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  • 1
    Keywords: Evolution (Biology) -- Congresses. ; Geomicrobiology -- Congresses. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (362 pages)
    Edition: 1st ed.
    ISBN: 9781402083068
    Series Statement: Modern Approaches in Solid Earth Sciences Series ; v.4
    DDC: 550.1579
    Language: English
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  • 2
    ISSN: 1520-5029
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Energy & fuels 6 (1992), S. 540-544 
    ISSN: 1520-5029
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1440-1738
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract  The Solund-Stavfjord ophiolite complex (SSOC) in western Norway represents a remnant of the Late Ordovician oceanic lithosphere, which developed in an intermediate- to fast-spreading Caledonian back-arc basin. The internal architecture and magmatic features of its crustal component suggest that the SSOC has a complex, multistage sea floor spreading history in a supra-subduction zone environment. The youngest crustal section associated with the propagating rift tectonics consists of a relatively complete ophiolite pseudostratigraphy, including basaltic volcanic rocks, a transition zone between the sheeted dyke complex and the extrusive sequence, sheeted dykes, and high-level isotropic gabbros. Large-scale variations in major and trace element distributions indicate significant remobilization far beyond that which would result from magmatic processes, as a result of the hydrothermal alteration of crustal rocks. Whereas K2O is strongly enriched in volcanic rocks of the extrusive sequence, Cu and Zn show the largest enrichment in the dyke complex near the dyke–volcanic transition zone or within this transition zone. The δ18O values of the whole-rock samples show a general depletion structurally downwards in the ophiolite, with the largest and smallest variations observed in volcanic rocks and the transition zone, respectively. δ18O values of epidote–quartz mineral pairs indicate 260–290°C for volcanic rocks, 420°C for the transition zone, 280–345°C for the sheeted dyke complex and 290–475°C for the gabbros. The 87Sr/86Sr isotope ratios show the widest range and highest values in the extrusive rocks (0.70316–0.70495), and generally the lowest values and the narrowest range in the sheeted dyke complex (0.70338–0.70377). The minimum water/rock ratios calculated show the largest variations in volcanic rocks and gabbros (approximately 0–14), and generally the lowest values and range in the sheeted dyke complex (approximately 1–3). The δD values of epidote (−1 to −12‰), together with the δ18O calculated for Ordovician seawater, are similar to those of present-day seawater. Volcanic rocks experienced both cold and warm water circulation, resulting in the observed K2O-enrichment and the largest scatter in the δ18O values. As a result of metal leaching in the hot reaction zone above a magma chamber, Zn is strongly depleted in the gabbros but enriched in the sheeted dyke complex because of precipitation from upwelling of discharged hydrothermal fluids. The present study demonstrates that the near intact effect of ocean floor hydrothermal activity is preserved in the upper part of the SSOC crust, despite the influence of regional lower greenschist facies metamorphism.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 91 (1985), S. 188-195 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Anomalously low and variable 18O/16O ratios (whole rock δ 18OSMOW=−1.9 to +6.0) have been measured in several Late Proterozoic metamorphic units associated with a large scale low-angle ductile shear zone at Meatiq Dome in the central Eastern Desert of Egypt. The low-18O units consist of granite gneiss, quartzofeldspathic mylonite, and quartz phyllonite. These are intruded by syntectonic diorite-tonalite-granodiorite and post-tectonic granite, both having normal δ 18O. No evidence for other low-18O country rock units has been found. Oxygen isotope fractionation between quartz and magnetite in the granite gneiss (Δ QZ-MT=8.0 to 9.3) is consistent with equilibration at amphibolite grade temperatures, suggesting that 18O depletion occurred prior to metamorphism. Whole rock geochemical analyses indicate that the low-18O units were derived from two granitic protoliths, one of which apparently underwent local sericitic alteration prior to metamorphism; it is proposed that 18O depletion and sericitic alteration occurred simultaneously in a high-temperature meteorichydrothermal system associated with emplacement of these granitic protoliths. The relatively high ductility of the sericitically altered rock may have been an important factor in the subsequent localization of the shear zone.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 77 (1981), S. 150-157 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract δ 18O and87Sr/86Sr isotopic data from smectites, calcites, and whole rocks, together with published isotopic age determinations, alkali element concentration data and petrographic observations suggest a sequential model of ocean floor alteration. The early stage lasts about 3 m.y. and is characterized by palagonite and smectite formation, and solutions with a large basaltic component, increasing with temperature which varies from 15° to 80° C at DSDP site 418A. Most carbonates are depositedafter this stage from solutions with a negligible basaltic Sr component and temperatures of 15° to 40° C. Water of seawater Sr and O isotopic composition is shown to percolate to at least 500 m into the basaltic basement. No evidence was found for continuing exchange of strontium or oxygen after 3 m.y.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 74 (1980), S. 285-292 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Isotopic compositions were determined for quartz, sericite and bulk rock samples surrounding the Uwamuki no. 4 Kuroko ore body, Kosaka, Japan. δ 18O values of quartz from Siliceous Ore (S.O.), main body of Black Ore B.O.) and the upper layer of B.O. are fairly uniform, +8.7 to +10.5‰. Formation temperatures calculated from fractionation of 18O between sericite and quartz from B.O. and upper S.O. are 250° to 300° C. The ore-forming fluids had δ 18O values of +1‰ and δD values of −10‰, from isotope compositions of quartz and sericite. Tertiary volcanic rocks surrounding the ore deposits at Kosaka have uniform δ 18O values, +8.1±1.0‰ (n=50), although their bulk chemical compositions are widely varied because of different degrees of alteration. “White Rhyolite”, which is an intensely altered rhyolite occurring in close association with the Kuroko ore bodies, has also uniform δ 18O values, +7.9±0.9‰ (n=19). Temperatures of alteration are estimated to be around 300° C from the oxygen isotope fractionation between quartz and sericite. Paleozoic basement rocks phyllite and chert, have high δ 18O values, +18 and +19‰. The Sasahata formation of unknown age, which lies between Tertiary and Paleozoic formations, has highly variable δ 18O, +8 to +16‰ (n=4). High δ 18O values of the basement rocks and the sharp difference in δ 18O at their boundary suggest that the hydrothermal system causing Kuroko mineralization was mainly confined within permeable Tertiary rocks. δD values of altered Tertiary volcanic rocks are highly variable ranging from −34 to −64% (n=12). The variation of δD does not correlate with change of chemical composition, δ 18O values, nor distance from the ore deposits. The relatively high δD values of the altered rocks indicate that the major constituent of the hydrothermal fluid was sea water. However, another fluid having lower δD must have also participated. The fluid could be “evolved” sea water modified by interaction with rocks and the admixture of magmatic fluid. The variation in δD may suggest that sea water mixed dispersively with the fluid.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 79 (1982), S. 76-79 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract An extremely differentiated suite of unaltered volcanic rocks dredged from the Galapagos Spreading Center ranges in δ 18O from 5.7 to 7.1‰ At 95°W, low K-tholeiites, FeTi-basalts, andesites and rhyodacites were recovered. Their lithologic and major element geochemical variation can be accounted for by crystal fractionation of plagioclase, pyroxenes, olivine and titanomagnetite in the same proportions and amounts needed to model the δ 18O variation by simple Rayleigh fractionation. More complicated behaviour was observed in a FeTi-basalt suite from 85°W. This study shows that 90% fractionation only enriches the residual melt by about 1.2‰ in 18O. It also implies that the magma chambers along parts of the Galapagos Spreading Center were static and isolated such that extreme differentiation could occur.
    Type of Medium: Electronic Resource
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  • 9
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    PANGAEA
    In:  Supplement to: Alt, Jeffrey C; Laverne, Christine; Muehlenbachs, Karlis (1985): Alteration of the upper oceanic crust: Mineralogy and processes in Deep Sea Drilling Project Hole 504B, Leg 83. In: Anderson, RN; Honnorez, J; Becker, K; et al. (eds.), Initial Reports of the Deep Sea Drilling Project, Washington (U.S. Govt. Printing Office), 83, 217-247, https://doi.org/10.2973/dsdp.proc.83.108.1985
    Publication Date: 2023-05-12
    Description: Leg 83 of the Deep Sea Drilling Project has deepened Hole 504B to over 1 km into basement, 1350 m below the seafloor (BSF). The hole previously extended through 274.5 m of sediment and 561.5 m of pillow basalts altered at low temperature (〈 100°C), to 836 m BSF. Leg 83 drilling penetrated an additional 10 m of pillows, a 209-m transition zone, and 295 m into a sheeted dike complex. Leg 83 basalts (836-1350 m BSF) generally contain superimposed greenschist and zeolite-facies mineral parageneses. Alteration of pillows and dikes from 836 to 898 m BSF occurred under reducing conditions at low water/rock ratios, and at temperatures probably greater than 100°C. Evolution of fluid composition resulted in the formation of (1) clay minerals, followed by (2) zeolites, anhydrite, and calcite. Alteration of basalts in the transition zone and dike sections (898-1350 m BSF) occurred in three basic stages, defined by the opening of fractures and the formation of characteristic secondary minerals. (1) Chlorite, actinolite, pyrite, albite, sphene, and minor quartz formed in veins and host basalts from partially reacted seawater (Mg-bearing, locally metal-and Si-enriched) at temperatures of at least 200-250°C. (2) Quartz, epidote, and sulfides formed in veins at temperatures of up to 380°C, from more evolved (Mg-depleted, metal-, Si-, and 18O-enriched) fluids. (3) The last stage is characterized by zeolite formation: (a) analcite and stilbite formed locally, possibly at temperatures less than 200°C followed by (b) formation of laumontite, heulàndite, scolecite, calcite, and prehnite from solutions depleted in Mg and enriched in Ca and 18O, at temperatures of up to 250°C. The presence of small amounts of anhydrite locally may be due to ingress of relatively unaltered seawater into the system during Stage 3. Alteration was controlled by the permeability of the crust and is characterized by generally incomplete recrystallization and replacement reactions among secondary minerals. Secondary mineralogy in the host basalts is strongly controlled by primary mineralogy. The alteration of Leg 83 basalts can be interpreted in terms of an evolving hydrothermal system, with (a) changes in solution composition because of reaction of seawater fluids with basalts at high temperatures; (b) variations in permeability caused by several stages of sealing and reopening of cracks; and (c) a general cooling of the system, caused either by the cooling of a magma chamber beneath the spreading center and/or the movement of the crust away from the heat source. The relationship of the high-temperature alteration in the transition zone and dike sections to the low-temperature alteration in the overlying pillow section remains uncertain.
    Keywords: Deep Sea Drilling Project; DSDP
    Type: Dataset
    Format: application/zip, 14 datasets
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  • 10
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    Unknown
    PANGAEA
    In:  Supplement to: Furnes, Harald; Muehlenbachs, Karlis; Torsvik, Terje; Thorseth, Ingunn H; Tumyr, Ole (2001): Microbial fractionation of carbon isotopes in altered basaltic glass from the Atlantic Ocean, Lau Basin and Costa Rica Rift. Chemical Geology, 173(4), 313-330, https://doi.org/10.1016/S0009-2541(00)00285-0
    Publication Date: 2023-06-27
    Description: Textural and DNA studies of pillow lavas in DSDP/ODP cores from the Atlantic Ocean, the Lau Basin and the Costa Rica Rift indicate that microbes had a significant role in the alteration of basaltic glasses. Carbon isotopes (d13C) in carbonates from glassy and crystalline basalts from these locations also show differences that may relate to microbial activity during alteration. The generally low d13C values (〈 -7 per mil) in the basaltic glass of a high proportion of samples from the Atlantic, and most of the Costa Rica Rift material were attributed to alteration influenced by Bacteria and oxidation of organic matter. Positive d13C values of some samples from the Atlantic suggest lithotrophic utilization of CO2, in which methanogenic Archaea produced CH4 from H2 and CO2. This may result from higher abiotic production of H2 in the slow-spreading, fault-dominated Atlantic crust, due to more extensive serpentinization than at the intermediate-spreading Costa Rica Rift.
    Keywords: 106-648B; 135-834B; 46-396B; 49-407; 49-408; 49-409; 49-410A; 49-411; 49-412A; Age, dated; Age, maximum/old; Age, minimum/young; Calcite; Comment; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Event label; Glomar Challenger; Joides Resolution; Latitude of event; Leg106; Leg135; Leg46; Leg49; Longitude of event; Mass spectrometer Finnigan MAT 251; North Atlantic/BASIN; North Atlantic/FRACTURE ZONE; North Atlantic/RIDGE; Sample code/label; Sample comment; Sediment thickness; South Atlantic Ocean; South Pacific Ocean; δ13C; δ18O
    Type: Dataset
    Format: text/tab-separated-values, 488 data points
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