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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Sensors and Actuators B: Chemical 11 (1993), S. 347-350 
    ISSN: 0925-4005
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Biotechnology 32 (1994), S. 127-138 
    ISSN: 0168-1656
    Keywords: Carbon dioxide sensor ; Optical sensor ; Optrode ; Oxygen sensor ; pH sensor
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Talanta 41 (1994), S. 985-991 
    ISSN: 0039-9140
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' journal of analytical chemistry 364 (1999), S. 48-53 
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The first decay time-based fiber optic pH microsensors are presented which are without cross-sensitivity to molecular oxygen. They are based on radiationless energy transfer from the donor ruthenium(II)-tris(1,10-phenanthroline) to a pH-sensitive sulfonephthalein acceptor dye. The microsensors have decay times in the microsecond range, a fact that makes them compatible with existing devices designed for optical oxygen microsensing. The sensor tips have diameters of 20 to 30 μm. Outstanding features are the excellent mechanical stability and the inertness to quenching by oxygen. The dynamic range depends on the pKa of the selected pH indicator. The sensors were characterized with respect to the dynamic range, response, storage stability and photostability. A high resolution pH measurement in a marine sediment core serves as an example for its utility.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' journal of analytical chemistry 366 (2000), S. 481-487 
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A fast responding fiber-optic microsensor for sensing pCO2 in marine sediments with high spatial resolution is presented. The tip diameter varies typically between 20 and 50 μm. In order to make the pH-indicator ¶8-hydroxypyrene-1,3,6-trisulfonate soluble in the ethyl cellulose matrix, it was lipophilized with tetraoctylammonium as the counterion [HPTS-(TOA)4]. The microsensor was tuned to sense very low levels of dissolved carbon dioxide which are typically present in marine systems. The detection limit is 0.04 hPa pCO2 which corresponds to 60 ppb CO2 of dissolved carbon dioxide. A soluble Teflon derivative with an extraordinarily high gas permeability was chosen as a protective coating to eliminate interferences by ionic species like chloride or pH. Response times of less than 1 min were observed. The performance of the new microsensor is described with respect to reproducibility of the calibration curves, dynamic range, temperature behavior, long term stability and storage stability. The effect of hydrogen sulfide as an interferent, which is frequently present in anaerobic sediment layers, was studied in detail.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' journal of analytical chemistry 362 (1998), S. 73-76 
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Colorimetric sensing membranes for the determination of sulfur dioxide were developed and characterized. These films can be used for sensing trace amounts of sulfur dioxide both in the gas phase and in aqueous solutions. Lipophilic pH indicator ion pairs were immobilized in hydrophobic gas-permeable silicone and phenyl substituted ormosil. On exposure to SO2 the films undergo a visually detectable color change from blue to yellow. No cross-sensitivity to pH and CO2 was observed. Response times depend on the thickness of the sensing membranes, the indicator concentration in the film as well as on the respective SO2 concentration. Membranes with response times of 〈 1 min (t90) were developed. The sensitivity to sulfur dioxide depends on the pKa of the indicator. An increase in the pKa results in a lower detection limit. The new optical SO2 sensors are chemically and mechanically stable and are easy to manufacture. The storage stability of the membranes is at least 7 months if stored in the dark.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' journal of analytical chemistry 368 (2000), S. 196-202 
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract An optical sensor for the measurement of salinity in seawater has been developed. It is based on a chloride-quenchable fluorescent probe (lucigenin) immobilized on a Nafion film. Two approaches for measuring salinity via chloride concentration are presented. In the first, a change in salinity corresponds to a change in the fluorescence intensity of lucigenin. In the second, the fluorescence intensity information is converted into a phase angle information by adding an inert phosphorescent reference luminophore (a ruthenium complex entrapped in poly(acrylonitrile) beads). Under these conditions, the chloride-dependent fluorescence intensity of lucigenin can be converted into a chloride-dependent fluorescence phase shift which serves as the analytical information. This scheme is referred to as dual lifetime referencing (DLR). The sensor was used to determine the salinity in seawater and brackish water of the North Sea.
    Type of Medium: Electronic Resource
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