Description: Brothers volcano, of the Kermadec intraoceanic arc, is host to a hydrothermal system unique among seafloor hydrothermal systems known anywhere in the world. It has two distinct vent fields, known as the NW Caldera and Cone sites, whose geology, permeability, vent fluid compositions, mineralogy, and ore-forming conditions are in stark contrast to each other. The NW Caldera site strikes for ∼600 m in a SW–NE direction with chimneys occurring over a ∼145-m depth interval, between ∼1,690 and 1,545 m. At least 100 dead and active sulfide chimney spires occur in this field and are typically 2–3 m in height, with some reaching 6–7 m. Their ages (at time of sampling) fall broadly into three groups: 〈4, 23, and 35 years old. The chimneys typically occur near the base of individual fault-controlled benches on the caldera wall, striking in lines orthogonal to the slopes. Rarer are massive sulfide crusts 2–3 m thick. Two main types of chimney predominate: Cu-rich (up to 28.5 wt.% Cu) and, more commonly, Zn-rich (up to 43.8 wt.% Zn). Geochemical results show that Mo, Bi, Co, Se, Sn, and Au (up to 91 ppm) are correlated with the Cu mineralization, whereas Cd, Hg, Sb, Ag, and As are associated with the dominant Zn-rich mineralization. The Cone site comprises the Upper Cone site atop the summit of the recent (main) dacite cone and the Lower Cone site that straddles the summit of an older, smaller, more degraded dacite cone on the NE flank of the main cone. Huge volumes of diffuse venting are seen at the Lower Cone site, in contrast to venting at both the Upper Cone and NW Caldera sites. Individual vents are marked by low-relief (≤0.5 m) mounds comprising predominately native sulfur with bacterial mats. Vent fluids of the NW Caldera field are focused, hot (≤300°C), acidic (pH ≥ 2.8), metal-rich, and gas-poor. Calculated end-member fluids from NW Caldera vents indicate that phase separation has occurred, with Cl values ranging from 93% to 137% of seawater values. By contrast, vent fluids at the Cone site are diffuse, noticeably cooler (≤122°C), more acidic (pH 1.9), metal-poor, and gas-rich. Higher-than-seawater values of SO4 and Mg in the Cone vent fluids show that these ions are being added to the hydrothermal fluid and are not being depleted via normal water/rock interactions. Iron oxide crusts 3 years in age cover the main cone summit and appear to have formed from Fe-rich brines. Evidence for magmatic contributions to the hydrothermal system at Brothers includes: high concentrations of dissolved CO2 (e.g., 206 mM/kg at the Cone site); high CO2/3He; negative δD and δ18OH2O for vent fluids; negative δ34S for sulfides (to −4.6‰), sulfur (to −10.2‰), and δ15N2 (to −3.5‰); vent fluid pH values to 1.9; and mineral assemblages common to high-sulfidation systems. Changing physicochemical conditions at the Brothers hydrothermal system, and especially the Cone site, occur over periods of months to hundreds of years, as shown by interlayered Cu + Au- and Zn-rich zones in chimneys, variable fluid and isotopic compositions, similar shifts in 3He/4He values for both Cone and NW Caldera sites, and overprinting of “magmatic” mineral assemblages by water/rock-dominated assemblages. Metals, especially Cu and possibly Au, may be entering the hydrothermal system via the dissolution of metal-rich glasses. They are then transported rapidly up into the system via magmatic volatiles utilizing vertical (∼2.5 km long), narrow (∼300-m diameter) “pipes,” consistent with evidence of vent fluids forming at relatively shallow depths. The NW Caldera and Cone sites are considered to represent stages along a continuum between water/rock- and magmatic/hydrothermal-dominated end-members.

Description: Helium isotope measurements in six major basins in the Gulf of California show that the deep Guaymas Basin has 3He/4He 65–70% higher than atmospheric helium, clear evidence of mantle helium injection. Smaller 3He excesses observed in the Carmen and Farallon basins may be derived from this Guaymas Basin anomaly. The 3He concentrations in the Mazatlan Basin in the mouth of the Gulf of California are similar to average eastern Pacific values, indicating that the Gulf does not provide a significant flux of 3He into the general Pacific circulation. On the basis of temperature and salinity measurements an upper limit of 0.28°C can be placed on the amount of geothermal heating observed in any of the basins. The isotopic ratio of the injected Guaymas Basin helium is found to be 3He/4He = (1.10±0.06) × 10−5, almost identical to the helium signature observed at the Galapagos Rift but somewhat lower than the average ratio in oceanic basalt glasses.

Description: Along the Galápagos Spreading Center (GSC), 3He/4He varies from 8.5–5.9 RA. High 3He/4He ratios, resembling those in the western and southern Galápagos islands, are absent. This lack of high 3He/4He contrasts markedly with other localities of plume–ridge interaction, such as Iceland, Easter, and Amsterdam/St. Paul. The most striking feature is a 3He/4He gradient, decreasing westward from 8.4–7.0 RA between 89 and 93°W, where the GSC is shallowest and shows “axial high” morphology. The intra-segment 3He/4He variability within this region indicates that magma crosses the mantle/crust boundary at multiple points beneath individual ridge segments, and lateral mixing within the crust and upper mantle is limited. Some of the 3He/4He variability may also reflect transfer of discrete heterogeneity from beneath the northern sector of the Galápagos plateau. One possible explanation for the absence of high 3He/4He along the GSC is that helium is a relatively ineffective downstream tracer of mantle material from the core of the Galápagos plume, due to its preferential extraction beneath the archipelago compared to other incompatible, lithophile tracers. A second explanation is that the heterogeneous Galápagos plume is sheared in the upper mantle by motion of the Nazca Plate relative to the migrating GSC. In this case, plume core material having high 3He/4He (from beneath Fernandina and Isabela) would be dispersed mostly away from the ridge, while plume edge material having low 3He/4He plus enriched Sr and Pb isotope signatures (from beneath the northern periphery of the archipelago) is smeared into the sub-ridge mantle.

Description: Subduction of oceanic crust and the formation of volcanic arcs above the subduction zone are important components in Earth’s geological and geochemical cycles. Subduction consumes and recycles material from the oceanic plates, releasing fluids and gases that enhance magmatic activity, feed hydrothermal systems, generate ore deposits and nurture chemosynthetic biological communities. Among the first lavas to erupt at the surface from a nascent subduction zone are a type classified as boninites. These lavas contain information about the early stages of subduction, yet because most subduction systems on Earth are old and well-established, boninite lavas have previously only been observed in the ancient geological record. Here we observe and sample an active boninite eruption occurring at 1,200 m depth at the West Mata submarine volcano in the northeast Lau Basin, southwest Pacific Ocean. We find that large volumes of H2O, CO2 and sulphur are emitted, which we suggest are derived from the subducting slab. These volatiles drive explosive eruptions that fragment rocks and generate abundant incandescent magma-skinned bubbles and pillow lavas. The eruption has been ongoing for at least 2.5 years and we conclude that this boninite eruption is a multi-year, low-mass-transfer-rate eruption. Thus the Lau Basin may provide an important site for the long-term study of submarine volcanic eruptions related to the early stages of subduction.

Description: Strombolian-style volcanic activity has persisted for six years at the NW Rota-1 submarine volcano in the southern Mariana Arc, allowing direct observation and sampling of gas-rich fluids produced by actively degassing lavas, and permitting study of the magma-hydrothermal transition zone. Fluids sampled centimeters above erupting lava and percolating through volcaniclastic sediments around an active vent have dissolved sulfite 〉100 mmol/kg, total dissolved sulfide 1 mmol/kg. If NW Rota is representative of submarine arc eruptions, then volcanic vent fluids from seawater-lava interaction on submarine arcs have a significant impact on the global hydrothermal flux of sulfur and Al to the oceans, but a minimal impact on Mg removal. Gas ratios (SO2, CO2, H2, and He) are variable on small spatial and temporal scales, indicative of solubility fractionation and gas scrubbing. Elemental sulfur (Se) is abundant in solid and molten form, produced primarily by disproportionation of magmatic SO2 injected into seawater. Se accumulates within the porous rock surrounding the lava conduit connecting the magma source to the seafloor. Accumulated Se can be heated, melted, and pushed upward by rising magma to produce molten Se flows and lavas saturated with Se. Molten Se near the top of the lava conduit may be ejected up into the water column by escaping gases or boiling water. This mechanism of Se accumulation and refluxing may underlie the relatively widespread occurrence of Se deposits of many sizes found on submarine arc volcanoes.