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  • 1
    Keywords: Siderophiles Element. ; Electronic books.
    Description / Table of Contents: Reviews in Mineralogy & Geochemistry (RiMG) volumes contain concise advances in theoretical and/or applied mineralogy, crystallography, petrology, and geochemistry.
    Type of Medium: Online Resource
    Pages: 1 online resource (798 pages)
    Edition: 1st ed.
    ISBN: 9781501502095
    Series Statement: Reviews in Mineralogy and Geochemistry Series ; v.81
    DDC: 549/.112
    Language: English
    Note: Intro -- Table of Contents -- 1. Experimental Results on Fractionation of the Highly Siderophile Elements (HSE) at Variable Pressures and Temperatures during Planetary and Magmatic Differentiation -- INTRODUCTION AND SCOPE -- SOLID METAL -LIQUID METAL PARTITIONING -- EXPERIMENTAL APPROACH TO SOLID METAL-LIQUID METAL PARTITIONING (DSM/LM) -- HSE SOLUBILITY EXPERIMENTS: IMPLICATIONS FOR METAL-SILICATE PARTITIONING -- CALCULATING THE METAL-SILICATE MELT PARTITION COEFFICIENT FROM SOLUBILITY DATA -- Controls on the metal-silicate partition coefficient -- Metal inclusions in experiments and the analysis of contaminated phases -- Possible mechanisms of metal inclusion formation -- Experimental methods to measure HSE solubility and metal-silicate partitioning -- Summary of experimental data -- Application of results to core formation -- SILICATE AND OXIDE CONTROL ON HSE FRACTIONATION -- Experimental approach -- Spinel-melt partitioning of HSEs -- Silicate mineral-melt partitioning of HSEs -- Origin of the variation in partitioning -- Local PGM saturation during chromite growth -- MAGMATIC SULFIDE AND ASSOCIATED PHASES -- Experimental approach -- MSS-sulfide melt partitioning -- MSS-ISS-sulfide melt partitioning -- Sulfide melt-silicate melt and MSS-silicate melt partitioning -- Role of the chalcogens (Se, Te, As, Bi, Sb) -- SILICATE MELT-AQUEOUS LIQUID-VAPOR PARTITIONING -- Theoretical considerations -- Experimental methods -- The volatile/melt partitioning of Au -- The volatile/melt partitioning of PPGE -- The volatile/melt partitioning of IPGE and Re -- CONCLUDING REMARKS -- ACKNOWLEDGMENTS -- REFERENCES -- 2. Analytical Methods for the Highly Siderophile Elements -- INTRODUCTION -- DATA QUALITY CONSIDERATIONS FOR THE HSE -- Sample heterogeneity and reproducibility -- MEASUREMENT PROCEDURES -- Chemical separation of HSE. , REFERENCE MATERIALS FOR HSE ANALYSIS -- APPENDIX -- REFERENCES -- 3. Nucleosynthetic Isotope Variations of Siderophile and Chalcophile Elements in the Solar System -- INTRODUCTION -- ORIGIN OF ELEMENTS: STELLAR NUCLEOSYNTHESIS -- Production of elements from He to Fe via hydrogen to silicon burning -- PRESOLAR GRAINS -- Types of presolar grains and their origin -- ISOTOPE ANOMALIES OF SIDEROPHILE AND CHALCOPHILE ELEMENTS IN BULK METEORITES -- Isotope anomalies of siderophile elements in bulk meteorites -- Isotope anomalies of chalcophile elements in bulk meteorites -- INTERNAL ISOTOPE ANOMALIES PRESENT IN CHONDRITES -- CAIs -- Acid leachates and residues -- Isotopic constraints on the s-process nucleosynthetic component -- ORIGIN OF PLANETARY SCALE ISOTOPE ANOMALIES IN METEORITES -- CONCLUDING REMARKS -- ACKNOWLEDGMENTS -- REFERENCES -- 4. Highly Siderophile Elements in Earth, Mars, the Moon, and Asteroids -- INTRODUCTION -- MOTIVATION FOR STUDY AND BEHAVIOR OF THE HSE IN PLANETARY MATERIALS -- METHODS APPLIED TO INVESTIGATING SIDEROPHILE ELEMENTS IN PLANETARY MATERIALS -- HSE ABUNDANCES -- The rhenium-osmium, platinum-osmium and palladium-silver isotope systems -- Standardization in planetary studies -- Metal-sulfide-silicate modeling in chondritic systems -- Partial melt modeling of planetary mantles -- "Pristinity" of crustal and mantle samples -- Estimation of planetary mantle composition -- What do chondritic or nearly/broadly chondritic actually mean? -- PLANETARY MATERIALS -- Early Solar System materials -- Fragments of planetary cores and/or metal-rich melt pools -- Primitive achondrite meteorites -- Meteorites from differentiated asteroids -- Mars -- The Moon -- Terrestrial mantle composition -- Secondary alteration effects -- PLANETARY FORMATION PROCESSES -- Initial conditions and homogeneity of starting materials. , Partial melting and partitioning of the HSE -- Core crystallization -- 'Late-accretion' -- Alternative hypotheses for the abundances of the HSE in planetary mantles -- Magmatic processes -- Later impacts into planetary crusts -- COMPARATIVE PLANETOLOGY AND IMPLICATIONS FOR TERRESTRIAL FORMATION -- FUTURE DIRECTIONS -- ACKNOWLEDGEMENTS -- REFERENCES -- 5. Distribution and Processing of Highly Siderophile Elements in Cratonic Mantle Lithosphere -- INTRODUCTION -- THE CRATONIC MANTLE SAMPLE: PECULIARITIES, OPPORTUNITIES AND PITFALLS -- DATABASE -- MINERALOGY AND HSE HOSTS IN CRATONIC MANTLE PERIDOTITES -- ANALYTICAL TECHNIQUES FOR CRATONIC MANTLE PERIDOTITES -- Whole rocks and mineral separates -- Single-grain techniques -- UTILIZATION OF THE RE-OS ISOTOPE SYSTEM IN CRATONIC MANTLE STUDIES -- EFFECT OF MELT DEPLETION DURING CRATONIC LITHOSPHERE STABILIZATION ON SULFUR AND HSE SYSTEMATICS -- Sulfur and the persistence of sulfides -- Alloy saturation -- Chalcogens -- HSE PROCESSING DURING MANTLE METASOMATISM -- Modification during intraplate mantle metasomatism -- Modification during craton margin processes-subduction -- MODELLING OF PRIMARY VS. SECONDARY HSE SIGNATURES IN CRATONIC MANTLE -- HSE Concentrations of the Archean convecting mantle (ACM) -- Modelling Rationale -- Effects of partial melt extraction on HSE based on modelling -- Post-core formation, sluggish downward mixing of a late veneer -- SUMMARY -- ACKNOWLEDGMENTS -- REFERENCES -- 6. Highly Siderophile Element and 187Os Signatures in Non-cratonic Basalt-hosted Peridotite Xenoliths: Unravelling the Origin and Evolution of the Post-Archean Lithospheric Mantle -- INTRODUCTION -- CONSTRAINING THE HSE AND 187Os/188Os ISOTOPIC COMPOSITION OF THE PRIMITIVE BULK SILICATE EARTH -- PETROLOGY AND LOCATION OF NON-CRATONIC PERIDOTITE XENOLITHS. , A BRIEF REVIEW OF HSE AND Os ISOTOPE ANALYTICAL METHODS AND HSE NORMALIZATION VALUES -- HOST MINERALS OF HIGHLY SIDEROPHILE ELEMENTS IN NON-CRATONIC PERIDOTITE XENOLITHS -- Nature of the host minerals -- Petrography of the base metal sulfides -- Origin of the base metal sulfides and platinum group minerals -- HIGHLY SIDEROPHILE ELEMENTS AND 187Os/188Os RESULTS FROM NON-CRATONIC PERIDOTITE XENOLITHS -- Summary of results from whole-rock studies -- Summary of results from base metal sulfides and other mineral phases -- Reconciling 187Os/188Os results from whole-rock and base metal sulfide analyses -- THE LIFE OF A XENOLITH, AS RECORDED IN HSE- AND Os-ISOTOPE SYSTEMATICS -- The HSE and 187Os composition of the Primitive Upper Mantle -- Whole-rock observations on samples representing melting residues -- Mineralogical control of HSE fractionation during partial melting -- Ancient melt-extraction events recorded by 187Os/188Os systematics -- Post-melting petrological history -- Syn- to post-eruptive processes -- CHRONOLOGICAL INTERPRETATION OF OS-ISOTOPIC DATA AND TECTONIC IMPLICATIONS -- Obtaining age information from Os isotopes of whole rocks -- Obtaining age information from Os isotopes of base metal sulfides -- Tectonic interpretation of Os model ages -- CONCLUSIONS -- ACKNOWLEDGEMENTS -- REFERENCES -- 7. Re-Pt-Os Isotopic and Highly Siderophile Element Behavior in Oceanic and Continental Mantle Tectonites -- INTRODUCTION -- BREVIA OF CONCEPTS, TERMINOLOGY, AND ANALYTICAL CAVEATS -- Re-Pt-Os parameters -- Normalization of concentration data -- Precision and accuracy of concentration data and analytical issues -- HIGHLY SIDEROPHILE ELEMENTS IN MANTLE TECTONITES FROM DIFFERENT GEODYNAMIC SETTINGS -- Summary of mantle tectonites and their geodynamic settings -- HSE IN ABYSSAL PERIDOTITES FROM SPREADING OCEANIC LITHOSPHERE. , HSE in mantle tectonites from continental extensional domains and continent-ocean transitions -- HSE in ophiolites that formed at fast spreading ridges with little or no influence from subduction processes -- High-temperature orogenic peridotites from convergent plate margin settings -- Highly siderophile elements in peridotites and melt-reacted lithologies of ophiolites influenced by convergent plate margin magmatism -- Highly siderophile elements in the mantle sections of ophiolites of uncertain origin -- DISCUSSION -- Influence of low-temperature alteration processes on the HSE in bulk rocks and minerals -- The influence of melt infiltration and partial melting on HSE abundances in mantle tectonites -- Summary-Mantle melting and mantle-magma interaction-different sides of the same coin -- Os isotopic heterogeneity in the mantle -- The role of recycled oceanic lithosphere in producing HSE and Os isotope signatures in magmas -- The relationship between abyssal peridotites and MORB: an osmium isotope perspective -- Interpretation of Re-Os model ages -- ACKNOWLEDGMENTS -- REFERENCES -- 8. Chalcophile and Siderophile Elements in Mantle Rocks: Trace Elements Controlled By Trace Minerals -- INTRODUCTION -- BACKGROUND -- Sulfides in the upper mantle and mantle rocks -- Abundance and phase control on chalcophile and siderophile elements in the fertile upper mantle -- Partial melting of the mantle: a BMS-removing and PGM producing petrogenetic process -- Chalcophile/siderophile element systematics in pyroxenites -- Low-pressure BMS dissolution in regional-scale open system melting of the sub-continental lithospheric mantle -- BMS precipitation associated with magma percolation/metasomatism -- Platinum-group minerals and magmatic percolation of the lithospheric mantle -- CONCLUDING REMARKS -- ACKNOWLEDGMENTS -- REFERENCES. , 9. Petrogenesis of the Platinum-Group Minerals.
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  • 2
    Publication Date: 2023-05-12
    Keywords: ANTIPODE; ANTP-109D-C; DEPTH, sediment/rock; Dredge; DRG; Melville; Osmium; Osmium-187/Osmium-188 ratio; Rhenium; ε-Thallium-205
    Type: Dataset
    Format: text/tab-separated-values, 133 data points
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  • 3
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    PANGAEA
    In:  Supplement to: Burton, Kevin W; Vance, Derek (2000): Glacial-interglacial variations in the neodymium isotope composition of seawater in the Bay of Bengal recorded by planktonic foraminifera. Earth and Planetary Science Letters, 176(3-4), 425-441, https://doi.org/10.1016/S0012-821X(00)00011-X
    Publication Date: 2024-01-09
    Description: This study presents neodymium isotope and elemental data for cleaned planktonic foraminifera from ODP site 758 in the southernmost reaches of the Bay of Bengal in the north-east Indian Ocean. Cleaning experiments using oxidative-reductive techniques suggest that diagenetic Fe-Mn oxyhydroxide coatings can be effectively removed, and that the measured Nd isotope composition reflects the composition of seawater from which the foraminiferal calcium carbonate was precipitated. Modern core-top Pulleniatina obliquiloculata and Globorotalia menardii give epsilon-Nd values of 310.12 +/- 0.16 and 310.28 +/- 0.16, respectively, indistinguishable from recent direct measurements of surface seawater in this area. A high-resolution Nd isotope record obtained from G. menardii for the past 150 kyr shows systematic variations (Delta epsilon-Nd = 3) on glacial-interglacial timescales. The timing of those variations shows a remarkable correspondence with the global oxygen isotope record, which suggests a process controlling the Nd isotope composition that responds in phase with global climate cycles. Palaeoclimate reconstruction indicates that during the last glacial maximum changes in monsoon circulation resulted in a reduction in rainfall over the Indian subcontinent, and a decrease in the flux of river water delivered to the Bay of Bengal. Thus, changes in the riverine input of Nd, a change in either flux or composition, most likely caused the isotope variations, although changes in dust source or local ocean circulation may have also played a role. These results clearly establish a link between climate change and variations in radiogenic isotopes in the oceans, and illustrate the potential of Nd isotopes in foraminifera for highresolution palaeoceanographic reconstruction.
    Keywords: 121-758A; DRILL; Drilling/drill rig; Indian Ocean; Joides Resolution; Leg121; Ocean Drilling Program; ODP
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 4
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    PANGAEA
    In:  Supplement to: Burton, Kevin W; Gannoun, Abdelmouhcine; Parkinson, Ian J (2010): Climate driven glacial-interglacial variations in the osmium isotope composition of seawater recorded by planktic foraminifera. Earth and Planetary Science Letters, 295(1-2), 58-68, https://doi.org/10.1016/j.epsl.2010.03.026
    Publication Date: 2024-01-09
    Description: This study presents osmium (Os) isotope and elemental data for cleaned planktic foraminifera, authigenic Fe-Mn oxyhydroxides and pelagic carbonate host sediments from ODP site 758 in the southernmost reaches of the Bay of Bengal. The Os in the bulk sediments appears to be dominantly hydrogeneous (sourced by carbonate and Fe-Mn oxyhydroxide), but variations in this particular core are controlled by the presence of volcanic ash. Fe-Mn oxyhydroxide leachates (of the bulk sediments) from Holocene samples also yield an Os isotope composition close to that of seawater, but the record diverges from that of foraminifera at a depth corresponding to the oxic/post-oxic boundary, suggesting diagenetic mobilization of Os at depths below this. Holocene planktic foraminifera, cleaned using oxidative-reductive techniques, also give Os isotope compositions indistinguishable from modern seawater, but the record obtained for the past 150 kyr shows strong covaraitions of 187Os/188Os with both the local and global oxygen isotope record, with less radiogenic Os isotope compositions during glacial intervals. These results indicate that foraminifera provide a robust record of seawater Os isotope compositions, and comparison of the data obtained here with records from the other major oceans demonstrate global changes in 187Os/188Os over this time interval, while the covariation with oxygen isotopes suggest a process controlling the Os isotope composition that is in phase with global climate cycles. Global excursions to relatively unradiogenic 187Os/188Os during glacial intervals are consistent with decreased input of radiogenic continental material, reflecting cooler temperatures and reduced continental runoff. Modelling indicates that the shift to unradiogenic values during glacial intervals could be caused by an ~30% decrease in the global river flux, with an ~5% change in river composition. If the residence time of Os in the oceans is ~5 ka then the post-glacial recovery to present-day seawater values is consistent with a corresponding increase in the river flux of around 30%. However, if the residence time of Os is closer to 40 ka, as is suggested by the global river flux, then this demands either significant changes in both the riverine Os flux and composition of around 40% and 30%, respectively, that closely follow the oxygen isotope record, or else a short-lived post-glacial pulse of weathering some 75% greater than the steady-state flux. In either case, these results clearly indicate that climatic changes affect both the flux and composition of weathered material delivered to the oceans on glacial-interglacial timescales.
    Keywords: 121-758A; DRILL; Drilling/drill rig; Indian Ocean; Joides Resolution; Leg121; Ocean Drilling Program; ODP
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 5
    Publication Date: 2024-01-09
    Description: Many marine radiogenic isotope records show both spatial and temporal variations, reflecting both the degree of mixing of distinct sources in the oceans and changes in the distribution of chemical weathering on the continents. However, changes in weathering and transport processes may themselves affect the composition of radiogenic isotopes released into seawater. The provenance of physically weathered material in the Labrador Sea, constrained through the use of Ar-Ar ages of individual detrital minerals, has been used to estimate the relative contributions of chemically weathered terranes releasing radiogenic isotopes into the Labrador Sea. A simple box-model approach for balancing observed Nd-isotope variations has been used to constrain the relative importance of localised input in the Labrador Sea, and the subsequent mixing of Labrador Sea Water into North Atlantic Deep-Water. The long-term pattern of erosion and deep-water formation around the North Atlantic seems to have been a relatively stable feature since 1.5 Ma, although there has been a dramatic shift in the nature of physical and chemical weathering affecting the release of Hf and Pb isotopes. The modelled Nd isotopes imply a relative decrease in water mass advection into the Labrador Sea between 2.4 and 1.5 Ma, accompanied by a decrease in the rate of overturning, possibly caused by an increased freshwater input into the Labrador Sea.
    Keywords: 105-647A; AGE; DRILL; Drilling/drill rig; Joides Resolution; Leg105; Number of observations; Ocean Drilling Program; ODP; South Atlantic Ocean; ε-Neodymium (0)
    Type: Dataset
    Format: text/tab-separated-values, 64 data points
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  • 6
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    Unknown
    PANGAEA
    In:  Supplement to: Reynolds, Ben C; Sherlock, Sarah C; Kelley, Simon P; Burton, Kevin W (2004): Radiogenic isotope records of Quaternary glaciations: Changes in the erosional source and weathering processes. Geology, 32(10), 861-864, https://doi.org/10.1130/G20734.1
    Publication Date: 2024-01-09
    Description: Variations of global and regional silicate weathering rates and paleo-ocean circulation patterns are estimated by using radiogenic isotope records, but the effects of changes in provenance are generally ignored. Here sediment provenance has been constrained through the use of Ar-Ar ages for individual detrital minerals from the Labrador Sea, which can be compared directly to the radiogenic isotope compositions from the same core material. Dramatic changes in the radiogenic isotope composition of North Atlantic Deep Water through the Quaternary Period are shown to reflect discrete changes in both sources and weathering processes accompanying Northern Hemisphere glaciation. Changes in the different radiogenic isotope systems reflect the influence of source, physical weathering, and chemical weathering, and not simply changes in the underlying weathering rate or ocean circulation patterns that are typically inferred.
    Keywords: 105-647A; AGE; Age, dated; Age, dated standard deviation; Argon-36/Argon-39; Argon-36/Argon-39, standard deviation; Argon-37/Argon-39; Argon-37/Argon-39, standard deviation; Argon-38/Argon-39; Argon-38/Argon-39, standard deviation; Argon-39; Argon-40; Argon-40, standard deviation; Argon-40/Argon-39; Argon-40/Argon-39, standard deviation; Calculated; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Infrared laser ablation microprobe (IRLAMP); Joides Resolution; Leg105; Method comment; Number; Ocean Drilling Program; ODP; Sample code/label; South Atlantic Ocean; Standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 4595 data points
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  • 7
    Publication Date: 2024-01-09
    Keywords: 121-758A; AGE; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Indian Ocean; Joides Resolution; Leg121; Manganese/Calcium ratio; Ocean Drilling Program; ODP; Osmium; Osmium-187/Osmium-188, error; Osmium-187/Osmium-188 ratio; Rhabdosphaera xiphos; Sample code/label
    Type: Dataset
    Format: text/tab-separated-values, 77 data points
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  • 8
    Publication Date: 2024-01-09
    Keywords: 121-758A; AGE; Burial rate of Osmium; Burial rate of Rhenium; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Indian Ocean; Joides Resolution; Leg121; Ocean Drilling Program; ODP; Osmium; Osmium-187/Osmium-188, error; Osmium-187/Osmium-188 ratio; Rhabdosphaera xiphos; Sample code/label
    Type: Dataset
    Format: text/tab-separated-values, 227 data points
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  • 9
    Publication Date: 2024-01-09
    Keywords: 209-1274A; Aluminium oxide; Calcium oxide; Calculated; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Iron oxide, Fe2O3; Joides Resolution; Leg209; Loss on ignition; Magnesium number; Magnesium oxide; Manganese oxide; Ocean Drilling Program; ODP; Potassium oxide; Sample code/label; Silicon dioxide; Sodium oxide; South Atlantic Ocean; Titanium dioxide; X-ray fluorescence (XRF)
    Type: Dataset
    Format: text/tab-separated-values, 240 data points
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  • 10
    Publication Date: 2024-01-09
    Keywords: 209-1274A; Age model; Age model, optional; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Joides Resolution; Leg209; Lithology/composition/facies; Negative-thermal ionization mass spectrometry (N-TIMS); Ocean Drilling Program; ODP; Osmium; Osmium-187/Osmium-188, error; Osmium-187/Osmium-188 ratio; Rhenium; Rhenium-187/Osmium-188 ratio; Sample code/label; South Atlantic Ocean
    Type: Dataset
    Format: text/tab-separated-values, 251 data points
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