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  • 1
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    Society of Petroleum Engineers
    In:  SPE Journal, 18 (06). pp. 1123-1139.
    Publikationsdatum: 2020-05-28
    Beschreibung: We study sequential formulations for coupled multiphase flow and reservoir geomechanics. First, we identify the proper definition of effective stress in multiphase-fluid systems. Although the average pore-pressure p¯--defined as the sum of the product of saturation and pressure of all the fluid phases that occupy the pore space--is commonly used to describe multiphase-fluid flow in deformable porous media, it can be shown that the'equivalent' pore pressure pE --defined as p¯ minusthe interfacial energy--is the appropriate quantity (Coussy 2004). We show, bymeans of a fully implicit analysis of the system, that only the equivalent porepressure pE leads to a continuum problem that is thermodynamically stable (thus, numerical discretizations on the basis of the average pore pressure p¯ cannot render unconditionally stable and convergent schemes). We then study the convergence and stability properties of sequential-implicit coupling strategies. We show that the stability and convergence properties of sequential-implicit coupling strategies for single-phase flow carry over for multiphase systems if the equivalent pore pressure pE is used. Specifically, the undrained and fixed-stress schemes are unconditionally stable, and the fixed-stress split is superior to the undrained approach in terms of convergence rate. The findings from stability theory are verified by use of nonlinear simulations of two-phase flow in deformable reservoirs.
    Materialart: Article , PeerReviewed
    Format: text
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  • 2
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    Unbekannt
    In:  [Poster] In: AGU Fall Meeting 2013, 09.-13.12.2013, San Francisco, USA .
    Publikationsdatum: 2014-01-07
    Materialart: Conference or Workshop Item , NonPeerReviewed
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Publikationsdatum: 2022-05-25
    Beschreibung: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 38 (2011): L06408, doi:10.1029/2011GL046768.
    Beschreibung: Methane is a potent greenhouse gas, but its effects on Earth's climate remain poorly constrained, in part due to uncertainties in global methane fluxes to the atmosphere. An important source of atmospheric methane is the methane generated in organic-rich sediments underlying surface water bodies, including lakes, wetlands, and the ocean. The fraction of the methane that reaches the atmosphere depends critically on the mode and spatiotemporal characteristics of free-gas venting from the underlying sediments. Here we propose that methane transport in lake sediments is controlled by dynamic conduits, which dilate and release gas as the falling hydrostatic pressure reduces the effective stress below the tensile strength of the sediments. We test our model against a four-month record of hydrostatic load and methane flux in Upper Mystic Lake, Mass., USA, and show that it captures the complex episodicity of methane ebullition. Our quantitative conceptualization opens the door to integrated modeling of methane transport to constrain global methane release from lakes and other shallow-water, organic-rich sediment systems, and to assess its climate feedbacks.
    Beschreibung: This work was supported by the U.S. Department of Energy (grants DE‐FC26‐06NT43067 and DE‐AI26‐05NT42496), an NSF Doctoral Dissertation Research grant (0726806), a GSA Graduate Student Research grant, and MIT Martin, Linden and Ippen fellowships.
    Schlagwort(e): Greenhouse gas ; Methane flux ; Freshwater methane ; Gas conduits ; Effective stress ; Ebullition
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Format: text/plain
    Format: application/pdf
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Publikationsdatum: 2022-10-27
    Beschreibung: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 20(5), (2019):2462-2472, doi:10.1029/2019GC008250.
    Beschreibung: Methane hydrate occurs naturally under pressure and temperature conditions that are not straightforward to replicate experimentally. Xenon has emerged as an attractive laboratory alternative to methane for studying hydrate formation and dissociation in multiphase systems, given that it forms hydrates under milder conditions. However, building reliable analogies between the two hydrates requires systematic comparisons, which are currently lacking. We address this gap by developing a theoretical and computational model of gas hydrates under equilibrium and nonequilibrium conditions. We first compare equilibrium phase behaviors of the Xe·H2O and CH4·H2O systems by calculating their isobaric phase diagram, and then study the nonequilibrium kinetics of interfacial hydrate growth using a phase field model. Our results show that Xe·H2O is a good experimental analog to CH4·H2O, but there are key differences to consider. In particular, the aqueous solubility of xenon is altered by the presence of hydrate, similar to what is observed for methane; but xenon is consistently less soluble than methane. Xenon hydrate has a wider nonstoichiometry region, which could lead to a thicker hydrate layer at the gas‐liquid interface when grown under similar kinetic forcing conditions. For both systems, our numerical calculations reveal that hydrate nonstoichiometry coupled with hydrate formation dynamics leads to a compositional gradient across the hydrate layer, where the stoichiometric ratio increases from the gas‐facing side to the liquid‐facing side. Our analysis suggests that accurate composition measurements could be used to infer the kinetic history of hydrate formation in natural settings where gas is abundant.
    Beschreibung: This work was funded in part by the U.S. Department of Energy, DOE [awards DE‐FE0013999 and DE‐SC0018357 (to R. J.) and DOE Interagency Agreement DE‐FE0023495 (to W. F. W.)]. X. F. acknowledges support by the Miller Research Fellowship at the University of California Berkeley. W. F. W. acknowledges support from the U.S. Geological Survey's Gas Hydrate Project and the Survey's Coastal, Marine Hazards and Resources Program. L. C. F. acknowledges funding from the Spanish Ministry of Economy and Competitiveness (grants RYC‐2012‐11704 and CTM2014‐54312‐P). L. C. F. and R. J. acknowledge funding from the MIT International Science and Technology Initiatives, through a Seed Fund grant. The simulation data are available on the UC Berkeley Dash repository at https://doi.org/10.6078/D1G67B.
    Beschreibung: 2019-11-06
    Schlagwort(e): Methane hydrates ; Xenon hydrates ; Phase behavior ; Growth kinetics ; Nonstoichiometry
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 43 (2016): 4374–4381, doi:10.1002/2016GL068668.
    Beschreibung: Methane is a potent greenhouse gas whose emission from sediments in inland waters and shallow oceans may both contribute to global warming and be exacerbated by it. The fraction of methane emitted by sediments that bypasses dissolution in the water column and reaches the atmosphere as bubbles depends on the mode and spatiotemporal characteristics of venting from the sediments. Earlier studies have concluded that hot spots—persistent, high-flux vents—dominate the regional ebullitive flux from submerged sediments. Here the spatial structure, persistence, and variability in the intensity of methane venting are analyzed using a high-resolution multibeam sonar record acquired at the bottom of a lake during multiple deployments over a 9 month period. We confirm that ebullition is strongly episodic, with distinct regimes of high flux and low flux largely controlled by changes in hydrostatic pressure. Our analysis shows that the spatial pattern of ebullition becomes homogeneous at the sonar's resolution over time scales of hours (for high-flux periods) or days (for low-flux periods), demonstrating that vents are ephemeral rather than persistent, and suggesting that long-term, lake-wide ebullition dynamics may be modeled without resolving the fine-scale spatial structure of venting.
    Beschreibung: U.S. National Science Foundation Grant Number: 045193; U.S. Department of Energy Grant Number: DE-FE0013999
    Beschreibung: 2016-11-04
    Schlagwort(e): Methane emissions ; Methane venting ; Ebullition ; Sonar ; Hydroacoustics
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Einschränkungen Verfügbarkeit
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