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  • 1
    Publikationsdatum: 2024-04-03
    Beschreibung: Highlights • Four rhyolitic explosive eruption events were distinguished from 13.1 Ma to 11.6 Ma. • Silicic volcanism occurred at termination of subduction in a thinning lithosphere. • Rhyolites show extreme magma differentiation and reduced-dry character. • Zircon trace element and Hf isotope fingerprint is an effective correlation tool. Abstract The Tokaj Mts. volcanism occurred in a thinning continental lithosphere regime at the final stage of the subduction process. Using high-precision zircon U-Pb dating, four major explosive eruption events were distinguished. Among them the 13.1 Ma Sátoraljaújhely and the 12.0 Ma Szerencs eruptions could have yielded large amount of volcanic material (possibly 〉 100 km3) and they were associated with caldera collapse as shown by the several hundred-metre-thick pyroclastic deposits and the long (〉100 km) runout pyroclastic flow in case of the 13.1 Ma eruption. The 12.3 Ma Hegyköz and the 11.6 Ma Vizsoly eruptions were relatively smaller. The volcanic products can be readily distinguished by zircon and glass trace elements and trace element ratios, which can be used for fingerprinting and to correlate with distal deposits. The Rb, Ba, Sr content and strong negative Eu-anomaly of the glasses reflect extreme crystal fractionation, particularly for the Szerencs rhyolitic magma. The silicic volcanic products of the Tokaj Mts. show compositional similarities with the so-called ‘dry–reduced–hot’ rhyolite type consistent with an origin in an extensional environment, where the primary magmas were formed by near-adiabatic decompression melting in the mantle with subordinate fluid flux. In contrast, some of the older Bükkalja rhyolitic magmas evolved via more hydrous evolutionary paths, where amphibole played a role in the control of the trace element budget. The significant increase of zircon ε Hf values from −8.8 to + 0.2 in the rhyolitic pyroclastic rocks of Tokaj Mts. with time implies that mantle-derived magmas became more dominant. This can be explained by the specific tectonic setting, i.e. the final stage of subduction when the descending subducted slab became almost vertical, which exerted a pull in the upper lithosphere leading to thinning and accelerated subsidence as well as asthenospheric mantle flow just before the slab detachment.
    Materialart: Article , PeerReviewed
    Format: text
    Format: archive
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Publikationsdatum: 2021-06-25
    Beschreibung: We show the results of a study on the volatiles dissolved inmineral waters discharged over a 200 km-long transect along the Rodna-Bârgău area and Călimani-Gurghiu-Harghita volcanic chain (Eastern Carpathians, Romania). All of the collected mineral water samples carry dissolved gas with carbon dioxide content up to 1.99 cm3STP/gH2O, and heliumcontent up to 2.3 × 10−5 cm3STP/gH2O. Carbon (δ13CTDIC total dissolved inorganic carbon, ranging from−15.6 to 5.32‰vs. VPDB), He systematics (He isotopes in the range of 0.38–0.99 Ra, Ra=air-normalized 3He/4He ratio) and CO2/3He ratio spanning over four orders ofmagnitude fromMORB-like values of 2.92× 109 to crustal-type values of 3.02 × 1013, coherently indicate the presence of fluids fromdifferent crustal sources (e.g. sediments, hydrocarbon reservoirs) besidesminor, but detectable contributions ofmantle/magmatic-derived fluids (up to 16.45%). Our investigations show that the wide range of chemical and isotopic composition can be explained in terms of mixings among different gas sources feeding the groundwater and the contemporary occurrence of gas-water interactions like degassing and deposition of carbonates, affecting the circulating waters after their infiltration.
    Beschreibung: Published
    Beschreibung: 117-128
    Beschreibung: 6A. Geochimica per l'ambiente
    Beschreibung: JCR Journal
    Schlagwort(e): Eastern Carpathians ; Dissolved gases ; Gas-water interactions ; Helium 13CTDIC ; gas geochemistry
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Publikationsdatum: 2021-06-25
    Beschreibung: We provide the first high-resolution CO2 flux data for the Neogene to Quaternary volcanic regions of the entire Carpathian-Pannonian Region, Eastern-Central Europe, and estimate the CO2 emission of the seemingly inactive Ciomadul volcanic complex, the youngest volcano of this area. Our estimate includes data from focused and diffuse CO2 emissions from soil. The CO2 fluxes of focused emissions range between 277 and 8172 g d−1, corresponding to a CO2 output into the atmosphere between 0.1 and 2.98 t per year. The investigated areas for diffuse soil gas emissions were characterized by wide range of CO2 flux values, at Apor Baths, ranging from 1.7 × 101 to 8.2 × 104 g m−2 d−1, while at Lăzărești ranging between 1.43 and 3.8 × 104 g m−2 d−1. The highest CO2 focused gas fluxes at Ciomadul were found at the periphery of the youngest volcanic complex, which could be explained either by tectonic control across the brittle older volcanic edifices or by degassing from a deeper crustal zone resulting in CO2 flux at the periphery of the supposed melt-bearing magma body beneath Ciomadul. The estimate of the total CO2 output in the area is 8.70 × 103 t y−1, and it is consistent with other long (N10 kyr) dormant volcanoes with similar age worldwide, such as in Italy and USA. Taking into account the isotopic composition of the gases that indicate deep origin of the CO2 emissions, this yields further support that Ciomadul may be considered indeed a dormant, or PAMS volcano (volcano with potentially active magma storage) rather than an inactive one. Furthermore, hazard of CO2 outpourings has to be taken into account and it has to be communicated to the visitors. Finally, we suggest that CO2 output of dormant volcanic systems has to be also accounted in the estimation of the global volcanic CO2 budget.
    Beschreibung: Published
    Beschreibung: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Beschreibung: JCR Journal
    Schlagwort(e): dormant volcano ; CO2 flux Total emission
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Publikationsdatum: 2020-02-13
    Beschreibung: Ciomadul is the youngest volcano in the Carpathian‐Pannonian Region, Eastern‐Central Europe, which last erupted 30 ka. This volcano is considered to be inactive, however, combined evidence from petrologic and magnetotelluric data, as well as seismic tomography studies, suggests the existence of a subvolcanic crystal mush with variable melt content. The volcanic area is characterized by high CO2 gas output rate, with a minimum of 8.7 × 103 t/year. We investigated 31 gas emissions at Ciomadul to constrain the origin of the volatiles. The δ13C–CO2 and 3He/4He compositions suggest the outgassing of a significant component of mantle‐derived fluids. The He isotope signature in the outgassing fluids (up to 3.10 Ra) is lower than the values in the peridotite xenoliths of the nearby alkaline basalt volcanic field (R/Ra 5.95 Ra ± 0.01), which are representative of a continental lithospheric mantle and significantly lower than MORB values. Considering the chemical characteristics of the Ciomadul dacite, including trace element and Sr–Nd and O isotope compositions, an upper crustal contamination is less probable, whereas the primary magmas could have been derived from an enriched mantle source. The low He isotopic ratios could indicate a strongly metasomatized mantle lithosphere. This could be due to infiltration of subduction‐related fluids and postmetasomatic ingrowth of radiogenic He. The metasomatic fluids are inferred to have contained subducted carbonate material resulting in a heavier carbon isotope composition (δ13C is in the range of −1.4‰ to −4.6‰) and an increase of CO2/3He ratio. Our study shows the magmatic contribution to the emitted gases.
    Beschreibung: Published
    Beschreibung: 3019–3043
    Beschreibung: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Beschreibung: JCR Journal
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Einschränkungen Verfügbarkeit
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