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  • 1
    Online Resource
    Online Resource
    Bremen : MARUM - Zentrum für Marine Umweltwissenschaften, Fachbereich Geowissenschaften, Universität Bremen
    Keywords: Sonne ; Expedition
    Type of Medium: Online Resource
    Pages: Online-Ressource (185 Seiten, 4.71 MB) , Illustrationen, Diagramme, Karten
    Series Statement: Berichte aus dem MARUM und dem Fachbereich Geowissenschaften der Universität Bremen 289
    Language: English
    Note: Förderkennzeichen BMBF 03GO0828A , Unterschiede zwischen dem gedruckten Dokument und der elektronischen Ressource können nicht ausgeschlossen werden
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  • 2
    Publication Date: 2021-02-08
    Description: The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at crossover stations. The IDP2017 consists of two parts: (1) a compilation of digital data for more than 450 TEIs as well as standard hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing an on-line atlas that includes more than 590 section plots and 130 animated 3D scenes. The digital data are provided in several formats, including ASCII, Excel spreadsheet, netCDF, and Ocean Data View collection. Users can download the full data packages or make their own custom selections with a new on-line data extraction service. In addition to the actual data values, the IDP2017 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering and for statistical analysis. Metadata about data originators, analytical methods and original publications related to the data are linked in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2017 as section plots and rotating 3D scenes. The basin-wide 3D scenes combine data from many cruises and provide quick overviews of large-scale tracer distributions. These 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of tracer plumes near ocean margins or along ridges. The IDP2017 is the result of a truly international effort involving 326 researchers from 22 countries. This publication provides the critical reference for unpublished data, as well as for studies that make use of a large cross-section of data from the IDP2017.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2021-03-19
    Description: The Rare Earth Elements (REEs) have been widely used to investigate marine biogeochemical processes as well as the sources and mixing of water masses. However, there are still important uncertainties about the global aqueous REE cycle with respect to the contributions of highly reactive basaltic minerals originating from volcanic islands and the role of Submarine Groundwater Discharge (SGD). Here we present dissolved REE concentrations obtained from waters at the island-ocean interface (including SGD, river, lagoon and coastal waters) from the island of Tahiti and from three detailed open ocean profiles on the Manihiki Plateau (including neodymium (Nd) isotope compositions), which are located in ocean currents downstream of Tahiti. Tahitian fresh waters have highly variable REE concentrations that likely result from variable water–rock interaction and removal by secondary minerals. In contrast to studies on other islands, the SGD samples do not exhibit elevated REE concentrations but have distinctive REE distributions and Y/Ho ratios. The basaltic Tahitian rocks impart a REE pattern to the waters characterized by a middle REE enrichment, with a peak at europium similar to groundwaters and coastal waters of other volcanic islands in the Pacific. However, the basaltic island REE characteristics (with the exception of elevated Y/Ho ratios) are lost during transport to the Manihiki Plateau within surface waters that also exhibit highly radiogenic Nd isotope signatures. Our new data demonstrate that REE concentrations are enriched in Tahitian coastal water, but without multidimensional sampling, basaltic island Nd flux estimates range over orders of magnitude from relatively small to globally significant. Antarctic Intermediate Water (AAIW) loses its characteristic Nd isotopic signature (-6 to-9) around the Manihiki Plateau as a consequence of mixing with South Equatorial Pacific Intermediate Water (SEqPIW), which shows more positive values (-1 to -2). However, an additional Nd input/exchange along the pathway of AAIW, eventually originating from the volcanic Society, Tuamotu and Tubuai Islands (including Tahiti), is indicated by an offset from the mixing array of AAIW and SEqPIW to more radiogenic Nd isotope compositions.
    Type: Article , PeerReviewed
    Format: text
    Format: image
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  • 4
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    NATURE PUBLISHING GROUP
    In:  EPIC3Nature Geoscience, NATURE PUBLISHING GROUP, 6(10), pp. 885-890, ISSN: 1752-0894
    Publication Date: 2019-07-17
    Description: During the last glacial cycle, greenhouse gas concentrations fluctuated on decadal and longer timescales. Concentrations of methane, as measured in polar ice cores, show a close connection with Northern Hemisphere temperature variability, but the contribution of the various methane sources and sinks to changes in concentration is still a matter of debate. Here we assess changes in methane cycling over the past 160,000 years by measurements of the carbon isotopic composition δ13C of methane in Antarctic ice cores from Dronning Maud Land and Vostok. We find that variations in the δ13C of methane are not generally correlated with changes in atmospheric methane concentration, but instead more closely correlated to atmospheric CO2 concentrations. We interpret this to reflect a climatic and CO2-related control on the isotopic signature of methane source material, such as ecosystem shifts in the seasonally inundated tropical wetlands that produce methane. In contrast, relatively stable δ13C values occurred during intervals of large changes in the atmospheric loading of methane. We suggest that most methane sources—most notably tropical wetlands—must have responded simultaneously to climate changes across these periods.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Format: application/pdf
    Format: application/zip
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  • 5
    Publication Date: 2018-08-13
    Description: The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at crossover stations. The IDP2017 consists of two parts: (1) a compilation of digital data for more than 450 TEIs as well as standard hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing an on-line atlas that includes more than 590 section plots and 130 animated 3D scenes. The digital data are provided in several formats, including ASCII, Excel spreadsheet, netCDF, and Ocean Data View collection. Users can download the full data packages or make their own custom selections with a new on-line data extraction service. In addition to the actual data values, the IDP2017 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering and for statistical analysis. Metadata about data originators, analytical methods and original publications related to the data are linked in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2017 as section plots and rotating 3D scenes. The basin-wide 3D scenes combine data from many cruises and provide quick overviews of large-scale tracer distributions. These 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of tracer plumes near ocean margins or along ridges. The IDP2017 is the result of a truly international effort involving 326 researchers from 25 countries. This publication provides the critical reference for unpublished data, as well as for studies that make use of a large cross-section of data from the IDP2017. This article is part of a special issue entitled: Conway GEOTRACES - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. González.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 6
    Publication Date: 2019-06-25
    Description: Impurities in polar ice cores have been studied so far mainly for the purpose of reconstructions of past atmospheric aerosol concentrations. However, impurities also critically influence physical properties of the ice matrix itself. To improve the data basis regarding the in-situ form of incorporation and spatial distribution of impurities in ice we used micro-cryo-Raman spectroscopy to identify the location, phase and composition of micrometer-sized inclusions in natural ice samples around the transition from marine isotope stage (MIS) 6 into 5e in the EDML ice core. The combination of Raman results with ice-microsctructure measurements and complementary impurity data provided by the standard analytical methods (IC, CFA, and DEP) allows for a more interdisciplinary approach interconnecting ice core chemistry and ice core physics. While the interglacial samples were dominated by sulfate salts - mainly gypsum, sodium sulfate (possibly thenardite) and iron-potassium sulfate (likely jarosite) - the glacial ice contained high numbers of mineral dust particles - in particular quartz, mica, feldspar, anatase, hematite and carbonaceous particles (black carbon). We cannot confirm cumulation of impurities in the grain boundary network as reported by other studies, neither micro-particles being dragged by migrating grain boundaries nor in form of liquid veins in triple junctions. We argue that mixing of impurities on millimeter scale and chemical reactions are facilitated by the deforming ice matrix. We review possible effects of impurities on physical properties of ice, however the ultimate identification of the deformation agent and the mechanism behind remains challenging.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 7
    Publication Date: 2021-05-21
    Description: In the context of the Arctic amplification of climate change affecting the regional atmospheric hydrological cycle, it is crucial to characterize the present-day moisture sources of the Arctic. The isotopic composition is an important tool to enhance our understanding of the drivers of the hydrological cycle due to the different molecular characteristics of water stable isotopes during phase change. This study introduces 2 years of continuous in situ water vapour and precipitation isotopic observations conducted since July 2015 in the eastern Siberian Lena delta at the research station on Samoylov Island. The vapour isotopic signals are dominated by variations at seasonal and synoptic timescales. Diurnal variations of the vapour isotopic signals are masked by synoptic variations, indicating low variations of the amplitude of local sources at the diurnal scale in winter, summer and autumn. Low-amplitude diurnal variations in spring may indicate exchange of moisture between the atmosphere and the snow-covered surface. Moisture source diagnostics based on semi-Lagrangian backward trajectories reveal that different air mass origins have contrasting contributions to the moisture budget of the Lena delta region. At the seasonal scale, the distance from the net moisture sources to the arrival site strongly varies. During the coldest months, no contribution from local secondary evaporation is observed. Variations of the vapour isotopic composition during the cold season on the synoptic timescale are strongly related to moisture source regions and variations in atmospheric transport: warm and isotopically enriched moist air is linked to fast transport from the Atlantic sector, while dry and cold air with isotopically depleted moisture is generally associated with air masses moving slowly over northern Eurasia.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 8
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
    Format: application/pdf
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  • 9
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 10
    Publication Date: 2019-07-17
    Description: Bubble enclosures in polar ice cores represent the only direct paleoatmospheric archive. To constrain past methane sources the isotopic composition (13C and D) of CH4 in high temporal resolution and with high precision is needed. dD(CH4) is of special interest in order to constrain the origin of additional atmospheric methane during rapid warming events (Dansgaard/Oeschger events).We developed an online gas chromatography isotope ratio monitoring mass spectrometry technique (GC-irmMS) based on developments by Merritt et al. (1995) and Rice et al. (2001). The method includes gas extraction from ice, preconcentration, chromatographic separation and pyrolysis (P) of methane. Internal isotopic calibration is implemented using synthetic air and pure methane. The reproducibility of these two standards for amounts of methane typical for 500 g of glacial ice (approx. 1 nmol CH4) is better than 5 permil and 3 permil, respectively. A new tool to process raw data is presented. Differences in accuracy and precision arising from different peak integration methods are discussed.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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