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  • 1
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Carboxylic acids -- Analysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (141 pages)
    Edition: 1st ed.
    ISBN: 9781483151250
    Language: English
    Note: Front Cover -- The Determination of Carboxylic Functional Groups -- Copyright Page -- Table of Contents -- Preface -- CHAPTER 1. INTRODUCTION -- CHAPTER 2. THE DETERMINATION OF CARBOXYLIC ACIDS -- 1. GENERAL -- 2. ACID-BASE EQUILIBRIUM IN WATER -- 3 . ACID-BASE EQUILIBRIUM IN NON-AQUEOUS MEDIA -- 4 . TITRIMETRIC DETERMINATION OF ACIDS -- 5. SPECTROPHOTOMETRIC METHODS -- 6. CHROMATOGRAPHIC METHODS -- 7. COUNTERCURRENT SEPARATION OF ORGANIC ACIDS -- 8. ELECTROPHORETIC SEPARATION OF ORGANIC ACIDS -- 9 . POLAROGRAPHY OF ORGANIC ACIDS -- 10. SOME OTHER CHEMICAL METHODS -- REFERENCES -- CHAPTER 3. THE DETERMINATION OF ACID ANHYDRIDES AND ACID CHLORIDES -- A. ACID ANHYDRIDES -- B. ACID CHLORIDES -- REFERENCES -- CHAPTER 4. THE DETERMINATION OF ESTERS -- 1. GENERAL -- 2. SAPONIFICATION METHODS -- 3 . SOME SPECIFIC METHODS -- 4. SPECTROSCOPIC METHODS -- 5. CHROMATOGRAPHY OF ESTERS -- 6 . SOME OTHER PHYSICAL METHODS -- 7. DETERMINATION OF LACTONES -- REFERENCES -- CHAPTER 5. DETERMINATION OF AMIDES -- 1. GENERAL -- 2. GENERAL METHODS -- 3 . USE OF GRIGNARD'S REAGENT -- 4. SPECIFIC METHODS FOR PRIMARY AMIDES -- REFERENCES -- CHAPTER 6. THE ANALYSIS OF BINARY AND TERNARY MIXTURES -- 1. GENERAL -- 2. DIFFERENTIATION OF ACIDS -- 3. MIXTURES OF ACIDS AND ANHYDRIDES -- 4. MIXTURES OF ACIDS AND ACID CHLORIDES -- 5. MIXTURES OF ACIDS AND ESTERS -- 6. MIXTURES OF ACIDS AND AMIDES -- REFERENCES -- INDEX.
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  • 2
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Cyanogen compounds -- Analysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (153 pages)
    Edition: 1st ed.
    ISBN: 9781483278612
    Language: English
    Note: Front Cover -- Analytical Methods for Organic Cyano Groups -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER 1. INTRODUCTION -- References -- PART A: CHEMICAL METHODS -- GENERAL INTRODUCTION -- CHAPTER 2. REACTIONS OF (ADDITION TO) THE CYANO GROUP -- Introduction -- 1. Reduction: -CN-CH2-NH2 -- 2. Hydrolysis -- 3. Addition of Hydrogen Sulphide -- 4. Addition of Alcohols -- 5. Addition of Ammonia -- 6. Addition of Hydroxylamine -- 7. Addition of Hydrazine -- 8. Addition of Mercaptans -- 9. Addition of Polyphenols -- 10. Addition of Grignard Reagent -- 11. Preparation of N-(2-Chloroalkyl) amides -- 12. Formation of Metal Complexes -- References -- CHAPTER 3. REACTIONS OF GROUPS ACTIVATED BY THE CYANO GROUP -- Introduction -- 1. α,β-Unsaturated Nitriles -- 2. Compounds Containing the - CH2CN or =CHCN Group -- 3. Compounds Containing the - NH - or NH2 Group Attached to -CN -- References -- CHAPTER 4. REACTIONS OF GROUPS SENSIBLY UNAFFECTED BY THE CYANO GROUP -- 1. Higher Aliphatic Nitriles -- 2.β,γ-Unsaturated Nitriles -- 3. Aromatic Groups in Nitriles -- 4. Halogen Atoms in Trichloroacetonitrile -- 5. Azo Group in Azobisisobutyronitrile -- 6. Hydrazo Group in 2,2'-Hydrazobisisobutyronitrile -- 7. Ester Group in Nitriles -- 8. Amino Groups (not Directly Linked to a Cyano Group) -- 9. Amidino or Guanidino Group in Dicyanodiamide -- 10. Cobalt in Vitamin B12 (Cyanocobalamin) -- 11. 5,6-Dimethylbenzimidazole in Vitamin B12 -- References -- CHAPTER 5. DEGRADATION REACTIONS DURING WHICH THE CYANO GROUP REMAINS INTACT -- Introduction -- 1. Pyrolysis without Added Reagent -- 2. Pyrolysis in Presence of Oxidising Agents -- 3. Pyrolysis in Presence of a Base -- 4. Reductive Fission of N-cyano Compounds -- 5. Hydrolytic Fission of Cyanohydrins -- 6. Formation of Bromine Cyanide, BrCN. , 7. Elimination of the Cyano Group in the Analytical Methods for Ethyl Dimethylphosphoramidocyanidate (Tabun) -- 8. Elimination of the Cyano Group as Hydrocyanic Acid in Determination of Vitamin B12 -- 9. Formation of Thiocyanic Acid by Reaction with Sulphur -- References -- CHAPTER 6. DEGRADATION REACTIONS INVOLVING DESTRUCTION OF THE CYANO GROUP -- References -- CHAPTER 7. MISCELLANEOUS CHEMICAL METHODS -- References -- PART B: PHYSICAL METHODS -- GENERAL INTRODUCTION -- CHAPTER 8. SPECTROSCOPIC AND SPECTROPHOTOMETRIC METHODS -- 1. Infrared -- 2. Ultraviolet and Visible -- 3. Mass Spectrometry -- 4. Flame Spectroscopy -- 5. Nuclear Magnetic Resonance -- References -- CHAPTER 9. CHROMATOGRAPHIC METHODS -- 1. Gas Chromatography -- 2. Other Chromatographic Methods, Principally PC and TLC -- References -- CHAPTER 10. ION EXCHANGE -- References -- CHAPTER 11. POLAROGRAPHY -- References -- CHAPTER 12. AZEOTROPIC DISTILLATION -- References -- AUTHOR INDEX -- SUBJECT INDEX.
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  • 3
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Epoxy compounds -- Analysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (88 pages)
    Edition: 1st ed.
    ISBN: 9781483150536
    Language: English
    Note: Front Cover -- The Determination of Epoxide Groups -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER 1. INTRODUCTION -- 1. General considerations -- 2. The determination of epoxide groups -- 3. Analytical methods -- References -- CHAPTER 2. METHODS INVOLVING EPOXIDE RING-OPENING BY HALOGEN ACIDS -- INTRODUCTION -- 1. Procedures considered -- 2. General comments -- 3. Interference effects -- 4. Convenience of the various procedures -- 5. Accuracy -- 6. Conclusions -- References -- CHAPTER 3. OTHER METHODS FOR EPOXIDE DETERMINATION -- INTRODUCTION -- 1. Methods considered -- 2. General comments -- References -- CHAPTER 4. CONCLUSIONS -- Chemical methods -- Physical methods -- Very sensitive methods -- Final comments -- INDEX.
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  • 4
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Hydrazides -- Analysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (410 pages)
    Edition: 1st ed.
    ISBN: 9781483153001
    Language: English
    Note: Front Cover -- The Determination of Hydrazino-Hydrazide Groups -- Copyright Page -- Table of Contents -- Dedication -- PREFACE -- GENERAL INTRODUCTION -- CHAPTER 1. OXIDATION METHODS -- 1. Use of Bromate -- 2. Use of Bromine -- 3. Use of N-Bromosuccinimide -- 4. Use of Ceric Sulfate -- 5. Use of Ceric Sulfate-Iodine Monochloride -- 6. Use of Diethylenetetraammonium Ceric Sulfate -- 7. Use of Chloramine-T -- 8. Use of Chloramine-T-Iodine Monochloride -- 9. Use of Chloramine-B -- 10. Use of Chloramine-B-Iodine Monochloride -- 11. Use of Copper Oxide -- 12. Use of Copper Oxide-Fehling's Solution -- 13. Use of Copper Sulfate -- 14. Use of Dichromate -- 15. Use of Potassium Ferricyanide-Ascorbic Acid -- 16. Use of Ferricyanide-Ceric Sulfate -- 17. Use of Ferricyanide-Zinc Sulfate -- 18. Use of Hypochlorous Acid -- 19. Use of Hypochlorite -- 20. Use of lodic Acid -- 21. Use of Iodine -- 22. Use of Iodate -- 23. Use of Periodate -- 24. Use of Periodate-Iodine Bromide -- 25· Use of Periodate-Iodine Cyanide -- 26. Use of Permanganate -- 27. Use of Selenious Acid -- 28. Use of Thallium -- 29. Use of Vanadic Acid -- References -- CHAPTER 2. GASOMETRIC METHODS -- 1. Use of Bromate -- 2. Use of Bromine-Hypobromite -- 3. Use of Cupric-Fehling's Solution -- 4. Use of Cupric Sulfate -- 5. Use of Ferricyanide -- 6. Use of Iodate -- 7. Use of Lead Oxide -- 8. Use of Mercuric Chloride -- References -- CHAPTER 3. COLORIMETRIC AND SPECTROPHOTOMETRIC METHODS -- 1. Determination of Isonicotinic Acid Hydrazide (INH) -- 2. Determination of Maleic Hydrazide -- 3. Determination of Hydrazine -- 4. Determination of Hydrazine and Benzylhydrazine -- 5. Determination of 1,1-Dimethylhydrazine (UDMH) -- 6. Determination of Monomethylhydrazine -- References -- CHAPTER 4. CHROMATOGRAPHIC METHODS -- 1. Ion Exchange Chromatography -- 2. Paper Chromatography. , 3. Thin Layer Chromatography -- References -- CHAPTER 5. COULOMETRIC METHODS -- 1. Determination of Hydrazine and Substituted Hydrazines -- References -- CHAPTER 6. POLAROGRAPHIC METHODS -- 1. Determination of Hydrazine, Phenylhydrazine, and Semicarbazide -- 2. Determination of Isonicotinic Acid Hydrazide -- 3. Determination of p,p-Oxybis (Benzenesulfonyl) Hydrazide -- References -- CHAPTER 7. ACID-BASE METHODS -- 1. Aqueous Methods -- 2. Non-aqueous Methods -- References -- CHAPTER 8. THE ANALYSIS OF MIXTURES -- 1. Hydrazine-l,l-Dimethylhydrazine Mixtures -- 2. Hydrazine-Monomethylhydrazine Mixtures -- 3. Hydrazine-1,1-Dimethylhydrazine and Monomethylhydrazine-1,1-Dimethylhydrazine Mixtures -- 4. Hydrazine-Monomethylhydrazine-I,I- Dimethylhydrazine Mixtures -- 5. Hydrazine-Aniline Mixtures -- 6. Hydrazine-Ammonia Mixtures -- 7. Hydrazine-Ammoida-Hydrogen-Nitrogen-Argon Mixtures -- 8. Hydrazine-Hydroxylamine Mixtures -- 9. Hydrazine-Ammonium Hydroxide-Hydroxylamine Mixtures -- 10. Hydrazine-Hydrazine Nitrate Mixtures -- 11. Determination of Diethylenetriamine (DETA) with either Hydrazine, Monomethylhydrazine, or 1,1-Dimethylhydrazine -- References -- CHAPTER 9. OTHER QUALITATIVE AND QUANTITATIVE TESTS -- 1. Spot Tests -- 2. Microbiological Tests -- 3. Field Tests -- References -- CHAPTER 10. THE USE OF HYDRAZINES AS ANALYTICAL REAGENTS -- 1. Use of 1,1-Dimethylhydrazine -- 2. Use of 2,4-Dinitrophenylhydrazine -- 3. Use of 1,5-Diphenylcarbazide -- 4. Use of Hydrazine -- 5. Use of 2-Hydrazinobenzothiazole -- 6. Use of Isonicotinic Acid Hydrazide -- 7. Use of Oxalyldihydrazide -- 8. Use of Phenylhydrazine -- 9. Use of Salicyloylhydrazide -- 10. Use of Semicarbazide -- References -- AUTHOR INDEX -- SUBJECT INDEX -- OTHER TITLES IN THE SERIES IN ORGANIC FUNCTIONAL GROUP ANALYSIS.
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  • 5
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Peroxides -- Analysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (130 pages)
    Edition: 1st ed.
    ISBN: 9781483160191
    Language: English
    Note: Front Cover -- The Determination of Organic Peroxides -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER 1. INTRODUCTION -- 1. Lipid Peroxides -- 2 . Polymers -- 3 . Petrochemicals -- 4 . Irradiation -- 5. Miscellaneous -- References -- CHAPTER 2 . STRUCTURE AND REACTIVITY -- 1 . Classification of peroxides -- 2 . Reactivity -- References -- CHAPTER 3. IODOMETRIC METHODS -- 1 . General comments -- 2. Choice of solvent -- 3 . Reaction conditions -- 4 . Titration with thiosulphate -- References -- CHAPTER 4 . FERROUS ION METHODS -- 1 . Introduction -- 2 . Choice of reagent -- 3. Choice of solvent -- 4 . Titration with titanous ions -- 5 . Titration with dichromate ions -- 6 . Titration with mercurous ions -- References -- CHAPTER 5. FURTHER TITRIMETRIC REAGENTS -- 1 . Introduction -- 2 . Arsenious methods -- 3 . Stannous methods -- 4 . Titanous methods -- 5 . Titration with anions -- 6. Sulphides and mercaptans -- References -- CHAPTER 6 . COLORIMETRIC METHODS -- 1 . Introduction -- 2 . Ferrous ions -- 3 . Leuco base of methylene blue -- 4 . Iodine -- 5. iV,A^'-Dimethyl-/?-phenylenediamme -- 6. Other colorimetric reagents -- References -- CHAPTER 7 . POLAROGRAPHIC METHODS -- 1 . Introduction -- 2 . Electrode reaction -- 3 . Polarographic teclmiques for peroxides -- 4 . Nature and concentration of peroxide -- 5 . Solvents and supporting electrolytes -- References -- CHAPTER 8. SPECTROSCOPIC TECHNIQUES -- 1 . Introduction -- 2 . Ultraviolet and visible absorption -- 3 . Infrared absorption -- 4 . Raman spectroscopy -- References -- CHAPTER 9 . CHROMATOGRAPHIC METHODS A. COLUMN CHROMATOGRAPHY -- 1 . Introduction -- 2 . Column techniques -- 3 . Solvent medium -- 4 . Stationary phase -- 5 . Type of peroxide -- References -- CHAPTER 10 . CHROMATOGRAPHIC METHODS B. PAPER CHROMATOGRAPHY -- 1 . Introduction -- 2 . Choice of paper. , 3. Mobile phase -- 4 . General techniques -- 5 . Chemical structure -- 6 . Detection -- 7 . Class of peroxide -- References -- CHAPTER 11 . CHROMATOGRAPHIC METHODS C. THIN-LAYER CHROMATOGRAPHY -- 1 . Introduction -- 2 . Adsorbents -- 3 . Solvent systems -- 4. Detection -- 5. Techniques -- 6. Applications -- References -- CHAPTER 12. CHROMATOGRAPHIC METHODS D. GAS CHROMATOGRAPHY -- 1. Introduction -- 2. Solid support -- 3. Stationary phase -- 4. Column temperature -- 5. Functional groups -- 6. Quantitative analysis -- References -- CHAPTER 13. CHOICE OF METHOD -- 1. Introduction -- 2. Concentration of peroxide -- 3. Reactivity of peroxide -- 4. Nature of the sample -- INDEX.
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  • 6
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Oxidation. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (204 pages)
    Edition: 1st ed.
    ISBN: 9781483160801
    Language: English
    Note: Front Cover -- Periodate Oxidation of Diol and Other Functional Groups: Analytical and Structural Applications -- Copyright Page -- Table of Contents -- PREFACE -- INTRODUCTION -- CHAPTER 1. HISTORY -- Literature Cited -- CHAPTER 2. PREPARATION AND PROPERTIES OF PERIODATES -- Preparation -- Solubility -- Stability of Aqueous Solutions -- Standard Potentials -- Ionization of Periodic Acid -- Structure of Periodates -- Literature Cited -- CHAPTER 3. MECHANISM OF PERIOD ATE OXIDATION -- 1,2-Diols -- 1,2-Hydroxycarbonyl Compounds and 1,2-Diketones -- 1,2-Aminoalcohols -- Active Méthylène Groups -- Literature Cited -- CHAPTER 4. ANOMALOUS PERIODATE OXIDATIONS -- Overoxidation -- Sulfur-containing Compounds -- Phenols -- Flavanols -- Amines -- Amino Acids -- Unsaturated Sugars -- Amino Sugars -- Proteins -- Oxidations at Elevated Temperature -- Oxidations in the Presence of Light -- Literature Cited -- CHAPTER 5. PERIODATE OXIDATION IN STRUCTURAL STUDIES -- Structure Assignment based on Periodate Oxidation Information -- Structure Assignment based on Periodate Oxidation and Other Information -- Structure and End-group Assay of Polysaccharides -- Nature of the Product of Periodate Oxidation -- Literature Cited -- CHAPTER 6. ANALYTICAL METHODS -- Conditions of the Oxidation -- Determination of Oxidant Consumption -- Other Methods for Periodate Determination -- Determination of Acid Produced -- Determination of Other Acids -- Determination of Formaldehyde -- Determination of Acetaldehyde -- Determination of Ammonia and Amines -- Determination of Carbon Dioxide -- Recommended General Methods -- Conclusions -- Literature Cited -- CHAPTER 7. SYNTHETIC AND OTHER APPLICATIONS OF PERIODATE OXIDATIONS -- Literature Cited -- AUTHOR INDEX -- SUBJECT INDEX.
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  • 7
    Keywords: Konferenzschrift ; Meereskunde ; Mikroalgen
    Type of Medium: Book
    Pages: XV, 551 S. , Ill., graph. Darst.
    Series Statement: Manuals and guides / Intergovernmental Oceanographic Commission 33
    Language: English
    Note: Literaturangaben , Subject index S. 545 - 547 , Taxonomical index S. 549 - 551
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  • 8
    Keywords: Aufsatzsammlung
    Type of Medium: Book
    Pages: S. 2365 - 2876 , Ill., graph. Darst
    Series Statement: Deep sea research 52.2005,19/21
    Language: English
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  • 9
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 47 (1955), S. 1604-1604 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 9 (1997), S. 1870-1879 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present a diffuse-interface treatment of the internal gravity waves which have been observed experimentally by Berg et al. in xenon near its thermodynamic critical point. The results are compared with theoretical predictions by Berg et al. that were obtained using separate models above and below the critical temperature Tc. The diffuse-interface model applies both above and below Tc, and is formulated by using the density as an order parameter. The diffuse interface is represented as a transition zone of rapid but smooth density variation in the model, and density gradients appear in a capillary tensor, or Korteweg stress term, in the momentum equation. We obtain static density profiles, compute internal wave frequencies and compare with the experimental data and theoretical results of Berg et al. both above and below the critical temperature. The results reveal a singularity in the diffuse-interface model in the limit of incompressible perturbations.
    Type of Medium: Electronic Resource
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