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  • 1
    Publication Date: 2023-03-14
    Description: Copious amounts of organic carbon are stored for long periods of time in deep continental groundwaters. Little is known about its composition and cycling, mainly due to the difficulties in obtaining sample material. Cool fracture waters of different origins can be obtained under clean conditions at Äspö Hard Rock Laboratory (Äspö HRL, Sweden), operated by the Swedish Nuclear Fuel and Waste Management Company (SKB). We sampled groundwater from different depth (171 to 507 meter below sea level) in the bedrock fractures in November 2018 and March-April 2019. We assessed water chemistry and dissolved organic matter composition via stable carbon isotopic and molecular-formula level analysis in recent Baltic Sea-influenced to old saline fracture waters in the granitic Fennoscandian shield. Physicochemical parameters, major ions, water isotopic compositions (δ18O and δD), total nitrogen as well as dissolved organic matter concentration and stable isotopic composition were obtained for unfiltered groundwater samples from different boreholes.
    Keywords: aquifer; BalticSea_Äspö; BalticSea_Kalmar; Calcium; Carbon, organic, dissolved; Carbon, organic, dissolved, standard deviation; Carbon-14, modern, dissolved inorganic carbon; Carbon-14, modern, dissolved organic carbon; Chlorine; Conductivity; DATE/TIME; Elevation of event; Event label; Extraction efficiency; FT-ICR-MS; groundwater; HA2780A_1; Iron; Iron, total; Iron 2+; KA1755A_3; KA2051A01_5; KA2511A_5; KA2862A_1; KA2865A01_1; KA3105A_3; KA3385A_1; KA3510A_2; KA3600F_2; Latitude of event; Longitude of event; Magnesium; Manganese; Nitrogen, total dissolved; Nitrogen, total dissolved, standard deviation; Nitrogen in ammonium; Nitrogen in nitrate; Nitrogen in nitrite; pH; Phosphorus in phosphate; Potassium; SA1229A_1; SA1730A_1; SA2600A_1; Sodium; Sulfide in hydrogen sulfide; Sulfur in sulfate; Sweden; Temperature, water; Type; δ13C, dissolved inorganic carbon; δ13C, dissolved organic carbon; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 1050 data points
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2023-01-30
    Description: Copious amounts of organic carbon are stored for long periods of time in deep continental groundwaters. Little is known about its composition and cycling, mainly due to the difficulties in obtaining sample material. Cool fracture waters of different origins can be obtained under clean conditions at Äspö Hard Rock Laboratory (Äspö HRL, Sweden), operated by the Swedish Nuclear Fuel and Waste Management Company (SKB). We sampled groundwater from different depth (171 to 507 meter below sea level) in the bedrock fractures in November 2018 and March-April 2019. We assessed water chemistry and dissolved organic matter composition via stable carbon isotopic and molecular-formula level analysis in recent Baltic Sea-influenced to old saline fracture waters in the granitic Fennoscandian shield. Molecular-level dissolved organic matter composition via Fourier-transform ion cyclotron resonance mass spectrometry using electrospray ionization in negative mode (FT-ICR-MS, 15 T Bruker Solarix) was done on solid-phase extracted (PPL) DOM extracts. Relative peak intensities from FT-ICR-MS with molecular formula attributions, elemental ratios and compound group classification of the final dataset are given. ICBM-Ocean was used for processing of FT-ICR mass spectra and formula attribution (Merder et al., 2020; doi:10.1021/acs.analchem.9b05659).
    Keywords: aquifer; Aromaticity index, modified; BalticSea_Äspö; BalticSea_Kalmar; Double bond equivalent; Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS, 15 T Bruker Solarix); FT-ICR-MS; groundwater; HA2780A_1; Hydrogen/Carbon ratio; KA1755A_3; KA2051A01_5; KA2511A_5; KA2862A_1; KA2865A01_1; KA3105A_3; KA3385A_1; KA3510A_2; KA3600F_2; Mass of molecular formulas; Molecular formula; Nitrogen/Carbon ratio; Oxygen/Carbon ratio; Peak intensity; Phosphorus/Carbon ratio; Presence/absence; SA1229A_1; SA1730A_1; SA2600A_1; Sulfur/Carbon ratio; Sweden
    Type: Dataset
    Format: text/tab-separated-values, 814592 data points
    Location Call Number Limitation Availability
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