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  • 1
    Keywords: English language Dictionaries ; German ; German language Dictionaries ; English ; Law Dictionaries ; English ; Law Dictionaries ; German ; Wörterbuch ; Recht ; Englisch ; Recht ; Deutsch ; Englisch ; Deutsch ; Recht
    Type of Medium: Book
    Pages: 699 S.
    Edition: 2., bearb. und erw. Aufl.
    ISBN: 9783861173106 , 9783867520843 , 9783125140851
    Series Statement: Langenscheidt Fachwörterbücher
    DDC: 340
    RVK:
    Language: German , English
    Note: Achtung! Parallelausgabe mit CD-ROM , Text dt. und engl.
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  • 2
    Publication Date: 2023-07-07
    Description: Data from pore water (subterranean estuary) and seawater from Spiekeroog south (near ICBM time series station and campsite) and west beach ("Sturmeck"). South beach data were collected in August 2012, and west beach data were collected in November 2012. Pore water (event labels: DUNE, MIX, LTWL) sample collection was conducted at different sediment depths (50, 100, 150 cm below sediment surface). Stainless steel push-point lancets were insetred into the sediment, and pore water was withdrawn via vacuum (hand pumps) into nalgene polycarbonate bottles. Filtration was done using inline PES cartridge filters. The vacuum bottles were argon gas-flushed to avoid oxygen contamination. Sea water (event label SW) was collected with polycarbonate bottles and from LDPE seepage meter bags (event label SP) and filtered upon return to the laboratory (same day, PES filter cartridges). Sample collection was trace organic and metal clean (soaking and rinsing of bottles, tubing, and filters with diluted HNO3 and HCl suprapur), with sample materials consisting of polyethylene, polypropylene, and polycarbonate. Solid-phase extraction was done with BOND Elut PPL cartridges and elution with Methanol Optima grade. Measurements dissolved organic matter (DOM) were done with FT-ICR-MS. The crosstables describe the molecular composition of DOM and associated Fe and Cu. They contain characteristic properties and classifications of molecular sum formulas as well as FT-ICR-MS signal intensities of each sum formula for each sample (see event table of https://doi.pangaea.de/10.1594/PANGAEA.902704). File name description of “Spiekeroog beach STE_ESI_x_Crosstab_x": pos & neg = positive and negative ionization mode of electrospray ionization (ESI). BSA & NWA = basic/strong acidic and neutral/weak acidic DOM fraction (solid phase extracted)
    Keywords: copper; DOM trace metals; File content; File format; File name; File size; ICBM; Institut für Chemie und Biologie des Meeres; iron; ligands; pore water; subterranean estuary; Uniform resource locator/link to file
    Type: Dataset
    Format: text/tab-separated-values, 20 data points
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  • 3
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    PANGAEA
    In:  Supplement to: Waska, Hannelore; Brumsack, Hans-Jürgen; Massmann, Gudrun; Koschinsky, Andrea; Schnetger, Bernhard; Simon, Heike; Dittmar, Thorsten (2019): Inorganic and organic iron and copper species of the subterranean estuary: Origins and fate. Geochimica et Cosmochimica Acta, 259, 211-232, https://doi.org/10.1016/j.gca.2019.06.004
    Publication Date: 2023-07-07
    Description: Data from pore water (subterranean estuary) and seawater from Spiekeroog south (near ICBM time series station and campsite, 53°45'13.5"N 7°40'22.5"E) and west beach ("Sturmeck", 53°46'10.0"N 7°40'26.2"E). South beach data were collected in August 2012, and west beach data were collected in November 2012. Sample abbreviations: SB=South Beach, WB=West Beach. DUNE=most landward station near dunes, MIX=mid-way station between dune base and low water line, LTWL=low tide water line. Pore water (DUNE, MIX, LTWL) sample collection was conducted at different sediment depths (50, 100, 150 cm below sediment surface). Stainless steel push-point lancets were insetred into the sediment, and pore water was withdrawn via vacuum (hand pumps) into nalgene polycarbonate bottles. Filtration was done using inline PES cartridge filters. The vacuum bottles were argon gas-flushed to avoid oxygen contamination. Sea water (SW) was collected with polycarbonate bottles and from LDPE seepage meter bags (SP) and filtered upon return to the laboratory (same day, PES filter cartridges). Sample collection was trace organic and metal clean (soaking and rinsing of bottles, tubing, and filters with diluted HNO3 and HCl suprapur), with sample materials consisting of polyethylene, polypropylene, and polycarbonate. Solid-phase extraction was done with BOND Elut PPL cartridges and elution with Methanol Optima grade. Measurements were done with VA Computrace 757 (Cu ligand concentrations and stability constants), HR-ICP-MS (Cu, Fe, and Mn concentrations), FT-ICR-MS (DOM), spectrophotometry (nutrients), and TOC analyzer (DOC and TDN). Trace metal concentrations (Fe, Cu, Mn) and speciation (oxidation state, size fractions, and organic association), as well as nitrogen species and concentrations: "Spiekeroog beach subterranean estuary environmental data". Concentrations (µM or nM) are denoted in the headers. CuL1=Cu-binding ligands concentrations (nM), logK1=Cu-binding ligand stability constant. Molecular composition of dissolved organic matter and associated Fe and Cu: "Spiekeroog beach STE_ESI_x_Crosstab_x". pos & neg = positive and negative ionization mode. BSA & NWA = basic/strong acidic and neutral/weak acidic, refer to the extracted DOM fraction. Processed figures and tables based on the original data are published here: https://doi.org/10.1016/j.gca.2019.06.004
    Keywords: copper; DOM trace metals; ICBM; Institut für Chemie und Biologie des Meeres; iron; ligands; pore water; subterranean estuary
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 4
    Publication Date: 2024-03-22
    Description: Data from pore water (subterranean estuary) and seawater from Spiekeroog south (near ICBM time series station and campsite) and west beach ("Sturmeck"). South beach data were collected in August 2012, and west beach data were collected in November 2012. Pore water (event labels: DUNE, MIX, LTWL) sample collection was conducted at different sediment depths (50, 100, 150 cm below sediment surface). Stainless steel push-point lancets were insetred into the sediment, and pore water was withdrawn via vacuum (hand pumps) into nalgene polycarbonate bottles. Filtration was done using inline PES cartridge filters. The vacuum bottles were argon gas-flushed to avoid oxygen contamination. Sea water (event label SW) was collected with polycarbonate bottles and from LDPE seepage meter bags (event label SP) and filtered upon return to the laboratory (same day, PES filter cartridges). Sample collection was trace organic and metal clean (soaking and rinsing of bottles, tubing, and filters with diluted HNO3 and HCl suprapur), with sample materials consisting of polyethylene, polypropylene, and polycarbonate. Solid-phase extraction was done with BOND Elut PPL cartridges and elution with Methanol Optima grade. Measurements were done with VA Computrace 757 (Cu ligand concentrations and stability constants), HR-ICP-MS (Cu, Fe, and Mn concentrations), spectrophotometry (nutrients), and TOC analyzer (DOC and TDN).
    Keywords: Ammonium; Bottle, polycarbonate, Nalgene; Carbon, organic, dissolved, colloidal; Carbon, organic, dissolved, soluble; Carbon, organic, dissolved, total; Carbon, organic, dissolved of basic/strong acidic dissolved organic matter fraction; Carbon, organic, dissolved of neutral/weak acidic dissolved organic matter fraction; competitive ligand equilibration/adsorptive cathodic stripping voltammetry (Buck and Bruland, 2005); copper; Copper, colloidal; Copper, soluble; Copper, total; Copper-binding ligand 1; Copper-binding ligand 1, conditional stability constant; Copper of basic/strong acidic dissolved organic matter fraction; Copper of neutral/weak acidic dissolved organic matter fraction; DEPTH, sediment/rock; DOM trace metals; Event label; high resolution inductively coupled plasma mass spectrometry; ICBM; Institut für Chemie und Biologie des Meeres; iron; Iron, colloidal; Iron, ferrous, divalent; Iron, soluble; Iron, total; Iron of basic/strong acidic dissolved organic matter fraction; Iron of neutral/weak acidic dissolved organic matter fraction; Latitude of event; LDPSMB; ligands; Longitude of event; Low density polyethylen seepage meter bag; Manganese; NB_PC; Nitrogen, organic, dissolved; Nitrogen, total, dissolved of basic/strong acidic dissolved organic matter fraction; Nitrogen, total, dissolved of neutral/weak acidic dissolved organic matter fraction; Nitrogen, total dissolved, soluble; Nitrogen, total dissolved, total; Nitrogen oxide; pore water; Salinity; SB_DUNE; SB_LTWL; SB_MIX; SB_SP1; SB_SP2; SB_SW1; SB_SW2; Shimadzu TOC-VCPH total organic carbon analyzer; Spectrophotometry, ferrozine (Viollier et al., 2000); Spectrophotometry (Reckhardt et al., 2015); Spiekeroog, German Bight, North Sea; SSPP; stainless steel push-point lancet; subterranean estuary; WB_DUNE; WB_LTSW; WB_LTWL; WB_MIX; WB_SP1; WB_SP2; WB_SW1; WB_SW2
    Type: Dataset
    Format: text/tab-separated-values, 750 data points
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  • 5
    Publication Date: 2021-04-13
    Description: Advective flows of seawater and fresh groundwater through coastal aquifers form a unique ecohydrological interface, the subterranean estuary (STE). Here, freshly produced marine organic matter and oxygen mix with groundwater, which is low in oxygen and contains aged organic carbon (OC) from terrestrial sources. Along the groundwater flow paths, dissolved organic matter (DOM) is degraded and inorganic electron acceptors are successively used up. Because of the different DOM sources and ages, exact degradation pathways are often difficult to disentangle, especially in high-energy environments with dynamic changes in beach morphology, source composition, and hydraulic gradients. From a case study site on a barrier island in the German North Sea, we present detailed biogeochemical data from freshwater lens groundwater, seawater, and beach porewater samples collected over different seasons. The samples were analyzed for physico-chemistry (e.g., salinity, temperature, dissolved silicate), (reduced) electron acceptors (e.g., oxygen, nitrate, and iron), and dissolved organic carbon (DOC). DOM was isolated and molecularly characterized via soft-ionization ultra-high-resolution mass spectrometry, and molecular formulae were identified in each sample. We found that the islands’ freshwater lens harbors a surprisingly high DOM molecular diversity and heterogeneity, possibly due to patchy distributions of buried peat lenses. Furthermore, a comparison of DOM composition of the endmembers indicated that the Spiekeroog high-energy beach STE conveys chemically modified, terrestrial DOM from the inland freshwater lens to the coastal ocean. In the beach intertidal zone, porewater DOC concentrations, lability of DOM and oxygen concentrations, decreased while dissolved (reduced) iron and dissolved silicate concentrations increased. This observation is consistent with the assumption of a continuous degradation of labile DOM along a cross-shore gradient, even in this dynamic environment. Accordingly, molecular properties of DOM indicated enhanced degradation, and “humic-like” fluorescent DOM fraction increased along the flow paths, likely through accumulation of compounds less susceptible to microbial consumption. Our data indicate that the high-energy beach STE is likely a net sink of OC from the terrestrial and marine realm, and that barrier islands such as Spiekeroog may act as efficient “digestors” of organic matter.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 6
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    PERGAMON-ELSEVIER SCIENCE LTD
    In:  EPIC3Geochimica et Cosmochimica Acta, PERGAMON-ELSEVIER SCIENCE LTD, 259, pp. 211-232, ISSN: 0016-7037
    Publication Date: 2020-10-07
    Description: Subterranean estuaries (STEs) are land-ocean interfaces where meteoric fresh groundwater mixes with intruding seawater in a coastal aquifer, before discharging into the adjacent water column. In contrast to surface estuaries, STEs have the potential to amplify concentrations of constituents such as copper (Cu) and iron (Fe) due to long residence times and reductive dissolution of mineral phases along the groundwater flowpaths. However, oxidative precipitation of Fe and Mn at the sediment-water interface may scavenge many constituents again before they reach the coastal water column. Hence, the geochemical impact of the suboxic to anoxic submarine groundwater discharge (SGD) on the oxygenated coastal ocean relies on the capability of constituents such as Cu and Fe to stay in solution across redox boundaries. Here, we propose that dissolved organic matter (DOM) in the STE plays a pivotal role in the speciation of Cu and Fe through (i) fueling reductive dissolution and (ii) providing ligands to form stable metal-DOM complexes, increasing their transfer from the STE into the coastal ocean. We investigated the concentrations and speciation of Cu and Fe, and DOM chemical characteristics, in two beach STEs of a barrier island. By combining well-established techniques with novel quantification and speciation approaches from both the inorganic and organic geochemical realm (size-fractionation filtration, ferrozine detection, voltammetry, sequential DOM extraction, and ultra-high resolution mass spectrometry) we characterized metal-DOM associations down to the molecular level. Overall, pore water from both STEs was enriched with Cu and Fe compared to seawater, which indicated transfer potential for both trace metals across the sediment-water interface. However, Fe gradients from pore water to surface were steeper than those for Cu, indicating a larger net transfer of the latter compared to the former. Our voltammetry data showed that Cu was exclusively organically bound in both STEs and the water column, mostly in soluble form (〈20 nm). The majority of 〉60 newly identified Cu-containing complexes had primarily aliphatic character and N and S in their molecular formulae resembling labile marine DOM, while two Cu-DOM complexes had polyphenol (“humic-like”) molecular formulae indicative of terrestrial vascular plant-derived material. In contrast to Cu, the Fe pool consisted of either reduced, soluble (〈20 nm), likely free Fe(II) in the anoxic STE, or of larger colloids (〈200 nm and 〉20 nm) in the fresh groundwater and seawater endmembers, likely as Fe(III)(hydr)oxides stabilized by DOM. Furthermore, while Fe and humic-like DOM seemed to share common sources, all directly identified mobile Fe-DOM complexes appeared to have marine origins. Therefore, organic forms of Fe in the STE may primarily consist of immobile humic-Fe coagulates, partially mobile Fe-nanocolloids, and mobile, N-containing, marine aliphatic Fe-complexes. Our study indicates that aliphatic, N-containing ligands may play an important role in the organic complexation and stabilization of Fe and particularly Cu in the STE, and enable them to cross redox boundaries at the sediment-water interface.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
    Format: application/pdf
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  • 7
    Publication Date: 2021-11-16
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
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  • 8
    Publication Date: 2012-07-05
    Description: A dual function of Bcl11b/Ctip2 in hippocampal neurogenesis The EMBO Journal 31, 2922 (2012). doi:10.1038/emboj.2012.142 Authors: Ruth Simon, Heike Brylka, Herbert Schwegler, Sathish Venkataramanappa, Jacqueline Andratschke, Christoph Wiegreffe, Pentao Liu, Elaine Fuchs, Nancy A Jenkins, Neal G Copeland, Carmen Birchmeier & Stefan Britsch The development of the dentate gyrus is characterized by distinct phases establishing a durable stem-cell pool required for postnatal and adult neurogenesis. Here, we report that Bcl11b/Ctip2, a zinc finger transcription factor expressed in postmitotic neurons, plays a critical role during postnatal development of
    Keywords: Bcl11b/Ctip2dentate gyrusneurogenesistranscription factor
    Print ISSN: 0261-4189
    Electronic ISSN: 1460-2075
    Topics: Biology , Medicine
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  • 9
    Publication Date: 2012-12-01
    Description: Nature Photonics 6, 858 (2012). doi:10.1038/nphoton.2012.261 Authors: Benedikt Rudek, Sang-Kil Son, Lutz Foucar, Sascha W. Epp, Benjamin Erk, Robert Hartmann, Marcus Adolph, Robert Andritschke, Andrew Aquila, Nora Berrah, Christoph Bostedt, John Bozek, Nicola Coppola, Frank Filsinger, Hubert Gorke, Tais Gorkhover, Heinz Graafsma, Lars Gumprecht, Andreas Hartmann, Günter Hauser, Sven Herrmann, Helmut Hirsemann, Peter Holl, André Hömke, Loic Journel, Christian Kaiser, Nils Kimmel, Faton Krasniqi, Kai-Uwe Kühnel, Michael Matysek, Marc Messerschmidt, Danilo Miesner, Thomas Möller, Robert Moshammer, Kiyonobu Nagaya, Björn Nilsson, Guillaume Potdevin, Daniel Pietschner, Christian Reich, Daniela Rupp, Gerhard Schaller, Ilme Schlichting, Carlo Schmidt, Florian Schopper, Sebastian Schorb, Claus-Dieter Schröter, Joachim Schulz, Marc Simon, Heike Soltau, Lothar Strüder, Kiyoshi Ueda, Georg Weidenspointner, Robin Santra, Joachim Ullrich, Artem Rudenko & Daniel Rolles
    Print ISSN: 1749-4885
    Electronic ISSN: 1749-4893
    Topics: Physics
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