African Craton), as well as the western Anti-Atlas, which probably form the basement in this area. For interpreting the analyzed trace element results, we assume that elemental ratios such as La/Sc, Th/Sc, Cr/Th, Th/Co, La/Co and Eu/Eu∗ in the detrital silicate fraction of the sedimentary rocks behaved as a closed system during transport and cementation, which is justified by the consistency of all obtained results. The La/Y-Sc/Cr binary and La–Th–Sc ternary relationships suggest that the Tarfaya basin sediments were deposited in a passive margin setting. The trace element ratios of La/Sc, Th/Sc, Cr/Th and Th/Co indicate a felsic source. Moreover, chondrite-normalized REE patterns with light rare earth elements (LREE) enrichment, a flat heavy rare earth elements (HREE) and negative Eu anomalies can also be attributed to a felsic source for the Tarfaya basin sediments. The Nd isotope model ages (TDM = 2.0–2.2 Ga) of the Early Cretaceous sediments suggest that sediments were derived from the Eburnean terrain (Reguibat Shield). On the other hand, Late Cretaceous to Miocene–-Pliocene sediments show younger model ages (TDM = 1.8 Ga, on average) indicating an origin from both the Reguibat Shield and the western Anti-Atlas. In contrast, the southernmost studied Sebkha Aridal section (Oligocene to Miocene–Pliocene) yields older provenance ages (TDM = 2.5–2.6 Ga) indicating that these sediments were dominantly derived from the Archean terrain of the Reguibat Shield.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 2019-09-23
    Description: Highlights: • First ITF reconstruction combining detrital and authigenic isotope signatures. • At the core site signatures of surface water cannot be separated from bottom water. • Intermediate to deep waters remain unchanged in western Timor Sea during MIS3. • Clay-size fraction of the sediment indicates a persistently strong ITF during MIS3. Abstract: The Indonesian Throughflow (ITF) connects the western Pacific Ocean with the eastern Indian Ocean, thus forming one of the major near surface current systems of the global thermohaline circulation. The intensity of the ITF has been found to be sensitive to changes in global ocean circulation, fluctuations in sea level, as well as to the prevailing monsoonal conditions of the Indonesian Archipelago and NW Australia. This study presents the first reconstruction of ITF dynamics combining radiogenic isotope compositions of neodymium (Nd), strontium (Sr), and lead (Pb) of the clay-size detrital fraction to investigate changes in sediment provenance, and paleo seawater Nd signatures extracted from the planktonic foraminifera and authigenic Fe–Mn oxyhydroxide coatings of the marine sediments focussing on marine isotope stage 3 (MIS3). Sediment core MD01-2378 was recovered within the framework of the International Marine Global Change Study (IMAGES) and is located in the area of the ITF outflow in the western Timor Sea (Scott Plateau, 13° 04.95′ S and 121° 47.27′ E, 1783 m water depth). In order to produce reliable seawater signatures, several extraction methods were tested against each other. The results of the study show that at this core location the extraction of surface water Nd isotope compositions from planktonic foraminifera is complicated by incomplete removal of contributions from Fe–Mn oxyhydroxides carrying ambient bottom water signatures. The bottom water Nd isotope signatures reliably obtained from the sediment coatings (average εNd = −5.0) document an essentially invariable water mass composition similar to today throughout the entire MIS3. The radiogenic Nd, Sr, and Pb isotope records of the clay-sized detrital fraction suggest that the Indonesian Archipelago rather than NW Australia was the main particle source at the location of core MD01-2378, and thus indicating a persistently strong ITF during MIS3. Furthermore, the variations of the detrital radiogenic isotopes are shown to be more sensitive to changes in circulation and document a somewhat enhanced ITF intensity during the early part of MIS3 until 47.4 ka compared with the remaining MIS3.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 5
    facet.materialart.
    Unknown
    In:  [Talk] In: Goldschmidt Conference 2012, 24.-29.06.2012, Montreal, Canada .
    Publication Date: 2016-04-26
    Description: Large river systems draining the West African Monsoon area deliver sediments and dissolved trace elements into the Gulf of Guinea (GoG) in the easternmost equatorial Atlantic. The different catchment areas of these river systems are characterized by different geological ages and rock types releasing distinct radiogenic neodymium isotope compositions during weathering which are supplied to the GoG. The main rivers discharging into the GoG are the Niger, the Sanaga, the Nyong and the Ntem with present day εNd signatures of -10.5 [1], -12.3, -12.5 and -28.1 [2], respectively. These riverine inputs mix with the tropical Atlantic surface waters. At intermediate water depths Antarctic Intermediate Water (AAIW) prevails whereas the deep basin at this location is mainly filled with NADW. We focus on a marine sediment core that was recovered off the Sanaga and Ntem Rivers and we reconstruct changes in riverine inputs and in mixing of surface and deep water masses over the past 140,000 years. Changes in riverine inputs most likely reflecting latitudinal shifts of the rainfall zones across the different catchment areas were obtained from the Nd isotope signatures of the residual detrital fraction of the sediment. Sediment leachates of several GoG core top samples reflect the riverine input from nearby rivers indicating transport of particles coated in the rivers. Both the sediment leachates and the residual detrital fraction show similar patterns, with shifts towards radiogenic values during the interglacials and least radiogenic values during glacial periods. This shift in εNd values may be attributed to the migration of the rainfall zones towards the north during interglacial times and thus implies the increased influence of the northern rivers, the Sanaga and Nyong. The oxidatively-reductively cleaned planktonic foraminiferal calcite of the core top samples in the GoG reflects surface seawater signatures. Non-reductively cleaned planktonic foraminiferal tests and cleaned shallow endo-benthic and epi-benthic foraminiferal tests were used to acquire information about past bottom waters. Difficulties in cleaning down core foraminiferal samples were experienced and these samples appear to be contaminated by secondary manganese and iron bearing phases, even after cleaning. Those phases may have overprinted the original surface water Nd isotope composition in the planktonic foraminiferal tests. As the planktonic and benthic foraminiferal values are overall similar to the sediment leachates, the foraminiferal isotope signatures are most likely overprinted by isotopic signals originating from the rivers due to remobilization processes in the sediments and formation of secondary phases such as Mn-carbonates, which are attached to the foraminiferal calcites. References: [1] Goldstein et al. (1984) Earth and Planetary Science Letter 70, 221-236. [2] Weldeab et al. (2011) Geophysical Research Letter 38, pp. 5.
    Type: Conference or Workshop Item , NonPeerReviewed
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2019-09-23
    Description: Summary Meteor Cruise M81/1 was dedicated to the investigation of the distribution of dissolved and particulate trace metals and their isotopic compositions (TEIs) in the full water column of the tropical Atlantic Ocean and their driving factors including main external inputs and internal cycling and ocean circulation. The research program is embedded in the international GEOTRACES program (e.g. Henderson et al., 2007), which this cruise was an official part of and thus corresponds to GEOTRACES cruise GA11. This cruise was completely dedicated to the trace metal clean and contamination-free sampling of waters and particulates for subsequent analyses of the TEIs in the home laboratories of the national and international participants. Besides a standard rosette for the less contaminant prone metals, trace metal clean sampling was realized by using a dedicated and coated trace metal clean rosette equipped with Teflon-coated GO-FLO bottles operated via a polyester coated cable from a mobile winch that was thankfully made available by the U.S. partners of the GEOTRACES program for this cruise. The particulate samples were also collected under trace metal clean conditions using established in-situ pump systems. The cruise track led the cruise southward from the Canary Islands to 11°S and then continued northwestward along the northern margin of South America until it reached Port of Spain, Trinidad & Tobago. The track crossed areas of major external inputs including exchange with the volcanic Canary Islands, the Saharan dust plume, as well as the plume of the Amazon outflow. In terms of internal cycling the equatorial high biological productivity band, as well as increased productivity associated with the Amazon Plume were covered. All major water masses contributing the Atlantic Meridional Overturning Circulation, as well as the distinct narrow equatorial surface and subsurface east-west current bands were sampled. A total of 17 deep stations were sampled for the different dissolved TEIs, which were in most cases accompanied by particulate sampling. In addition, surface waters were continuously sampled under trace metal clean conditions using a towed fish.
    Type: Report , NonPeerReviewed
    Format: text
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 7
    facet.materialart.
    Unknown
    In:  [Poster] In: International Conference on Paleoceanography 2010, 29.08.-03.09.2010, San Diego, CA, USA .
    Publication Date: 2012-07-05
    Type: Conference or Workshop Item , NonPeerReviewed
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 8
    facet.materialart.
    Unknown
    In:  (PhD/ Doctoral thesis), Christian-Albrechts-Universität Kiel, Kiel, Germany, 197 pp
    Publication Date: 2014-01-21
    Type: Thesis , NonPeerReviewed
    Format: text
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 9
    facet.materialart.
    Unknown
    In:  [Talk] In: 22. V. M. Goldtschmidt Conference 2012, Earth in Evolution, 26.06.2012, Montréal, Québec, Canada .
    Publication Date: 2016-04-26
    Description: Large river systems draining the West African Monsoon area deliver sediments and dissolved trace elements into the Gulf of Guinea (GoG) in the easternmost equatorial Atlantic. The different catchment areas of these river systems are characterized by different geological ages and rock types releasing distinct radiogenic neodymium isotope compositions during weathering which are supplied to the GoG. The main rivers discharging into the GoG are the Niger, the Sanaga, the Nyong and the Ntem with present day εNd signatures of -10.5 [1], -12.3, -12.5 and -28.1 [2], respectively. These riverine inputs mix with the tropical Atlantic surface waters. At intermediate water depths Antarctic Intermediate Water (AAIW) prevails whereas the deep basin at this location is mainly filled with NADW. We focus on a marine sediment core that was recovered off the Sanaga and Ntem Rivers and we reconstruct changes in riverine inputs and in mixing of surface and deep water masses over the past 140,000 years. Changes in riverine inputs most likely reflecting latitudinal shifts of the rainfall zones across the different catchment areas were obtained from the Nd isotope signatures of the residual detrital fraction of the sediment. Sediment leachates of several GoG core top samples reflect the riverine input from nearby rivers indicating transport of particles coated in the rivers. Both the sediment leachates and the residual detrital fraction show similar patterns, with shifts towards radiogenic values during the interglacials and least radiogenic values during glacial periods. This shift in εNd values may be attributed to the migration of the rainfall zones towards the north during interglacial times and thus implies the increased influence of the northern rivers, the Sanaga and Nyong. The oxidatively-reductively cleaned planktonic foraminiferal calcite of the core top samples in the GoG reflects surface seawater signatures. Non-reductively cleaned planktonic foraminiferal tests and cleaned shallow endo-benthic and epi-benthic foraminiferal tests were used to acquire information about past bottom waters. Difficulties in cleaning down core foraminiferal samples were experienced and these samples appear to be contaminated by secondary manganese and iron bearing phases, even after cleaning. Those phases may have overprinted the original surface water Nd isotope composition in the planktonic foraminiferal tests. As the planktonic and benthic foraminiferal values are overall similar to the sediment leachates, the foraminiferal isotope signatures are most likely overprinted by isotopic signals originating from the rivers due to remobilization processes in the sediments and formation of secondary phases such as Mn-carbonates, which are attached to the foraminiferal calcites. References: [1] Goldstein et al. (1984) Earth and Planetary Science Letter 70, 221-236. [2] Weldeab et al. (2011) Geophysical Research Letter 38, pp. 5.
    Type: Conference or Workshop Item , NonPeerReviewed
    Format: text
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 10
    facet.materialart.
    Unknown
    In:  [Poster] In: Goldschmidt Conference 2011, 14.-19.08.2011, Prague, Czech Republic .
    Publication Date: 2012-07-05
    Type: Conference or Workshop Item , NonPeerReviewed
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...