ISSN:
0009-2940
Keywords:
Fullerenes
;
[3 + 2] Cycloadditions
;
Nitrile oxides
;
Isoxazoles
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Functionalization of C60 with Nitrile Oxides to 4,5-Dihydroisoxazoles and Their Structure DeterminationCycloadducts 3 of nitrile oxides 2 with C60 (1) are synthesized and isolated. The cycloadducts are characterized by 13C-NMR spectroscopy and high-resolution FAB mass spectrometry. X-ray structure determination of the 3-(9-anthryl)-4,5-dihydroisoxazole derivative 3a of C60 with CS2 included in the crystals is achieved at 173 K without disorder problems.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270318
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