Description: Knowledge of regional variations in response to abrupt climatic transitions is essential to understanding the climate system and anticipating future changes. Global climate models typically assume that major climatic changes occur synchronously over continental to hemispheric distances. The last major reorganization of the ocean-atmosphere system in the North Atlantic realm took place during the Younger Dryas (YD), an ~1100 yr cold period at the end of the last glaciation. Within this region, several terrestrial records of the YD show at least two phases, an initial cold phase followed by a second phase of climatic amelioration related to a resumption of North Atlantic overturning. We show that the onset of climatic amelioration during the YD cold period was locally abrupt, but time-transgressive across Europe. Atmospheric proxy signals record the resumption of thermohaline circulation midway through the Younger Dryas, occurring 100 yr before deposition of ash from the Icelandic Vedde eruption in a German varve lake record, and 20 yr after the same isochron in western Norway, 1350 km farther north. Synchronization of two high-resolution continental records, using the Vedde Ash layer (12,140 ± 40 varve yr B.P.), allows us to trace the shifting of the polar front as a major control of regional climate amelioration during the YD in the North Atlantic realm. It is critical that future climate models are able to resolve such small spatial and chronological differences in order to properly encapsulate complex regional responses to global climate change.

Description: We present a record of extreme spring–summer runoff events for the past 1600 yr preserved in the varved sediments of Lake Mondsee (Austrian Pre-Alps). Combined sediment microfacies analyses and high-resolution micro-X-ray fluorescence element scanning allow us to identify 157 detrital event layers deposited in spring–summer and to discriminate between regional flood and local debris flow deposits. Higher spring–summer flood activity with a mean event recurrence of 3–5 yr occurred in several well-confined multidecadal episodes during the Dark Ages Cold Period and Medieval time (A.D. 450–480, 590–640, 700–750, and 1140–1170) as well as during the early Little Ice Age (LIA; A.D. 1300–1330 and 1480–1520). In contrast, lowest spring–summer flood activity with an event recurrence of only 30–100 yr is observed during the Medieval Climate Anomaly (A.D. 1180–1300) and the coldest interval of the LIA (A.D. 1600–1700). These findings indicate a complex relationship between temperature conditions and extreme hydro-meteorological events and suggest that enhanced summer Mediterranean cyclogenesis triggers large-scale floods in the northeast Alps during climatic transitions. The Lake Mondsee data demonstrate the climatic sensitivity of spring–summer floods and prove the potential of varved sediment records to investigate the impact of changing climate boundary conditions on seasonal flood activity for pre-instrumental time.

Description: The Upper Critical Zone (UCZ) of the Bushveld Igneous Complex displays spectacular layering in the form of cyclic units comprising a basal chromitite layer overlain by a sequence of silicate cumulates in the order, from bottom to top, pyroxenite–norite–anorthosite. Electron microprobe and laser ablation inductively coupled plasma mass spectrometry analyses of chromite and silicate minerals in layers between the UG2 chromitite and the Merensky Reef reveal variations in major and trace element compositions that defy explanation with existing models of cumulate mineral–melt evolution. The anomalous features are best developed at sharp contacts of chromitite with adjacent anorthosite and pyroxenite cumulates. Here, chromite compositions change abruptly from high and constant Mg/(Mg + Fe 2+ ) and Fe 2+ /Fe 3+ ratios in chromitite layers to variable and generally lower values in chromite disseminated in silicate layers. Furthermore, the composition of disseminated chromites varies depending on the host silicate assemblage; for example, in Ti, V and Zn contents. Importantly, the abrupt change in chromite composition across the chromitite–silicate layer contacts is independent of the thickness of the chromitite layer and the estimated mass proportions of chromite to intercumulus liquid. Chemical variations in plagioclase are also abrupt and some are hard to reconcile with conventional models of re-equilibration with intercumulus liquid. Among those features is the decoupling of alkalis from other incompatible lithophile elements. In comparison with cumulus plagioclase, intercumulus poikilitic plagioclase in chromitite layers is enriched in rare earth elements but strongly depleted in equally incompatible Li, K and Rb. Strong alkali depletion is also observed in intercumulus pyroxene from ultramafic cumulates and chromitite layers. To explain these features, we propose a new model of post-cumulus recrystallization, which intensifies the modal layering in the crystal–liquid mush, producing the observed sequence of nearly monomineralic layers of chromitite, pyroxenite and anorthosite that define the cyclic units. The crucial element of this model is the establishment of redox potential gradients at contacts between chromite-rich cumulates and adjacent silicate layers owing to peritectic reactions between the crystals and intercumulus melt. Because basaltic melts are ionic electrolytes with Na + as the main charge carrier, the redox potential gradient induces electrochemical migration of Na + and other alkali ions. Selective mobility of alkalis can explain the enigmatic features of plagioclase composition in the cyclic units. Sodium migration is expected to cause remelting of previously formed cumulates and major changes in modal mineral proportions, which may eventually result in the formation of sharply divided monomineralic layers. The observed variations in ferric/ferrous iron ratios in chromite from the cyclic units and Fe distribution in plagioclase imply a redox gradient of the order of 0·9 log-units f O 2 , equivalent to a potential gradient of 60 mV. Preliminary estimates suggest that the resulting electrochemical flux of Na + ions is sufficient to mobilize about one-third of the total Na content of a 1 m thick mush layer within 10 years. The proposed electrochemical effect of post-cumulus crystallization is enhanced by the presence of cumulus chromite but, in principle, it can operate in any type of cumulates in which ferrous and ferric iron species are distributed unequally between crystalline and liquid phases.