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  • 1
    Online Resource
    Online Resource
    Dordrecht :Springer Netherlands,
    Keywords: Climatic changes -- Arctic regions. ; Climatology. ; Electronic books.
    Description / Table of Contents: The Arctic is now experiencing some of the most rapid and severe climate change on earth, with far-reaching consequences. This volume addresses a number of central topics including our understanding of the role of the Arctic in the global climate system.
    Type of Medium: Online Resource
    Pages: 1 online resource (472 pages)
    Edition: 1st ed.
    ISBN: 9789400720275
    Series Statement: Atmospheric and Oceanographic Sciences Library ; v.43
    DDC: 551.69113
    Language: English
    Note: Intro -- Arctic Climate Change -- Dedication -- Foreword -- Contents -- Contributors -- Chapter 1: The Origins of ACSYS -- References -- Part I: Observations -- Chapter 2: Advances in Arctic Atmospheric Research -- 2.1 Introduction -- 2.2 Energy Fluxes -- 2.3 The Arctic Oscillation, the PNA-Like, and Arctic Dipole Climate Patterns -- 2.4 Warm Temperatures of the 1930s and 2000s -- 2.5 Recent Climate Change -- References -- Chapter 3: Sea-Ice Observation: Advances and Challenges -- 3.1 The Arctic Marine Cryosphere in the Context of Climate -- 3.2 Objectives for the Arctic Climate System Study -- 3.3 Knowledge Base for the Arctic Climate System Study -- 3.3.1 Extent and Concentration -- 3.3.2 Drift -- 3.3.3 Thickness -- 3.3.4 Export -- 3.3.5 Atmosphere-Ice-Ocean Interaction -- 3.3.6 Sea Ice Processes -- 3.4 Achievements of the Arctic Climate System Study -- 3.4.1 Extent and Concentration -- 3.4.1.1 Operational Ice Charting -- 3.4.1.2 Historical Ice Charts -- 3.4.1.3 Hemispheric Variability -- 3.4.2 Drift -- 3.4.2.1 Satellite Tracking of Beacons -- 3.4.2.2 Kinematic Analysis of Satellite Imagery -- 3.4.2.3 Doppler Sonar -- 3.4.3 Thickness -- 3.4.3.1 In Situ Measurements -- 3.4.3.2 Top-Side Close Sensing -- 3.4.3.3 Bottom-Side Remote Sensing -- 3.4.3.4 Top-Side Remote Sensing -- 3.4.3.5 Ice Thickness from Draft or Elevation -- 3.4.4 Export -- 3.4.4.1 Fram Strait -- 3.4.4.2 Barents Sea -- 3.4.4.3 Bering Sea -- 3.4.4.4 Canadian Archipelago -- 3.4.5 Atmosphere-Ice-Ocean Interaction -- 3.4.5.1 Principal Initiatives -- 3.4.5.2 Climate Sensitivity of Level Ice -- 3.4.5.3 Freezing -- 3.4.5.4 Ice-Bottom Ablation -- 3.4.5.5 Ice-Top Ablation -- 3.4.5.6 Autonomous Monitoring of Surface Energy Balance -- 3.4.5.7 Flaw Leads and Polynyas -- 3.4.6 Sea-Ice Processes -- 3.4.6.1 Ice Thickness Redistribution -- 3.4.6.2 Stress and Strain. , 3.5 Sea Ice of the Southern Hemisphere -- 3.6 Deliverables -- 3.7 Tasks for the Future -- 3.7.1 The Seasonal Sea Ice Zone -- 3.7.2 Global Sea Ice Volume -- 3.7.3 Data Assimilation -- References -- Chapter 4: Observations in the Ocean -- 4.1 Mid 1800-1980: Exploration -- 4.2 1980-1990: Interpretation -- 4.3 The ACSYS Decade: New Insights, Variability and Change -- 4.3.1 Circulation and Transformation of Water Masses -- 4.3.1.1 Atlantic and Intermediate Water Circulation -- 4.3.1.2 Formation of the 'Lower Halocline' -- 4.3.1.3 Pacific Water -- 4.3.1.4 Shelf Processes, River Runoff, Ice Melt, Freezing and Brine Rejection -- 4.3.1.5 Tracking the Waters: Insights from Tracers -- 4.3.1.6 Mixing in the Interior -- 4.3.1.7 The Bottom Water: Stagnant or Ventilated? -- 4.3.1.8 Eddies -- 4.3.2 Change -- 4.3.2.1 The Atlantic Layer -- 4.3.2.2 Redistribution of Water Masses in the Upper Layers -- 4.3.2.3 Changes in the Halocline -- 4.3.2.4 The Intermediate Layers -- 4.3.3 Exchanges -- 4.3.3.1 Fram Strait Transports -- 4.3.3.2 The Barents Sea -- 4.3.3.3 Bering Strait -- 4.3.3.4 The Canadian Arctic Archipelago -- 4.4 The Arctic Ocean as Part of the Arctic Mediterranean Sea -- References -- Chapter 5: Observed Hydrological Cycle -- 5.1 Introduction -- 5.2 Observational Data -- 5.2.1 Precipitation -- 5.2.1.1 Systematic Gauge Measuring Error and Its Correction -- 5.2.1.2 Comparison of Gridded Precipitation Data Based on Different Data Sets -- 5.2.1.3 Comparison of Annual Precipitation and Runoff -- 5.2.2 Runoff -- 5.2.2.1 Database -- 5.2.2.2 Analysis and Results -- 5.2.2.3 Problems in Runoff -- 5.2.3 Snow Cover, Snow Depth -- 5.2.3.1 Observational Methods and Databases -- 5.2.3.2 Results -- 5.2.3.3 Conclusions -- 5.2.3.4 Problems -- 5.2.4 Atmospheric Moisture Flux, P-E Estimates -- 5.2.4.1 The Significance of the Atmospheric Moisture Flux. , 5.2.4.2 Observational and Computational Problems -- 5.2.4.3 Data and Calculations -- 5.2.4.4 Comparison of Different Results -- 5.2.4.5 Summary and Conclusion -- 5.3 Evaluation of Reanalysis Results and Observations -- 5.3.1 Description of the Reanalyses -- 5.3.1.1 ERA15 -- 5.3.1.2 ERA40 -- 5.3.1.3 NCEP Reanalysis -- 5.3.1.4 Additional Tools -- 5.3.2 The Hydrological Cycle over the Arctic Ocean Catchment -- 5.3.2.1 ERA15 Period 1979-1993 -- 5.3.2.2 Hydrological Cycle for Several Arctic Rivers in the Three ERA40 Subperiods -- 5.4 Synopsis of the Observed Arctic Hydrological Cycle: Where Are We Now? -- 5.4.1 Updated Precipitation Time Series -- 5.5 Open Questions, Future Tasks -- References -- Chapter 6: Interaction with the Global Climate System -- 6.1 The Arctic in the Global Climatic System -- 6.2 Thermohaline Convection and the "Great Conveyor Belt" -- 6.3 The Arctic Mediterranean System and Bimodal Catastrophe -- 6.4 Physical Processes Within the AM -- 6.4.1 Convection -- 6.5 Problems of Monitoring Climate Change in the AM -- 6.6 Early Twentieth Century Warming: An Example of Global Interaction? -- 6.7 Summary Statement -- References -- Part II: Modelling -- Chapter 7: Mesoscale Modelling of the Arctic Atmospheric Boundary Layer and Its Interaction with Sea Ice -- 7.1 Introduction -- 7.2 Cold-Air Outbreaks -- 7.3 On-Ice Airflow and Influence of Ridges -- 7.4 Convective Processes Over Ice-Covered Oceans -- 7.4.1 Convection Over Leads -- 7.4.2 Convection Over Sea Ice Caused by a Combination of Factors -- 7.5 Mesoscale Studies with Coupled Atmosphere-Sea Ice Models -- 7.5.1 Influence of Polar Mesoscale Cyclones on Fram Strait Sea Ice Export - Case Studies with the Mesoscale Model System METRAS/MESIM -- 7.5.2 Modelling of Sea Ice Drift in the Marginal Sea Ice Zone -- 7.6 Stable Boundary Layer Over the Greenland Ice Sheet. , 7.6.1 Simulations of Katabatic Wind Dynamics -- 7.6.1.1 Interaction Between the Katabatic Wind and the Formation of Coastal Polynyas -- 7.7 Summary -- References -- Chapter 8: Arctic Regional Climate Models -- 8.1 Introduction -- 8.2 Regional Climate Models of the Arctic Atmosphere -- 8.2.1 Spatial Resolution -- 8.2.2 Domain Choice and Lateral Boundary Forcing -- 8.2.3 Lower Boundary Forcing -- 8.2.4 Physical Parameterisations -- 8.2.5 Applications -- 8.2.6 Arctic Regional Climate Model Intercomparison Project (ARCMIP) -- 8.3 Coupled Regional Models of the Arctic Climate System -- 8.3.1 Model Dynamics and Physics -- 8.3.1.1 Atmosphere -- 8.3.1.2 Ocean -- 8.3.1.3 Sea Ice -- 8.3.1.4 Land Surface and Soil -- 8.3.2 Coupling Strategy -- 8.3.3 Validation and Applications -- 8.4 Past Climate Simulations of Arctic Climate -- 8.5 Scenario Simulations of the Future Arctic Climate -- 8.6 Global Implications of Arctic Climate Processes and Feedbacks -- 8.7 Summary and Conclusions -- References -- Chapter 9: Progress in Hydrological Modeling over High Latitudes: Under Arctic Climate System Study (ACSYS) -- 9.1 Introduction -- 9.2 Evolution of Land Surface Schemes -- 9.3 Arctic Hydrological Modeling During ACSYS -- 9.3.1 MAGS -- 9.3.2 BALTEX -- 9.3.3 GAME-Siberia -- 9.4 NATO Arctic Freshwater Balance Workshop -- 9.5 PILPS 2(e) -- 9.6 Freshwater Inflow to the Arctic Ocean -- 9.7 Conclusions: What Did the ACSYS Achieve? -- References -- Chapter 10: Sea-Ice-Ocean Modelling -- 10.1 Introduction -- 10.2 Sea-Ice Models -- 10.2.1 Thermodynamics -- 10.2.2 Dynamics -- 10.2.3 Model Simulations -- 10.3 Sea-Ice-Ocean Coupling -- 10.3.1 Development of Regional Ocean-Sea-Ice Simulations -- 10.3.2 Dynamical Coupling of Ocean and Sea-Ice Model Components -- 10.3.3 Sea-Ice-Ocean Coupling and Arctic Freshwater Balance -- 10.3.4 Surface Boundary Conditions. , 10.4 Synthesis and Outlook -- References -- Chapter 11: Global Climate Models and 20th and 21st Century Arctic Climate Change -- 11.1 Introduction -- 11.2 GCM Developments Since the Beginning of the ACSYS Era -- 11.2.1 Sea Ice Component -- 11.2.2 Flux Adjustments, Ocean Parameterizations, and Grids -- 11.2.3 Atmospheric Circulation and Clouds -- 11.2.4 Ice Sheet Modeling -- 11.3 CMIP3 Model Highlights -- 11.3.1 Late 20th Century Climate -- 11.3.2 Mid-21st Century Climate Change -- 11.4 Summary and Future Outlook -- Acknowledgments -- References -- Chapter 12: ACSYS: A Scientific Foundation for the Climate and Cryosphere (CliC) Project -- 12.1 Introduction -- 12.2 Project Goals and Objectives -- 12.3 The CliC Main Scientific Themes -- 12.4 CliC and Cryospheric Observations -- 12.5 CliC's Role in IPY -- 12.6 Polar Research Planning (ICARP II) -- 12.7 Assessments -- 12.8 WMO Global Cryosphere Watch -- 12.9 Polar and Cryospheric Reanalysis -- 12.10 Regional and National Developments -- 12.11 Data Management and Data Services -- 12.12 Way Forward -- References -- Index.
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  • 2
    Keywords: Climatic changes ; Environmental impact analysis ; Ocean-atmosphere interaction ; Arctic regions Environmental conditions ; Aufsatzsammlung ; Arktis ; Klimaänderung
    Type of Medium: Book
    Pages: XIV, 464 S. , Ill., graph. Darst., Kt.
    ISBN: 9400720262 , 9789400720268
    Series Statement: Atmospheric and oceanographic science library 43
    DDC: 551.6911/3
    RVK:
    Language: English
    Note: The origins of ACSYS , Sea-ice observation : advances and challenges , Observations in the ocean , Observed hydrological cycle , Interaction with the global climate system , Mesoscale modelling of the Arctic atmospheric boundary layer and its interaction with sea ice , Arctic regional climate models , Progress in hydrological modeling over high latitudes : under Arctic Climate System Study (ACSYS) , Sea-ice-ocean modelling , Global climate models and 20th and 21st century Arctic climate change , ACSYS : a scientific foundation for the Climate and Cryosphere (CliC) Project
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  • 3
    Keywords: Hochschulschrift
    Type of Medium: Online Resource
    Pages: Online-Ressource
    Series Statement: Berichte zur Polar- und Meeresforschung 573
    DDC: 540
    Language: English
    Note: Zugl.: Bremen, Univ., Habil.-Schr., 2006
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  • 4
    Publication Date: 2020-11-18
    Description: Atmospheric aging promotes internal mixing of black carbon (BC), leading to an enhancement of light absorption and radiative forcing. The relationship between BC mixing state and consequent absorption enhancement was never estimated for BC found in the Arctic region. In the present work, we aim to quantify the absorption enhancement and its impact on radiative forcing as a function of microphysical properties and mixing state of BC observed in situ at the Zeppelin Arctic station (78∘ N) in the spring of 2012 during the CLIMSLIP (Climate impacts of short-lived pollutants in the polar region) project. Single-particle soot photometer (SP2) measurements showed a mean mass concentration of refractory black carbon (rBC) of 39 ng m−3, while the rBC mass size distribution was of lognormal shape, peaking at an rBC mass-equivalent diameter (DrBC) of around 240 nm. On average, the number fraction of particles containing a BC core with DrBC〉80 nm was less than 5 % in the size range (overall optical particle diameter) from 150 to 500 nm. The BC cores were internally mixed with other particulate matter. The median coating thickness of BC cores with 220 nm 〈 DrBC〈 260 nm was 52 nm, resulting in a core–shell diameter ratio of 1.4, assuming a coated sphere morphology. Combining the aerosol absorption coefficient observed with an Aethalometer and the rBC mass concentration from the SP2, a mass absorption cross section (MAC) of 9.8 m2 g−1 was inferred at a wavelength of 550 nm. Consistent with direct observation, a similar MAC value (8.4 m2 g−1 at 550 nm) was obtained indirectly by using Mie theory and assuming a coated-sphere morphology with the BC mixing state constrained from the SP2 measurements. According to these calculations, the lensing effect is estimated to cause a 54 % enhancement of the MAC compared to that of bare BC particles with equal BC core size distribution. Finally, the ARTDECO radiative transfer model was used to estimate the sensitivity of the radiative balance to changes in light absorption by BC as a result of a varying degree of internal mixing at constant total BC mass. The clear-sky noontime aerosol radiative forcing over a surface with an assumed wavelength-dependent albedo of 0.76–0.89 decreased, when ignoring the absorption enhancement, by −0.12 W m−2 compared to the base case scenario, which was constrained with mean observed aerosol properties for the Zeppelin site in Arctic spring. The exact magnitude of this forcing difference scales with environmental conditions such as the aerosol optical depth, solar zenith angle and surface albedo. Nevertheless, our investigation suggests that the absorption enhancement due to internal mixing of BC, which is a systematic effect, should be considered for quantifying the aerosol radiative forcing in the Arctic region.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
    Format: application/pdf
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  • 5
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    In:  EPIC3Physical chemistry chemical physics, 1, pp. 5517-5521
    Publication Date: 2019-07-17
    Description: The atmospheric concentration of peroxyacetyl nitrate (PAN) was measured over the South Atlantic Ocean in the range between 37° and 70° S inMarch 1999 in order to investigate its latitudinal distribution and its role in the NOy chemistry of the remote marine boundary layer (MBL) in the high latitudes of thesouthern hemisphere. The measurements were performed using an automatic gas chromatographic system aboard RV Polarstern. Mean mixing ratios of 62 (+/- 21)pptv were obtained between 37° and 49° S. South of 55° S, PAN concentrations were very low with values of the order of 10-30 pptv.Pronounced diurnal cycles could not be observed. The concentrations over the South Atlantic were considerably lower compared with the North Atlantic where theMBL is influenced by continental air masses.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 6
    Publication Date: 2019-12-03
    Description: Because investigations of PAN at higher southern latitudes are very scarce, we measuredsurface PAN concentrations for the first time in Antarctica. During the PhotochemicalExperiment at Neumayer (PEAN'99) campaign mean surface PAN mixing ratios of(13 ± 7) pptv and maximum values of 48 pptv were found. When these PAN mixing ratioswere compared to the sum of NOx and inorganic nitrate they were found to be equal orhigher. Low ambient air temperatures and low PAN concentrations caused a slowhomogeneous PAN decomposition rate of approximately 5 x 10^-2 pptv hr^-1. These slowdecay rates were not sufficient to firmly establish the simultaneously observed NOxconcentrations. In addition, low concentration ratios of [HNO3] / [NOx] imply that thephotochemical production of NOx within the snow pack can influence surface NOx mixingratios in Antarctica. Alternate measurements of PAN mixing ratios at two different heightsabove the snow surface were performed to derive fluxes between the lower troposphereand the underlying snow pack using calculated friction velocities. Most of the concentrationdifferences were below the precision of the measurements. Therefore, only an upper limitfor the PAN flux of ± 1 x 10^13 molecules m^-2 s^-1 without a predominant direction canbe estimated. However, PAN fluxes below this limit can still influence both the transfer ofnitrogen compounds between atmosphere and ice, and the PAN budget in higher southernlatitudes.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 7
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    In:  EPIC3Geophysical Research Letters, 28(8), pp. 1499-1502, ISSN: 0094-8276
    Publication Date: 2019-12-03
    Description: It has been shown that NOx is produced photochemically within the snowpack of polar regions. If emitted to the atmosphere, this processcould be a major source of NOx in remote snowcovered regions. We report here on measurements made at the German Antarctic station,Neumayer, during austral summer 1999, aimed at detecting and quantifying emissions of NOx from the surface snow. Gradients of NOxwere measured, and fluxes calculated using local meteorology measurements. On the 2 days of flux measurements, the derived fluxesshowed continual release from the snow surface, varying between similar to0 and 3x10(8) molecs/cm(2)/s. When not subject toturbulence, the variation was coincident with the uv diurnal cycle, suggesting rapid release once photochemically produced. Scaling thediurnal average of Feb. 7th (1.3x10(8) molecs/cm(2)/s) suggests an annual emission over Antarctica of the order 0.0076TgN.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 8
    Publication Date: 2019-07-17
    Description: Recent results from kinetic and spectroscopic laboratory studies of reactions of free radicals such as NO3 and SO4- with aromaticcompounds in aqueous solution at T = 298 K are presented. Three different experimental approaches, (i) laser photolysis-visible long-pathlaser absorption, (ii) laser photolysis-UV long-path laser absorption and (iii) time-resolved broadband diode-array spectroscopy, havebeen used to investigate the kinetics of reactions of NO3 and SO4- with aromatics, as well as the formation of oxidation intermediates.For the reactions of NO3 with benzene (1), anisole (2), p-xylene (3), p-cresol (4), toluene (5), mesitylene (6) and 1,4-dimethoxybenzene(7), rate coefficients of k(1) = (4.0 +/- 0.6) x 10(8) 1 mol(-1) s(-1), k(2) = (1.0 +/- 0.4) x 10(9) 1 mol(-1) s(-1), k(3) (1.6 +/- 0.1) x10(9) 1 mol s(-1), k(2) = (1.0 +/- 0.4) x 10(9) mol(-1) 1 s(-1), k(3) = (1.6 +/- 0.1) x 10(9) 1 mol(-1) s(-1), k(4) = (8.4 +/- 2.3) x 10(8)1 mol s(-1) k(5) = (1.2 +/- 0.3) x 10(9) 1 mol(-1) s(-1), k(6) = (1.3 +/- 0.3) x 10(9) 1 mol(-1) s(-1) and k(7) = (1.0 +/- 0.3) x 10(9) 1mol(-1) s(-1) were obtained. For the corresponding reactions of SO4- with benzene (8), toluene (9), p-xylene (10), p-cresol (11) andmesitylene (12), rate coefficients of k(8) = (6.4 +/- 2.5) x 10(8) 1 mol(-1) s(-1), k(9) = (1.3 +/- 0.6) x 10(9) 1 mol(-1) s(-1), k(10) =(2.7 +/- 0.9) x 10(9) 1 mol(-1) s(-1)k(11) = (2.8 +/- 0.8) x 10(9) 1 mol(-1) s(-1) and k(12) = (1.3 +/- 0.4) x 10(9) 1 mol(-1) s(-1) weredetermined. Reactivity correlations for both radical species with the aromatic compounds are presented and potential applications of suchcorrelations are discussed. In addition, the effect of ionic strength in the reactions of NO3 with benzene and toluene has been investigated.Transient intermediates have been spectroscopically identified in the reactions of the sulfate radical anion in aerated as well as inoxygen-free solutions. The nature of these intermediates is discussed in view of the existing literature. Finally, possible impacts offree-radical reactions with aromatic compounds on the current understanding of chemical conversion processes within troposphericmultiphase systems are considered.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 9
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    In:  EPIC3in P. Warneck (Hrsg.), Heterogeneous and liquid phase processes, pp. 146-152
    Publication Date: 2014-04-15
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 10
    Publication Date: 2019-07-17
    Description: H2O2 is an important component of the atmospheric oxidizingcapacity, determining the lifetime of atmospheric tracespecies. Bi-directional summertime H2O2 fluxes from thesnowpack at Summit, Greenland, reveal a daytime release fromthe surface snow reservoir during the warm part of the dayand a partial re-deposition at night. The data also providethe first direct evidence of a strong net summertime H2O2release from the snowpack, increasing average boundary layerH2O2 concentrations ~ 7-fold and the OH and HO2concentrations by 70% and 50%, respectively. Changes in H2O2concentration in the snow combined with photochemical andair-snow interaction modeling show that the net snowpackrelease is driven by temperature induced desorption of H2O2as deposited snow, which is supersaturated with respect toice-air partitioning, approaches equilibrium. The resultsshow that the physical cycling of H2O2, and possibly othervolatile species is a key to understanding snowpacks ascomplex physical-photochemical reactors and has far reachingimplications for the interpretation of ice core records aswell as for the photochemistry in polar regions and in thevicinity of snowpacks in general.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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